Cited by 554Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsNanomaterials for catalytic reactions

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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation

Wang, Xiaoguang, Kolen'ko, Yury V., Bao, Xiao‐Qing, Kovnir, Kirill, Liu, Lifeng·2015·Angewandte Chemie International Edition

DOI 10.1002/anie.201502577

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Abstract

Nickel phosphide is an emerging low‐cost, earth‐abundant catalyst that can efficiently reduce water to generate hydrogen. However, the synthesis of nickel phosphide catalysts usually involves multiple steps and is laborious. Herein, a convenient and straightforward approach to the synthesis of a three‐dimensional (3D) self‐supported biphasic Ni 5 P 4‐Ni 2 P nanosheet (NS) array cathode is presented, which is obtained by direct phosphorization of commercially available nickel foam using phosphorus vapor. The synthesized 3D Ni 5 P 4‐Ni 2 P‐NS array cathode exhibits outstanding electrocatalytic activity and long‐term durability toward the hydrogen evolution reaction (HER) in acidic medium. The fabrication procedure reported here is scalable, showing substantial promise for use in water electrolysis. More importantly, the approach can be readily extended to synthesize other self‐supported transition metal phosphide HER cathodes.

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Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
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Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
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Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
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Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
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Pan, Y., Liu, Y., Zhao, J., Yang, K., Liang, J., Liu, D., Hu, W., Liu, D., Liu, Y., & Liu, C. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04867a · Cited by 652
Enhanced electrocatalytic activity for hydrogen evolution reaction from self-assembled monodispersed molybdenum sulfidenanoparticles on an Au electrode
Wang, T., Liu, L., Zhu, Z., Papakonstantinou, P., Hu, J., Liu, H., & Li, M. (2013) · Energy Environ. Sci. · doi:10.1039/c2ee23513g · Cited by 393
Self-citation
Nickel phosphide: the effect of phosphorus content on hydrogen evolution activity and corrosion resistance in acidic medium
Kucernak, A. R. J., & Naranammalpuram Sundaram, V. N. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta03468f · Cited by 379

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10.1021/cr1002326 · DOI · Paper page
10.1023/B:JACH.0000031161.26544.6a · DOI
10.1002/adma.201302685 · DOI · Paper page
10.1016/j.jpowsour.2014.04.066 · DOI
10.1016/j.ijhydene.2013.07.021 · DOI
10.1039/C3EE42441C · DOI
10.1039/C1SC00117E · DOI
10.1039/c3cc41945b · DOI · Paper page
10.1002/anie.201402998 · DOI
10.1002/ange.201402998 · DOI
10.1016/j.apcatb.2009.01.003 · DOI
10.1039/c4cp00482e · DOI
10.1021/nn5022204 · DOI
10.1039/C4NR03037K · DOI
10.1016/j.ijhydene.2014.09.104 · DOI
10.1039/C4NR04866K · DOI
10.1039/C4NR05862C · DOI
10.1039/C5CC00370A · DOI
10.1002/ange.201402646 · DOI
10.1021/cm501273s · DOI
10.1039/C4TA02368D · DOI
10.1016/j.nanoen.2014.08.013 · DOI · Paper page
10.1002/anie.201404161 · DOI
10.1002/ange.201404161 · DOI
10.1002/anie.201406848 · DOI · Paper page
10.1002/ange.201406848 · DOI
10.1021/nn5048553 · DOI
10.1016/j.nanoen.2015.01.027 · DOI
10.1039/c3cc43107j · DOI
10.1039/C4EE00957F · DOI · Paper page
10.1002/adma.201401692 · DOI · Paper page
10.1021/cm502035s · DOI
10.1039/C4CC04709E · DOI
10.1002/anie.201403842 · DOI
10.1002/ange.201403842 · DOI
10.1021/cr00083a012 · DOI
10.1002/1521-3773(20000717)39:14<2508::AID-ANIE2508>3.0.CO;2-O · DOI
10.1002/1521-3757(20000717)112:14<2561::AID-ANGE2561>3.0.CO;2-B · DOI
10.3891/acta.chem.scand.19-1694 · DOI
10.1002/anie.200462170 · DOI
10.1002/ange.200462170 · DOI
10.1006/jssc.1999.8499 · DOI
10.1016/j.jssc.2006.08.012 · DOI
10.1016/j.jssc.2008.12.007 · DOI
10.1039/C4TA00577E · DOI
10.1039/C3TA13584E · DOI · Paper page
10.1039/c3cc45416a · DOI · Paper page

