Cited by 554Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsNanomaterials for catalytic reactions

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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation

Wang, Xiaoguang, Kolen'ko, Yury V., Bao, Xiao‐Qing, Kovnir, Kirill, Liu, Lifeng·2015·Angewandte Chemie International Edition

Abstract

Nickel phosphide is an emerging low‐cost, earth‐abundant catalyst that can efficiently reduce water to generate hydrogen. However, the synthesis of nickel phosphide catalysts usually involves multiple steps and is laborious. Herein, a convenient and straightforward approach to the synthesis of a three‐dimensional (3D) self‐supported biphasic Ni 5 P 4‐Ni 2 P nanosheet (NS) array cathode is presented, which is obtained by direct phosphorization of commercially available nickel foam using phosphorus vapor. The synthesized 3D Ni 5 P 4‐Ni 2 P‐NS array cathode exhibits outstanding electrocatalytic activity and long‐term durability toward the hydrogen evolution reaction (HER) in acidic medium. The fabrication procedure reported here is scalable, showing substantial promise for use in water electrolysis. More importantly, the approach can be readily extended to synthesize other self‐supported transition metal phosphide HER cathodes.

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Metadata

Authors
Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L.
Affiliations
  • International Iberian Nanotechnology Laboratory (PT)
  • University of California, Davis (US)
Corresponding author
Liu, Lifeng
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-06
Volume
54
Issue
28
Pages
8188-8192
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2097730964
Cited by
554
References
0
Citations by year
2026: 6 · 2025: 13 · 2024: 29 · 2023: 17 · 2022: 52 · 2021: 41 · 2020: 55 · 2019: 76 · 2018: 82 · 2017: 93 · 2016: 77 · 2015: 12
FWCI
26.05
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
Keywords
nickel phosphide, nanosheet arrays, self-supported catalysts, hydrogen evolution reaction, electrocatalysis, phosphorization, nickel foam, phosphorus vapor, water electrolysis, acidic media, transition metal phosphides, three-dimensional nanostructures

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