Fe, C, and O isotope compositions of banded iron formation carbonates demonstrate a major role for dissimilatory iron reduction in ~2.5Ga marine environments
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Some siderite formed during diagenetic and subsequent metamorphic oxidation of microbial biomass to CO2/bicarbonate coupled to reduction of Fe(III), followed by reaction of Fe2+aq with sediment pore-water bicarbonate.
“Such features suggest that some siderite formed during the diagenetic (biological or non-biological), and subsequent metamorphic, oxidation of microbial biomass to CO2/bicarbonate coupled to the reduction of Fe(III), followed by reaction of the product Fe 2+ aq with sediment pore-water bicarbonate (Johnson et al., 2008; Heimann et al., 2010; Köhler et al., 2013; Halama et al., 2016).”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Heimann et al., 2010
Reactions 3, 5, and 6 predict that a decreasing component of seawater carbonate (high δ13C and δ18O) produces decreases in both δ13C and δ18O of IF carbonate that correlate with a shift from siderite-facies IF to oxide-facies IF.
“Heimann et al. (2010) recognised that reactions 3, 5, and 6 predict changes in both the δ 13 C and δ 18 O values of IF carbonates”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Heimann et al. (2010)
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- Authors
- Heimann, A., Johnson, C. M., Beard, B. L., Valley, J. W., Roden, E. E., Spicuzza, M. J., & Beukes, N. J.
- Affiliations
- University of Wisconsin–Madison (US)
- University of Johannesburg (ZA)
- Corresponding author
- Heimann, Adriana
- Venue
- Earth and Planetary Science Letters
- Publisher
- Elsevier BV
- Published
- 2010-05
- Volume
- 294
- Issue
- 1-2
- Pages
- 8-18
- ISSN
- 0012-821X (ISSN-L)
- OpenAlex
- W2148984976
- Cited by
- 283
- References
- 93
- Citations by year
- 2026: 15 · 2025: 20 · 2024: 27 · 2023: 28 · 2022: 18 · 2021: 22 · 2020: 16 · 2019: 17 · 2018: 15 · 2017: 23 · 2016: 14 · 2015: 13 · 2014: 13 · 2013: 16 · 2012: 11
- FWCI
- 9.09
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Earth and Planetary Science Letters (publishedVersion)
- Funders
- National Science Foundation
- NASA Astrobiology Institute
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- banded iron formations, siderite, dissimilatory iron reduction, δ13C, oxygen isotope composition, iron oxide inclusions, iron remobilization, microbial iron reduction, Precambrian geochemistry
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