Multishape memory effect of norbornene-based copolymers with cholic acid pendant groups
Abstract
Multishape memory copolymers were prepared through copolymerization of two norbornene derivatives: one based on cholic acid and the other on triethylene glycol monomethyl ether. The glass transition temperature ( T g ) of the copolymers can be tuned over a temperature range from −58 to 176 °C. Most of these copolymers displayed a very broad T g over a 20 °C range which can allow a multishape memory effect. The shape memory properties of the copolymer incorporating an equal molar amount of both monomers have been studied in detail. The multishape memory effect was investigated by dynamic mechanical analysis using a thermomechanical programming process, in which multiple steps created two, three, and four temporary shapes. The polymer displayed good shape fixing and recovery in different thermal processing stages over the broad glass transition range. This series of copolymers with broad and tunable T g ’s may be useful as functional materials with multishape memory effect.
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The temperature-memory effect approach has been largely employed to achieve multiple-way SMPs with a broad glass transition or a broad melting transition as the switching transition.
“Such an approach has been largely employed to achieve multiple-way SMPs with a broad glass transition [82-92] and a broad melting transition [93-95] as the switching transition.”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [86]
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- Authors
- Shao, Y., Lavigueur, C., & Zhu, X. X.
- Affiliations
- Université de Montréal (CA)
- Corresponding author
- Zhu, X. X.
- ORCID
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-10
- Volume
- 45
- Issue
- 4
- Pages
- 1924-1930
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2330349169
- Cited by
- 80
- References
- 45
- Citations by year
- 2026: 1 · 2024: 3 · 2023: 3 · 2022: 4 · 2021: 6 · 2020: 6 · 2019: 6 · 2018: 8 · 2017: 6 · 2016: 9 · 2015: 6 · 2014: 9 · 2013: 11 · 2012: 2
- FWCI
- 7.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Funders
- Canada Research Chairs
- Fonds Québécois de la Recherche sur la Nature et les Technologies
- Korea Astronomy and Space Science Institute
- Natural Sciences and Engineering Research Council of Canada
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Keywords
- norbornene copolymers, triethylene glycol monomethyl ether, functional polymers
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