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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation
Abstract
Nickel phosphide is an emerging low‐cost, earth‐abundant catalyst that can efficiently reduce water to generate hydrogen. However, the synthesis of nickel phosphide catalysts usually involves multiple steps and is laborious. Herein, a convenient and straightforward approach to the synthesis of a three‐dimensional (3D) self‐supported biphasic Ni 5 P 4‐Ni 2 P nanosheet (NS) array cathode is presented, which is obtained by direct phosphorization of commercially available nickel foam using phosphorus vapor. The synthesized 3D Ni 5 P 4‐Ni 2 P‐NS array cathode exhibits outstanding electrocatalytic activity and long‐term durability toward the hydrogen evolution reaction (HER) in acidic medium. The fabrication procedure reported here is scalable, showing substantial promise for use in water electrolysis. More importantly, the approach can be readily extended to synthesize other self‐supported transition metal phosphide HER cathodes.
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“The Ni5P4−Ni2P nanosheet11 supported on nickel foam (NF) exhibited good durability for 72 h at a current density of 10 mA cm−2”
From Silver Nanowire Aerogel Support Promotes Stable Hydrogen Evolution Reaction at High Current Density (2024) · cites this paper as [11]
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Metadata
- Authors
- Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L.
- Affiliations
- International Iberian Nanotechnology Laboratory (PT)
- University of California, Davis (US)
- Corresponding author
- Liu, Lifeng
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-06
- Volume
- 54
- Issue
- 28
- Pages
- 8188-8192
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2097730964
- Cited by
- 554
- References
- 0
- Citations by year
- 2026: 6 · 2025: 13 · 2024: 29 · 2023: 17 · 2022: 52 · 2021: 41 · 2020: 55 · 2019: 76 · 2018: 82 · 2017: 93 · 2016: 77 · 2015: 12
- FWCI
- 26.05
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- nickel phosphide, nanosheet arrays, self-supported catalysts, hydrogen evolution reaction, electrocatalysis, phosphorization, nickel foam, phosphorus vapor, water electrolysis, acidic media, transition metal phosphides, three-dimensional nanostructures
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