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Background
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Background
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Background
Electrocatalytic layers for hydrogen evolution reaction based on nickel phosphides: cost-effective fabrication and XPS characterization
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“[38] Wang X, Kolen’ko Y V, Bao X, et al (2015) One-step syn-”
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Nickel phosphide polymorphs with an active (001) surface as excellent catalysts for water splitting
Jung, C. S., Park, K., Lee, Y., Kwak, I. H., Kwon, I. S., Kim, J., Seo, J., Ahn, J.-P., & Park, J. (2019) · CrystEngComm · doi:10.1039/c8ce01884g · Cited by 23
Synergistic modulation in a triphasic Ni5P4-Ni2P@Ni3S2 system manifests remarkable overall water splitting.
Pundir, V., Gaur, A., Kaur, R., Sharma, J., Kumar, R., & Bagchi, V. (2023) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2023.07.112 · Cited by 22
Ruthenium-Alloyed Iron Phosphide Single Crystal with Increased Fermi Level for Efficient Hydrogen Evolution
Kang, Y. S., Han, Y., Chen, H., Borrmann, H., Adler, P., Pohl, D., Hantusch, M., Koenig, M., He, Y., Ma, Y., et al. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c16419 · Cited by 24
Self-citation
Three-Dimensional Needle Branch-like PANI/CoNiP Hybrid Electrocatalysts for Hydrogen Evolution Reaction in Acid Media
Meng, F., Yu, Y., Sun, D., Lin, S., Zhang, X., Xi, T., Xu, C., Ouyang, H., Chu, W., Shang, L., et al. (2021) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c03033 · Cited by 29
A Fe–Ni5P4/Fe–Ni2P heterojunction electrocatalyst for highly efficient solar-to-hydrogen generation
Zhang, R., Wang, G., Wei, Z., Teng, X., Wang, J.-J., Miao, J., Wang, Y.-H., Yang, F.-X., Zhu, X.-W., Chen, C.-F., et al. (2021) · doi:10.1039/d0ta08631b · Cited by 22
Nickel Phosphides Fabricated through a Codeposition–Annealing Technique as Low-Cost Electrocatalytic Layers for Efficient Hydrogen Evolution Reaction
Bernasconi, R., Khalil, M. I., Iaquinta, C., Lenardi, C., Nobili, L. G., & Magagnin, L. (2020) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c00733 · Cited by 28
One-Dimensional Single-Chain Nb2Se9as Efficient Electrocatalyst for Hydrogen Evolution Reaction
Agyapong-Fordjour, F., Oh, S., Lee, J., Chae, S., Choi, K. H., Choi, S. H., Boandoh, S., Yang, W., Huh, J., Kim, K. K., et al. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.9b00918 · Cited by 24
A novel particle-in-nanoplate architecture of iron nickel phosphide intertwined with carbon nanotubes for efficient water oxidation and high-performance sodium-ion batteries
Hao, X., Jiang, Z., Tian, X., Hao, X., Maiyalagan, T., & Jiang, Z. (2019) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2019.03.311 · Cited by 26
Strained Nickel Phosphide Nanosheet Array.
Duan, J.-J., Chen, S., & Zhao, C. (2018) · ACS Applied Materials and Interfaces · doi:10.1021/acsami.8b09147 · Cited by 22
Room Temperature Dissolution of Bulk Elemental Ni and Se for Solution Deposition of a NiSe2 HER Electrocatalyst
McCarthy, C. L., Downes, C. A., & Brutchey, R. L. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b01594 · Cited by 25
Ultra-fast electrochemical preparation of Ni-Cu-Fe nano-micro dendrite as a highly active and stable electrocatalyst for overall water splitting
kazemi, Z. M., Rouhaghdam, A. S., Darband, G. B., Maleki, M., Han, D., & Shanmugam, S. (2023) · Electrochimica Acta · doi:10.1016/j.electacta.2023.142468 · Cited by 21
