The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Chemistry and electrochemistry of hot corrosion of metals
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In the citing paper
“The predominant chemical reactant involved in hot corrosion has been confirmed to be sodium sulfate (Na2SO4), due to its extraordinary stability over a wide range of temperatures and oxygen partial pressures [1, 6, 19].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
In the citing paper
“As with the thin aqueous layer on alloys in atmospheric corrosion, this molten salt layer is a pure ionic conductor which separates the alloys from the gas phase physically [1, 19, 47].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
In the citing paper
“These sulfate salts easily attach onto the surfaces of high temperature components and are melted to form a thin fused salt film at elevated temperatures.”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
In the citing paper
“Moreover, S2O7 2is more active than other oxygen species, i.e., O2 and SO4 2- , and is reduced to SO4 2and SO3 - . This half-reaction can be the main reduction reaction [6, 19, 75].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
In the citing paper
“In the O2-SO2-SO3 environment (Eq. (1)), the solubilities of both O2 and SO2 in molten salt are poor. In contrast, SO3 can dissolve in molten salt because of the formation of pyrosulfate ions through Eq. (2) [1, 19].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
In the citing paper
“In the oxidizing environment without SO2 or SO3, several cathodic reactions including the reduction of oxygen and sulfate ions might be involved as shown in Eq. (18-21) [19, 84].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
In the citing paper
“Chromium is widely recognized as a beneficial element to combat the hot corrosion of various alloys [2, 19].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [19]
Citations
Cites
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Na2SO4-induced accelerated oxidation (hot corrosion) of nickel
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Whitney Award Lecture—1986: Chemistry and Electrochemistry of the Hot Corrosion of Metals
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Self-citationFormation and Reactivity Thermodynamics of Sodium Sulfate With Gas Turbine Alloys
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The Solubilities of NiO , Co3 O 4, and Ternary Oxides in Fused Na2 SO 4 at 1200°K
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Research works printed but not linked: 4
- Bornstein, 1969, Trans. Metall. Soc. AIME, 245, 1947
- Y.S. Zhang and R.A. Rapp, Solubilities of CeO2, HfO2 and Y2O3 in fused Na2SO4−30 m/o NaVO3 and CeO2 in pure Na2SO4 at 900 °C, Corrosion, in the press.
- Rahmel, 1987, Proc. Int. Symp. on High Temperature Corrosion, 85
- Rapp, 1983, 24, 23
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High-temperature corrosion behavior of BaCeO3 in Na2SO4+V2O5 salt mixture
Raj, P. V. S., & Babu, S. P. K. (2024) · Next Materials · doi:10.1016/j.nxmate.2024.100374 · Cited by 3
Sotelo-Mazon, O., Cuevas-Arteaga, C., Porcayo-Calderón, J., Melgoza-Alemán, R. M., Cisneros, M. G. V., Izquierdo-Montalvo, G., & Gómez, L. M. (2015) · International Journal of Electrochemical Science · doi:10.1016/s1452-3981(23)11164-3 · Cited by 3
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Differential aeration corrosion of silver in sulfate melts at 900 °C
Diomande, D., Mathieu, S., Panteix, P., Siblani, M., Aranda, L., Petitjean, C., & Vilasi, M. (2023) · Corrosion Science · doi:10.1016/j.corsci.2023.111504 · Cited by 2
Hot corrosion behavior of Y 3 NbO 7 as thermal barrier coating material
V., S. R. P., P, K. B. S., V., A., & Manivannan, S. (2025) · Surface Engineering · doi:10.1177/02670844251315284 · Cited by 2
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Birks, N., Meier, G. H., & Pettit, F. S. (1996) · Springer eBooks · doi:10.1007/978-94-009-1501-5_11 · Cited by 2
Low-Temperature Hot Corrosion in the Refining Industry
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Fly ash based zeolitic pigments for application in anticorrosive paints
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Surface Engineering for High Temperature Corrosion Resistance
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Hot corrosion characteristics of SrCeO3 as thermal barrier coating material
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Multi-Walled CNT Reinforcement to Thermal Spray Coatings
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Metadata
- Authors
- Rapp, R. A.
- Affiliations
- The Ohio State University (US)
- Corresponding author
- Rapp, Robert A
- Venue
- Materials Science and Engineering
- Publisher
- Elsevier BV
- Published
- 1987-03
- Volume
- 87
- Pages
- 319-327
- ISSN
- 0025-5416 (ISSN-L)
- OpenAlex
- W2027813190
- Cited by
- 155
- References
- 26
- Citations by year
- 2026: 9 · 2025: 8 · 2024: 6 · 2023: 8 · 2022: 6 · 2021: 12 · 2020: 5 · 2019: 9 · 2018: 6 · 2017: 3 · 2016: 4 · 2015: 2 · 2014: 7 · 2013: 7 · 2012: 1
- FWCI
- 4.35
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Materials Science and Engineering (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Electrochemistry › Molten salt chemistry and electrochemical processes
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Metals and Alloys › Metallurgical Processes and Thermodynamics
- Keywords
- hot corrosion, oxide solubility, Pourbaix diagrams, sodium sulfate, sodium metavanadate, acid solubility, electrochemical corrosion mechanism, metal oxides, iron oxide, chromium oxide, alumina
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