Evidence for free oxygen in the Neoarchean ocean based on coupled iron–molybdenum isotope fractionation
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In the Nauga Formation, observations co-occur with evidence from stable iron isotopes for partial iron oxidation.
“In the Nauga Formation, these observations co-occur with evidence from stable iron isotopes for partial iron oxidation (Czaja et al. 2012).”
From The History of Ocean Oxygenation (2022) · cites this paper as Czaja et al. 2012
Strong Re and Mo enrichments and coupled Mo-Fe isotope data were interpreted as evidence for oxidative weathering of sulfide-bearing minerals on the continents, and thus the evolution of oxygenic photosynthesis as early as ca. 2.6 Ga.
“Strong Re and Mo enrichments and coupled Mo-Fe isotope data were interpreted as evidence for oxidative weathering of sulfide-bearing minerals on the continents, and thus the evolution of oxygenic photosynthesis as early as ca. 2.6 Ga (Anbar et al., 2007; Kendall et al., 2010; Czaja et al., 2012; Stüeken et al., 2015b).”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Czaja et al., 2012
Czaja et al. estimated 35 μM O2 content in the photic zone during 2.65-2.5 Ga, being ~12% of modern level.
“The calculations of Czaja et al. (2012), based on covariation in Mo and Fe isotope compositions in carbonates of the 2.65-2.5 Ga Campbellrand-Malmami carbonate platform, estimated 35 µM O2 content in the photic zone during this time period, being ~12% of modern level.”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Czaja et al., 2012
Estimates of maximum O2 contents in shallow oceans potentially provide evidence that the shallow oceans had significant free O2 levels by 3.2 Ga, hundreds of millions of years prior to the rise in atmospheric O2.
“potentially provide evidence that the shallow oceans had significant free O2 levels by 3.2 Ga, hundreds of millions of years prior to the rise in atmospheric O2.”
From Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history (2017) · cites this paper as Czaja et al., 2012
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Self-citationCoagulation/sedimentation of submicron iron particles in a eutrophic lake
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Self-citationMo isotope composition in Mo-rich high- and low-T hydrothermal systems from the Swiss Alps
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Self-citationIsotope fractionation during microbial metal uptake measured by MC-ICP-MS
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Stable Fe isotope fractionations produced by aqueous Fe(II)-hematite surface interactions
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Self-citationNumerical adventures with geochemical cycles
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Evidence for oxygenic photosynthesis half a billion years before the Great Oxidation Event
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Self-citationIron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history
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Self-citationTHE STABLE ISOTOPE GEOCHEMISTRY OF MOLYBDENUM
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Self-citationMolybdenum isotope variations in magmatic rocks
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Biologically recycled continental iron is a major component in banded iron formations
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Self-citationIdentification of an Archean marine oxygen oasis
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Uranium isotope fractionation suggests oxidative uranium mobilization at 2.50 Ga
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The Geologic History of Seawater
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Global glaciations and atmospheric change at ca. 2.3 Ga
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Self-citationEarth's First Redox Revolution
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The biogeochemistry of ferruginous lakes and past ferruginous oceans
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An anoxic, Fe(II)-rich, U-poor ocean 3.46 billion years ago
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Self-citationThe History of Ocean Oxygenation
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Modulation of oxygen production in Archaean oceans by episodes of Fe(II) toxicity
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Self-citationAerobic iron and manganese cycling in a redox-stratified Mesoarchean epicontinental sea
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Self-citationReexamination of 2.5-Ga “whiff” of oxygen interval points to anoxic ocean before GOE
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Iron formation carbonates: paleoceanographic proxy or recorder of microbial diagenesis?
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Self-citationBiogeochemical Transformations in the History of the Ocean
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Fossilized iron bacteria reveal a pathway to the biological origin of banded iron formation
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UV radiation limited the expansion of cyanobacteria in early marine photic environments
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A novel framework for interpreting pyrite-based Fe isotope records of the past
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Geologic and Geochemical Constraints on Earth's Early Atmosphere
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Self-citationOxygenation of Ediacaran Ocean recorded by iron isotopes
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Self-citationTriple iron isotope constraints on the role of ocean iron sinks in early atmospheric oxygenation
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Self-citationEvidence for anoxic shallow oceans at 2.45 Ga: Implications for the rise of oxygenic photosynthesis
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Fe isotopes of a 2.4 Ga hematite-rich IF constrain marine redox conditions around the GOE
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- Authors
- Czaja, A. D., Johnson, C. M., Roden, E. E., Beard, B. L., Voegelin, A. R., Nägler, T. F., Beukes, N. J., & Wille, M.
- Affiliations
- University of Wisconsin–Madison (US)
- University of Bern (CH)
- University of Johannesburg (ZA)
- University of Tübingen (DE)
- Corresponding author
- Czaja, Andrew D.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2012-06
- Volume
- 86
- Pages
- 118-137
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2136298067
- Cited by
- 162
- References
- 125
- Citations by year
- 2026: 3 · 2025: 12 · 2024: 11 · 2023: 7 · 2022: 13 · 2021: 11 · 2020: 10 · 2019: 9 · 2018: 16 · 2017: 14 · 2016: 9 · 2015: 14 · 2014: 11 · 2013: 20 · 2012: 2
- FWCI
- 11.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Funders
- NASA Astrobiology Institute
- Swiss National Science Foundation (20021-126759)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- Great Oxidation Event, free oxygen, Fe(II) oxidation, oxygenic photosynthesis, iron-formation, Kaapvaal Craton
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