PH-responsive shape memory poly(ethylene glycol)–poly(ε-caprolactone)-based polyurethane/cellulose nanocrystals nanocomposite
Abstract
In this study, we developed a pH-responsive shape-memory polymer nanocomposite by blending poly(ethylene glycol)-poly(ε-caprolactone)-based polyurethane (PECU) with functionalized cellulose nanocrystals (CNCs). CNCs were functionalized with pyridine moieties (CNC-C6H4NO2) through hydroxyl substitution of CNCs with pyridine-4-carbonyl chloride and with carboxyl groups (CNC-CO2H) via 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) mediated surface oxidation, respectively. At a high pH value, the CNC-C6H4NO2 had attractive interactions from the hydrogen bonding between pyridine groups and hydroxyl moieties; at a low pH value, the interactions reduced or disappeared due to the protonation of pyridine groups, which are a Lewis base. The CNC-CO2H responded to pH variation in an opposite manner. The hydrogen bonding interactions of both CNC-C6H4NO2 and CNC-CO2H can be readily disassociated by altering pH values, endowing the pH-responsiveness of CNCs. When these functionalized CNCs were added in PECU polymer matrix to form nanocomposite network which was confirmed with rheological measurements, the mechanical properties of PECU were not only obviously improved but also the pH-responsiveness of CNCs could be transferred to the nanocomposite network. The pH-sensitive CNC percolation network in polymer matrix served as the switch units of shape-memory polymers (SMPs). Furthermore, the modified CNC percolation network and polymer molecular chains also had strong hydrogen bonding interactions among hydroxyl, carboxyl, pyridine moieties, and isocyanate groups, which could be formed or destroyed through changing pH value. The shape memory function of the nanocomposite network was only dependent on the pH variation of the environment. Therefore, this pH-responsive shape-memory nancomposite could be potentially developed into a new smart polymer material.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
CNCs containing SMCs were characterized by improved mechanical properties.
“The CNCs containing SMCs were characterized by improved mechanical properties”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [186]
Modifying nanofiller surface with pyridine moieties [CNC-C6H4NO2] created a pH-sensitive CNCs percolation network in the polymer matrix, acting as switch units.
“By modifying the nanofiller surface with pyridine moieties [CNCC6H4NO2] it was possible to create pH-sensitive CNCs percolation network in the polymer matrix, acting as the switch units of the materials.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [186]
At low pH, these interactions were reduced or disappeared due to protonation of pyridine groups (Lewis base).
“At low pH value, these interactions were reduced or disappeared due to the protonation of pyridine groups (Lewis base).”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [186]
At high pH, CNC-C6H4NO2 had attractive interactions from hydrogen bonding between pyridine groups and hydroxyl moieties.
“The explored working idea here was that at high pH value, the CNC-C6H4NO2 had attractive interactions from the hydrogen bonding between pyridine groups and hydroxyl moieties.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [186]
Functionalized CNCs can be used effectively for production of pH-responsive SMCs by blending PECU.
“Functionalized CNCs can be used effectively for the production of pH-responsive SMCs by blending poly(ethylene glycol)poly( e -caprolactone)-based polyurethane (PECU) [186].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [186]
Hydrogen bonding interactions can be disassociated by altering pH, monitoring pH-responsiveness of the nanofillers and the materials' shape-memory responsiveness.
“Therefore, the hydrogen bonding interactions can be easily disassociated by altering the pH-environment values monitoring the pH-responsiveness of the nanofillers and the materials shape-memory responsiveness (Fig. 14(d)).”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [186]
Cites
Cellulose nanocrystals: chemistry, self-assembly, and applications
Habibi, Y., Lucia, L. A., & Rojas, O. J. (2010) · Chemical Reviews · doi:10.1021/cr900339w · Cited by 5,980 · see citing works