Atomic Structure and Dynamics of Epitaxial Platinum Bilayers on Graphene.
Robertson, A. W., Lee, G.-D., Lee, S.-W., Buntin, P., Drexler, M., Abdelhafiz, A., Yoon, E., Warner, J. H., & Alamgir, F. (2019) · ACS Nano · doi:10.1021/acsnano.9b06701 · Cited by 21
Lattice Matched Carbide–Phosphide Composites with Superior Electrocatalytic Activity and Stability
Regmi, Y. N., Roy, A. L., King, L. A., Cullen, D. A., Meyer, H. M., Goenaga, G. A., Zawodzinski, T. A., Labbé, N., & Chmely, S. C. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b03377 · Cited by 25
Enhanced hydrogen evolution reaction activity through samarium-doped nickel phosphide (Ni2P) electrocatalyst
Shahroudi, A., & Habibzadeh, S. (2024) · Scientific Reports · doi:10.1038/s41598-024-66775-7 · Cited by 26
“…doping has reduced the Tafel slope of pristine Ni 2 P to values that allow the HER to proceed through the Volmer–Heyrovsky mechanism with a fast Volmer reaction and a controlling Heyrovsky reaction, which signifies that samarium doping has moderated the electrochemical hydrogen adsorption 53 .”
Method
Sphere-Shaped Bimetallic Sulphoselenide: An Efficient Electrocatalyst for Hydrogen Evolution Reaction
Majhi, K. C., & Yadav, M. (2021) · Energy & Fuels · doi:10.1021/acs.energyfuels.1c01079 · Cited by 23
Facile Synthesis of Well-Dispersed Ni2P on N-Doped Nanomesh Carbon Matrix as a High-Efficiency Electrocatalyst for Alkaline Hydrogen Evolution Reaction
Yang, F., Huang, S., Zhang, B., Hou, L., Ding, Y., Bao, W., Xu, C., Wang, Y., & Li, Y. (2019) · Nanomaterials · doi:10.3390/nano9071022 · Cited by 23
“In recent years, Ni2P with different structures has been widely studied and applied in hydrogen evolution reactions, for example, MOF-derived Ni2P [16], Ni2P nanosheets [17], self-supported Ni2P [18], which have been proven to show high hydrogen evolution catalytic activity.”
Background
Composition-controlled synthesis of Ni2−xCoxP nanocrystals as bifunctional catalysts for water splitting
Liang, Q., Huang, K.-K., Wu, X., Wang, X.-Y., Ma, W., & Feng, S.-H. (2017) · RSC Advances · doi:10.1039/c6ra26691f · Cited by 20
Self-citation
Fine Tuning of Torus‐Shaped Mo‐Doped Ni 2 P Nanorings for Enhanced Seawater Electrolysis
Yadav, A., Das, M. R., & Deka, S. (2024) · Small · doi:10.1002/smll.202408036 · Cited by 24
Strong Interface Enhanced Hydrogen Evolution over Molybdenum-Based Catalysts
Peng, Z., Wang, K., Xu, W., Wang, B., Mao, B., Han, Y. H., Tsung, C., Yang, B., Liu, Z., & Li, Y. (2020) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c00045 · Cited by 23
Self-supported NiCoP/nanoporous copper as highly active electrodes for hydrogen evolution reaction
Li, Z. B., Wang, J., Liu, X., Li, R., Wang, H., Wu, Y., Wang, X. Z., & Lü, Z. (2019) · Scripta Materialia · doi:10.1016/j.scriptamat.2019.07.035 · Cited by 21
Self-citation
Modulating Electronic Structure of Cobalt Phosphide Precatalysts via Dual-Metal Incorporation for Highly Efficient Overall Water Splitting
Ding, S., Cao, D., Liu, D., Lin, Y., Wang, C., Wu, C., Zhou, Y., Chen, S., & Song, L. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.9b01501 · Cited by 23
Electrochemically active novel amorphous carbon (a-C)/Cu3P peapod nanowires by low-temperature chemical vapor phosphorization reaction as high efficient electrocatalysts for hydrogen evolution reaction
Manikandan, A., Sriram, P., Hsu, K.-C., Wang, Y., Chen, C.-W., Shih, Y., Yen, T., Jeng, H., Kuo, H., & Chueh, Y. (2019) · Electrochimica Acta · doi:10.1016/j.electacta.2019.05.089 · Cited by 21
Phytic acid-assisted hollow Fe2P/N-C nanoshuttle derived from NH2MIL: Synthesis strategy and electrochemical application for hydrogen evolution
