Significant impact of thermo-mechanical conditions on polymer triple-shape memory effect
Abstract
A polymer triple-shape memory effect represents one of the most recent discoveries in the rapidly expanding field of shape memory polymers. It refers to the capability of a polymer to memorize two temporary shapes and subsequently recover them, all in one shape memory cycle. Although several examples of triple-shape polymers had been reported in the literature, they were notably evaluated under very different thermo-mechanical conditions. In this study, the effect of various thermo-mechanical conditions on the polymer triple-shape properties was investigated using Nafion as a model material. The choice of the programming and recovery heating methods in constructing triple-shape cycles was found to have a profound impact on the triple-shape properties. As such, the results of this study provided useful reference for future development of triple-shape polymers.
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Parallel studies demonstrated the importance of the thermomechanical programming step, specifically the control of stress and strain in the applied methods.
“Parallel studies demonstrated the importance of the thermomechanical programming step. It concerned precisely the control of the stress and the strain in the applied methods [77,78].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [77]
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- Authors
- Li, J., & Xie, T.
- Affiliations
- General Motors (United States) (US)
- Corresponding author
- Xie, Tao
- ORCID
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-13
- Volume
- 44
- Issue
- 1
- Pages
- 175-180
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2080573691
- Cited by
- 121
- References
- 37
- Citations by year
- 2025: 2 · 2024: 3 · 2023: 6 · 2022: 3 · 2021: 6 · 2020: 7 · 2019: 4 · 2018: 7 · 2017: 11 · 2016: 11 · 2015: 14 · 2014: 15 · 2013: 8 · 2012: 14
- FWCI
- 18.86
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
- Keywords
- triple shape memory effect, shape memory polymers, Nafion, shape recovery
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