Azizi Samir, M. A. S., Alloin, F., & Dufresne, A. (2005) · Biomacromolecules · doi:10.1021/bm0493685 · Cited by 2,311 · see citing works
Light-induced shape-memory polymers
Lendlein, A., Jiang, H., Jünger, O., & Langer, R. (2005) · Nature · doi:10.1038/nature03496 · Cited by 2,006 · see citing works
Shape-memory polymers and their composites: stimulus methods and applications
Leng, J., Lan, X., Liu, Y., & Du, S. (2011) · Progress in Materials Science · doi:10.1016/j.pmatsci.2011.03.001 · Cited by 1,495 · see citing works
Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis
Bondeson, D., Mathew, A., & Oksman, K. (2006) · Cellulose · doi:10.1007/s10570-006-9061-4 · Cited by 1,372 · see citing works
Hu, J., Zhu, Y., Huang, H., & Lu, J. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.001 · Cited by 1,279 · see citing works
A review of stimuli-responsive shape memory polymer composites
Meng, H., & Li, G. (2013) · Polymer · doi:10.1016/j.polymer.2013.02.023 · Cited by 1,190 · see citing works
Fleige, E., Quadir, M., & Haag, R. (2012) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2012.01.020 · Cited by 1,114 · see citing works
Multifunctional Shape‐Memory Polymers
Behl, M., Razzaq, M. Y., & Lendlein, A. (2010) · Advanced Materials · doi:10.1002/adma.200904447 · Cited by 971 · see citing works
Stimuli-Responsive Polymer Nanocomposites Inspired by the Sea Cucumber Dermis
Capadona, J. R., Shanmuganathan, K., Tyler, D. J., Rowan, S. J., & Weder, C. (2008) · Science · doi:10.1126/science.1153307 · Cited by 965 · see citing works
Mohr, R., Kratz, K., Weigel, T., Lucka-Gabor, M., Moneke, M., & Lendlein, A. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0600079103 · Cited by 819 · see citing works
Self-shaping composites with programmable bioinspired microstructures
Erb, R. M., Sander, J. S., Grisch, R., & Studart, A. R. (2013) · Nature Communications · doi:10.1038/ncomms2666 · Cited by 656 · see citing works
TEMPO-mediated surface oxidation of cellulose whiskers
Habibi, Y., Chanzy, H., & Vignon, M. R. (2006) · Cellulose · doi:10.1007/s10570-006-9075-y · Cited by 635 · see citing works
Polymers move in response to light
Jiang, H. Y., Kelch, S., & Lendlein, A. (2006) · Advanced Materials · doi:10.1002/adma.200502266 · Cited by 631 · see citing works
Review of electro-active shape-memory polymer composite
Liu, Y., Lv, H., Lan, X., Leng, J., & Du, S. (2009) · Composites Science and Technology · doi:10.1016/j.compscitech.2008.08.016 · Cited by 548 · see citing works
Shape and temperature memory of nanocomposites with broadened glass transition
Miaudet, P., Derré, A., Maugey, M., Zakri, C., Piccione, P. M., Inoubli, R., & Poulin, P. (2007) · Science · doi:10.1126/science.1145593 · Cited by 416 · see citing works
pH‐Stimulated DNA Hydrogels Exhibiting Shape‐Memory Properties
Guo, W., Lu, C., Orbach, R., Wang, F., Qi, X., Cecconello, A., Seliktar, D., & Willner, I. (2015) · Advanced Materials · doi:10.1002/adma.201403702 · Cited by 388 · see citing works
Zhou, S., Deng, X., & Yang, H. (2003) · Biomaterials · doi:10.1016/s0142-9612(03)00207-2 · Cited by 384 · see citing works
TEMPO-Mediated Oxidation of Cellulose III
Perez, D. D. S., Montanari, S., & Vignon, M. R. (2003) · Biomacromolecules · doi:10.1021/bm034144s · Cited by 384 · see citing works
Bioinspired mechanically adaptive polymer nanocomposites with water-activated shape-memory effect
Mendez, J., Annamalai, P. K., Eichhorn, S. J., Rusli, R., Rowan, S. J., Foster, E. J., & Weder, C. (2011) · Macromolecules · doi:10.1021/ma201502k · Cited by 319 · see citing works
pH-induced shape-memory polymers
Han, X., Dong, Z., Fan, M., Liu, Y., li, J., Wang, Y., Yuan, Q., Li, B., & Zhang, S. (2012) · Macromolecular Rapid Communications · doi:10.1002/marc.201200153 · Cited by 304 · see citing works
Self-citationpH-Responsive Cellulose Nanocrystal Gels and Nanocomposites
Way, A. E., Hsu, L., Shanmuganathan, K., Weder, C., & Rowan, S. J. (2012) · ACS Macro Letters · doi:10.1021/mz3003006 · Cited by 286 · see citing works
A high strength nanocomposite based on microcrystalline cellulose and polyurethane
Wu, Q., Henriksson, M., Liu, X., & Berglund, L. A. (2007) · Biomacromolecules · doi:10.1021/bm701061t · Cited by 265 · see citing works
