Cited by 554Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsNanomaterials for catalytic reactions

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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation

Wang, Xiaoguang, Kolen'ko, Yury V., Bao, Xiao‐Qing, Kovnir, Kirill, Liu, Lifeng·2015·Angewandte Chemie International Edition

DOI 10.1002/anie.201502577

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Abstract

Nickel phosphide is an emerging low‐cost, earth‐abundant catalyst that can efficiently reduce water to generate hydrogen. However, the synthesis of nickel phosphide catalysts usually involves multiple steps and is laborious. Herein, a convenient and straightforward approach to the synthesis of a three‐dimensional (3D) self‐supported biphasic Ni 5 P 4‐Ni 2 P nanosheet (NS) array cathode is presented, which is obtained by direct phosphorization of commercially available nickel foam using phosphorus vapor. The synthesized 3D Ni 5 P 4‐Ni 2 P‐NS array cathode exhibits outstanding electrocatalytic activity and long‐term durability toward the hydrogen evolution reaction (HER) in acidic medium. The fabrication procedure reported here is scalable, showing substantial promise for use in water electrolysis. More importantly, the approach can be readily extended to synthesize other self‐supported transition metal phosphide HER cathodes.

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Authors: Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L.
Affiliations: International Iberian Nanotechnology Laboratory (PT)
University of California, Davis (US)
Corresponding author: Liu, Lifeng
ORCID: Wang, Xiaoguang
Kovnir, Kirill
Liu, Lifeng
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2015-06
Volume: 54
Issue: 28
Pages: 8188-8192
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201502577
OpenAlex: W2097730964
Cited by: 554
References: 0
Citations by year: 2026: 6 · 2025: 13 · 2024: 29 · 2023: 17 · 2022: 52 · 2021: 41 · 2020: 55 · 2019: 76 · 2018: 82 · 2017: 93 · 2016: 77 · 2015: 12
FWCI: 26.05
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
Keywords: nickel phosphide, nanosheet arrays, self-supported catalysts, hydrogen evolution reaction, electrocatalysis, phosphorization, nickel foam, phosphorus vapor, water electrolysis, acidic media, transition metal phosphides, three-dimensional nanostructures

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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation

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