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Upgrading Carbon Dioxide by Incorporation into Heterocycles
Abstract
Carbon dioxide is commonly regarded as the primary greenhouse gas, but from a synthetic standpoint can be utilized as an alternative and sustainable C 1 synthon in organic synthesis rather than a waste. This results in the production of organic carbonates, carboxylic acids, and derivatives. Recently, CO 2 has emerged as an appealing tool for heterocycle synthesis under mild conditions without using stoichiometric amounts of organometallic reducing reagents. This Minireview summarizes recent advances on methodologies for CO 2 incorporation into N‐, O‐, and C‐nucleophiles to provide various heterocycles, including cyclic carbamates, benzoxazine‐2‐one, 4‐hydroxyquinolin‐2‐one, quinazoline‐2,4(1 H,3 H)‐diones, benzimidazolones, α‐alkylidene cyclic carbonate.
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Self-citation
Metadata
- Authors
- Yu, B., & He, L.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2014-09-10
- Volume
- 8
- Issue
- 1
- Pages
- 52-62
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2006664150
- Cited by
- 358
- References
- 118
- FWCI
- 16.70
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.