Du, H., & Zhang, J. (2010) · Soft Matter · doi:10.1039/b922220k · Cited by 260 · see citing works
Evaluation of nanoparticulate fillers for development of shape memory polyurethane nanocomposites
Gunes, I. S., Cao, F., & Jana, S. C. (2008) · Polymer · doi:10.1016/j.polymer.2008.03.021 · Cited by 255 · see citing works
Evaluation of a degradable shape-memory polymer network as matrix for controlled drug release
Wischke, C., Neffe, A. T., Steuer, S., & Lendlein, A. (2009) · Journal of Controlled Release · doi:10.1016/j.jconrel.2009.05.027 · Cited by 248 · see citing works
Shape memory properties of poly(d,l-lactide)/hydroxyapatite composites
Zheng, X., Zhou, S., Li, X., & Weng, J. (2006) · Biomaterials · doi:10.1016/j.biomaterials.2006.03.043 · Cited by 230 · see citing works
Conductive shape memory nanocomposites for high speed electrical actuation
Luo, X., & Mather, P. T. (2010) · Soft Matter · doi:10.1039/c001295e · Cited by 229 · see citing works
Cellulose micro/nanocrystals reinforced polyurethane
Marcovich, N. E., Auad, M. L., Bellesi, N. E., Nutt, S., & Aranguren, M. I. (2006) · Journal of materials research/Pratt's guide to venture capital sources · doi:10.1557/jmr.2006.0105 · Cited by 228 · see citing works
Shape‐Memory Polymer in Response to Solution
Lv, H., Leng, J., Liu, Y., & Du, S. (2008) · Advanced Engineering Materials · doi:10.1002/adem.200800002 · Cited by 218 · see citing works
SAHOO, N., JUNG, Y., YOO, H., & CHO, J. (2007) · Composites Science and Technology · doi:10.1016/j.compscitech.2006.10.013 · Cited by 216 · see citing works
Liu, Y., Li, Y., Yang, G., Zheng, X., & Zhou, S. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am5081056 · Cited by 214 · see citing works
Self-citationRapidly switchable water-sensitive shape-memory cellulose/elastomer nano-composites
Zhu, Y., Hu, J., Luo, H., Young, R. J., Deng, L., Zhang, S., Fan, Y., & Ye, G. (2012) · Soft Matter · doi:10.1039/c2sm07035a · Cited by 208 · see citing works
Polymer-Grafted Cellulose Nanocrystals as pH-Responsive Reversible Flocculants
Kan, K. H. M., Li, J., Wijesekera, K. N., & Cranston, E. D. (2013) · Biomacromolecules · doi:10.1021/bm400752k · Cited by 202 · see citing works
Lin, N., & Dufresne, A. (2013) · Macromolecules · doi:10.1021/ma4010154 · Cited by 201 · see citing works
Liu, X., Zhao, K., Gong, T., Song, J. H., Bao, C., Luo, E., Weng, J., & Zhou, S. (2014) · Biomacromolecules · doi:10.1021/bm401911p · Cited by 179 · see citing works
Recent Insights Into the Biomedical Applications of Shape‐memory Polymers
Serrano, M. C., & Ameer, G. A. (2012) · Macromolecular Bioscience · doi:10.1002/mabi.201200097 · Cited by 165 · see citing works
Highly pH-sensitive polyurethane exhibiting shape memory and drug release
Chen, H., Li, Y., Liu, Y., Gong, T., Wang, L., & Zhou, S. (2014) · Polymer Chemistry · doi:10.1039/c4py00474d · Cited by 162 · see citing works
Gao, C., Zhang, S., Wang, F., Wen, B., Han, C., Ding, Y., & Yang, M. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am501843s · Cited by 156 · see citing works
Xiao, Y., Zhou, S., Wang, L., & Gong, T. (2010) · ACS Applied Materials & Interfaces · doi:10.1021/am100692n · Cited by 153 · see citing works
Annamalai, P. K., Dagnon, K. L., Monemian, S., Foster, E. J., Rowan, S. J., & Weder, C. (2013) · ACS Applied Materials & Interfaces · doi:10.1021/am404382x · Cited by 145 · see citing works
Shape-Memory Polymer Composites
Madbouly, S. A., & Lendlein, A. (2009) · Advances in polymer science · doi:10.1007/12_2009_28 · Cited by 138 · see citing works
Zheng, X., Zhou, S., Xiao, Y., Yu, X., Li, X., & Wu, P. (2009) · Colloids and Surfaces B Biointerfaces · doi:10.1016/j.colsurfb.2009.01.009 · Cited by 112 · see citing works
Opacification of Shape Memory Polymer Foam Designed for Treatment of Intracranial Aneurysms
Rodriguez, J. N., Yu, Y.-J., Miller, M. W., Wilson, T. S., Hartman, J., Clubb, F. J., Gentry, B., & Maitland, D. J. (2011) · Annals of Biomedical Engineering · doi:10.1007/s10439-011-0468-1 · Cited by 111 · see citing works
Aoki, D., Teramoto, Y., & Nishio, Y. (2007) · Biomacromolecules · doi:10.1021/bm7006828 · Cited by 105 · see citing works
Water-induced shape-memory poly(d,l-lactide)/microcrystalline cellulose composites
Liu, Y., Li, Y., Chen, H., Yang, G., Zheng, X., & Zhou, S. (2014) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2014.01.031 · Cited by 103 · see citing works
