Evaluation of nanoparticulate fillers for development of shape memory polyurethane nanocomposites
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Nano Si-based inorganic particles deteriorated the shape memory effect of shape memory polymers even at very low loading.
“Research at the early 90s showed that nano Si-based inorganic particles deteriorated the SME of SMPs even at very low loading.”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [52]
Gunes et al. observed negative effect of SiC on the SME of SMPUs, which they ascribed as due to the dramatically decreased soft segment crystallinity of the SMPU.
“Gunes et al. [52,324] also observed negative effect of SiC on the SME of SMPUs, which they ascribed as due to the dramatically decreased soft segment crystallinity of the SMPU.”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [52]
SMPNCs showed greater stiffness and tensile strength than pure SMPs, which help overcome problems associated with shape-memory materials.
“Interestingly, such SMPNCs showed greater stiffness and tensile strength than pure SMPs, which help to overcome the problems associated with such shape-memory materials.40,41”
Fillers can negatively affect shape recoverability of an SMP due to their size and higher stiffness compared to matrix polymer, and at high loading levels may disturb polymer networks responsible for SM functionality.
“However, in some cases fillers are prone to have negative effects on the shape recoverability of an SMP due to their size and substantially higher stiffness compared to the matrix polymer.At high loading levels, they may even disturb the polymer networks responsible for SM functionality [198].”
From Review on the Functional Determinants and Durability of Shape Memory Polymers (2010) · cites this paper as [198]
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- Authors
- Gunes, I. S., Cao, F., & Jana, S. C.
- Affiliations
- University of Akron (US)
- Corresponding author
- Jana, Sadhan C.
- ORCID
- Jana, Sadhan C.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2008-04
- Volume
- 49
- Issue
- 9
- Pages
- 2223-2234
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2035762490
- Cited by
- 255
- References
- 92
- Citations by year
- 2026: 4 · 2025: 8 · 2024: 12 · 2023: 11 · 2022: 12 · 2021: 14 · 2020: 12 · 2019: 15 · 2018: 13 · 2017: 12 · 2016: 21 · 2015: 20 · 2014: 15 · 2013: 16 · 2012: 15
- FWCI
- 15.87
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Funders
- National Science Foundation
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- shape memory polyurethane, polyurethane nanocomposites, organoclay, carbon nanofibers, silicon carbide, carbon black, soft segment crystallinity, crystallization temperature, mechanical reinforcement, MDI
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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