Gong, Y.-X., Xu, L.-H., Zhang, X.-J., Cosnier, S., & Dan, S. (2023) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2023.169418 · Cited by 18
Accelerate the alkaline hydrogen evolution reaction of the heterostructural Ni2P@Ni(OH)2/NF by dispersing a trifle of Ru on the surface
Zhang, Q., Jiao, S., Wang, B., Wang, Z., Lv, X., Wang, W., Tan, Y., Cui, C., & Chen, Y. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.05.136 · Cited by 22
Self-Templated Formation of Fluffy Graphene-Wrapped Ni5P4 Hollow Spheres for Li-Ion Battery Anodes with High Cycling Stability
Zhang, C., Park, G., Lee, B., Xia, L., Miao, H., Yuan, J., & Yu, J. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c03696 · Cited by 24
Nanostructured nickel phosphide as an efficient photocatalyst: Effect of phase on physical properties and dye degradation
Farahi, E., & Memarian, N. (2019) · Chemical Physics Letters · doi:10.1016/j.cplett.2019.06.041 · Cited by 18
Cobalt Based Nanoparticles Embedded Reduced Graphene Oxide Aerogel for Hydrogen Evolution Electrocatalyst
Koo, S. H., Li, D. J., Yun, T., Choi, D. S., Lee, K. E., Lee, G. Y., Oh, Y., Lim, J., Sasikala, S. P., Lee, H. J., et al. (2019) · Particle & Particle Systems Characterization · doi:10.1002/ppsc.201900090 · Cited by 21
Active Pore-Edge Engineering of Single-Layer Niobium Diselenide Porous Nanosheets Electrode for Hydrogen Evolution
Wang, J., Liu, X., Liu, Y., & Yang, G. (2019) · Nanomaterials · doi:10.3390/nano9050751 · Cited by 21
Improving the oxygen evolution performance of nickel phosphide nanoparticles with satellite nitrogen-doped carbon quantum dots
Liao, W., & Huang, L. (2017) · doi:10.1016/j.matlet.2017.07.127 · Cited by 18
Three-dimensional reduced graphene oxide–Mn 3 O 4 nanosheet hybrid decorated with palladium nanoparticles for highly efficient hydrogen evolution
Yan, D., Li, F., Xu, Y., Liu, C., Wang, Y., Tang, Y., Yang, L., & Wang, L. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.06.083 · Cited by 19
Self-supported Ni2P nanotubes coated with FeP nanoparticles electrocatalyst (FeP@Ni2P/NF) for oxygen evolution reaction
Li, H., Du, Y., Fu, Y., Wu, C., Xiao, Z., Liu, Y., Sun, X., & Wang, L. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.10.210 · Cited by 21
Doped Nickel-Based Nanocatalysts for Electrochemical Water Splitting: A Review
Rathore, D., Boruah, A., & Pande, S. (2025) · ACS Applied Nano Materials · doi:10.1021/acsanm.5c03051 · Cited by 23
Implementation of Transition Metal Phosphides as Pt-Free Catalysts for PEM Water Electrolysis
Brito, J., Restivo, J., Sousa, J. P. S., Spera, N. C. M., Falcão, D. S., Rocha, A., Pinto, A. M. F. R., Pereira, M. F. R., & Soares, O. S. G. P. (2022) · Energies · doi:10.3390/en15051821 · Cited by 19
Construction of hollow structure cobalt iron selenide polyhedrons for efficient hydrogen evolution reaction
Xue, Y., Wang, X., Zhu, M., Yan, Q., Zhu, K., Cheng, K., Ye, K., Yan, J., Cao, D., & Wang, G. (2020) · International Journal of Energy Research · doi:10.1002/er.5855 · Cited by 19
“The ohmic resistance generated by the electrolyte is represented by Rs, R1 is caused by the interfacial resistance between the catalyst and the carbon cloth substrate, Rct represents the charge transfer resistance at the interface of the catalyst.(49) The Rct of (Co,Fe)Se2 obtained by equivalent circuit fitting is 6.”
BackgroundSelf-citation
N 2 plasma-activated NiO nanosheet arrays with enhanced water splitting performance
Sai, K. N. S., Tang, Y., Dong, L., Yu, X., & Hong, Z. (2020) · Nanotechnology · doi:10.1088/1361-6528/aba929 · Cited by 23
