A general approach towards thermoplastic multishape-memory polymers via sequence structure design
Abstract
The chain sequence of a poly(styrene-co-methyl acrylate) copolymer is designed to form a V-shaped gradient sequence via controlled/living radical emulsion copolymerization. This specially designed chain sequence gives this common copolymer the capacity of multishape memory. The copolymer can sequentially recover to its permanent shape from three or more previously programmed temporary shapes with the stimulus of temperature.
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Thermoplastic amorphous m-SMPs proposed by Luo et al. were easily processable.
“In contrast thermoplastic amorphous m-SMPs proposed by Luo et al. were easily processable [79].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [79]
Observed island morphology, nanodomains of St surrounded by PMMA matrix, confirmed network structure formation on the basis of physical cross-linking.
“The observed island morphology, nanodomains of St surrounded by PMMA matrix, confirmed the network structure formation on the basis of the physical cross-linking.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [79]
The broad Tg of V-shaped poly(St-grad-MA) (ranging from 20°C to 100°C) offered the possibility to create various materials with t-, q- and quintuple-SME.
“The broad Tg of V-shaped poly(St-grad-MA) (ranging from 20 ° C to 100 ° C), offered the possibility to create various materials with t-, q- and quintuple-SME.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [79]
The respective homopolymers of styrene and methyl acrylate possess two well-separated Tg.
“Their respective homopolymers have the advantage to possess two well-separate Tg.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [79]
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- Authors
- Luo, Y., Guo, Y., Gao, X., Li, B., & Xie, T.
- Affiliations
- State Key Laboratory of Chemical Engineering (CN)
- Corresponding author
- Gao, Xiang
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2012-10-26
- Volume
- 25
- Issue
- 5
- Pages
- 743-748
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2088311110
- Cited by
- 188
- References
- 28
- Citations by year
- 2026: 3 · 2025: 8 · 2024: 6 · 2023: 11 · 2022: 16 · 2021: 13 · 2020: 16 · 2019: 16 · 2018: 15 · 2017: 21 · 2016: 20 · 2015: 23 · 2014: 14 · 2013: 6
- FWCI
- 21.03
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- shape memory polymers, thermoplastics, controlled radical polymerization, shape recovery
- MeSH terms
- Computer Simulation, Materials Testing, Models, Chemical, Models, Molecular, Polymers, Temperature, Elastic Modulus
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