Morphology engineering of 3D nanostructure MMNS as bifunctional electrocatalysts towards high-efficient overall water splitting
Yang, Z., Lin, Y., Jiao, F., Li, J., Wang, W., Gong, Y., & Jing, X. (2019) · Applied Surface Science · doi:10.1016/j.apsusc.2019.144147 · Cited by 20
Electric Field-Driven Interfacial Alloying for in Situ Fabrication of Nano-Mo2C on Carbon Fabric as Cathode toward Efficient Hydrogen Generation
Jiang, R., Pi, L., Deng, B., Hu, L., Liu, X., Cui, J., Mao, X., & Wang, D. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b11253 · Cited by 24
Predictive fabrication of Ni phosphide embedded in carbon nanofibers as active and stable electrocatalysts
Kim, J.-Y., Park, H., Joo, W., Nam, D., Lee, S., Kim, H. G., Ahn, I., Kang, H., Lee, G., Jung, I., et al. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00455f · Cited by 30
Engineering transition metal phosphide nanomaterials as highly active electrocatalysts for water splitting
Shi, Y., & Zhang, B. (2017) · Dalton Transactions · doi:10.1039/c7dt03648e · Cited by 33
Stoichiometric Control of Electrocatalytic Amorphous Nickel Phosphide to Increase Hydrogen Evolution Reaction Activity and Stability in Acidic Medium
Wasalathanthri, R. N., Jeffrey, S., Su, N., Sun, K., & Giolando, D. M. (2017) · ChemistrySelect · doi:10.1002/slct.201701755 · Cited by 19
Overcoming Stability Hurdles of Transition Metal Phosphides for H 2 Evolution: A Review
da Silva, A. B., dos Reis, E. A., Ribeiro, C., & Mascaro, L. H. (2025) · ChemSusChem · doi:10.1002/cssc.202501388 · Cited by 23
Rational design of ultrahigh porosity Co foam supported flower-like FeNiP-LDH electrocatalysts towards hydrogen evolution reaction
Liu, X., Pei, Y., Huang, L., Lei, W., Li, F.-L., Li, Y.-G., Zhang, H.-J., Jia, Q., & Zhang, S.-W. (2021) · Catalysis Today · doi:10.1016/j.cattod.2021.11.011 · Cited by 16
P-doped nickel sulfide nanosheet arrays for alkaline overall water splitting
He, W.-J., Jia, D., Cheng, J., Wang, F., Zhang, L., Li, Y., Liu, C., Hao, Q., & Zhao, J. (2020) · Catalysis Science & Technology · doi:10.1039/d0cy01577f · Cited by 26
Halamishite, Ni5P4, a new terrestrial phosphide in the Ni–P system
Britvin, S. N., Murashko, M. N., Vapnik, Y., Polekhovsky, Y. S., Krivovichev, S. V., Верещагин, О. С., Shilovskikh, V. V., Vlasenko, N. S., & Krzhizhanovskaya, M. G. (2020) · Physics and Chemistry of Minerals · doi:10.1007/s00269-019-01073-7 · Cited by 22

Authors: Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L.
Affiliations: International Iberian Nanotechnology Laboratory (PT)
University of California, Davis (US)
Corresponding author: Liu, Lifeng
ORCID: Wang, Xiaoguang
Kovnir, Kirill
Liu, Lifeng
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2015-06
Volume: 54
Issue: 28
Pages: 8188-8192
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201502577
OpenAlex: W2097730964
Cited by: 554
References: 0
Citations by year: 2026: 6 · 2025: 13 · 2024: 29 · 2023: 17 · 2022: 52 · 2021: 41 · 2020: 55 · 2019: 76 · 2018: 82 · 2017: 93 · 2016: 77 · 2015: 12
FWCI: 26.05
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
Keywords: nickel phosphide, nanosheet arrays, self-supported catalysts, hydrogen evolution reaction, electrocatalysis, phosphorization, nickel foam, phosphorus vapor, water electrolysis, acidic media, transition metal phosphides, three-dimensional nanostructures

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One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation

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