Garle, A. L., Kong, S., Ojha, U., & Budhlall, B. M. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am2011542 · Cited by 101 · see citing works
Saralegi, A., Gonzalez, M. L., Valea, A., Eceiza, A., & Corcuera, M. A. (2014) · Composites Science and Technology · doi:10.1016/j.compscitech.2013.12.001 · Cited by 97 · see citing works
Triple Shape Memory Effect of Star-Shaped Polyurethane
Yang, X., Wang, L., Wang, W., Chen, H., Yang, G., & Zhou, S. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am5001344 · Cited by 86 · see citing works
Thermally activated reversible shape switch of polymer particles
Gong, T., Zhao, K. Y., Wang, W., Chen, H., Wang, L., & Zhou, S. (2014) · Journal of Materials Chemistry B · doi:10.1039/c4tb01155d · Cited by 83 · see citing works
Shape-Memory Polymer Composites
Madbouly, S. A., & Lendlein, A. (2009) · Advances in polymer science · doi:10.1007/978-3-642-12359-7_28 · Cited by 83 · see citing works
High-strain shape memory polymer networks crosslinked by SiO2
Zhang, Y., Wang, Q., Wang, C., & Wang, T. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm11022e · Cited by 79 · see citing works
Hassan, M. L., Moorefield, C. N., Elbatal, H. S., Newkome, G. R., Modarelli, D. A., & Romano, N. C. (2012) · Materials Science and Engineering B · doi:10.1016/j.mseb.2011.12.043 · Cited by 66 · see citing works
Use of intermolecular hydrogen bonding to synthesize triple-shape memory supermolecular composites
Chen, H., Liu, Y., Gong, T., Wang, L., Zhao, K., & Zhou, S. (2013) · RSC Advances · doi:10.1039/c3ra00091e · Cited by 53 · see citing works
Yu, X., Wang, L., Huang, M.-T., Gong, T., Li, W., Cao, Y., Ji, D.-J., Wang, P., Wang, J., & Zhou, S. (2011) · Journal of Materials Science Materials in Medicine · doi:10.1007/s10856-011-4475-4 · Cited by 44 · see citing works
Chen, S., Hu, J., & Zhuo, H. (2011) · Journal of Materials Science · doi:10.1007/s10853-011-5606-5 · Cited by 41 · see citing works
Tuning surface micropattern features using a shape memory functional polymer
Li, W., Gong, T., Chen, H., Wang, L., Li, J., & Zhou, S. (2013) · RSC Advances · doi:10.1039/c3ra41217b · Cited by 37 · see citing works
Novel bio-antifelting agent based on waterborne polyurethane and cellulose nanocrystals
Zhao, Q., Sun, G. Z., Yan, K., Zhou, A., & Chen, Y. (2012) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2012.08.020 · Cited by 33 · see citing works
Redox‐Triggered Self‐Rolling Robust Hydrogel Tubes for Cell Encapsulation
Liu, L., Wang, N., Han, Y., Li, Y., & Liu, W. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300784 · Cited by 30 · see citing works
Wu, T., O'Kelly, K., & Chen, B. (2013) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.23362 · Cited by 23 · see citing works
Wu, T., Su, Y., & Chen, B. (2014) · ChemPhysChem · doi:10.1002/cphc.201402157 · Cited by 14 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
A Review of Shape Memory Polymers and Composites: Mechanisms, Materials, and Applications
Xia, Y., He, Y., Zhang, F., Liu, Y., & Leng, J. (2020) · Advanced Materials · doi:10.1002/adma.202000713 · Cited by 1,293 · see citing works
Nanocellulose, a tiny fiber with huge applications
Abitbol, T., Rivkin, A., Cao, Y., Nevo, Y., Abraham, E., Shalom, T. B., Lapidot, S., & Shoseyov, O. (2016) · Current Opinion in Biotechnology · doi:10.1016/j.copbio.2016.01.002 · Cited by 1,008 · see citing works
Lü, W., Le, X., Zhang, J., Huang, Y., & Chen, T. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00754f · Cited by 463 · see citing works
Shape-memory polymers for multiple applications in the materials world
Pilate, F., Toncheva, A., Dubois, P., & Raquez, J.-M. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.05.004 · Cited by 332 · see citing works
Khalid, M. Y., Rashid, A. A., Arif, Z. U., Ahmed, W., & Arshad, H. (2021) · Journal of Materials Research and Technology · doi:10.1016/j.jmrt.2021.07.128 · Cited by 264 · see citing works
Biodegradable Water-Based Polyurethane Shape Memory Elastomers for Bone Tissue Engineering
Wang, Y.-J., Jeng, U., & Hsu, S. (2018) · ACS Biomaterials Science & Engineering · doi:10.1021/acsbiomaterials.8b00091 · Cited by 163 · see citing works
Shape Memory Polymers Based on Supramolecular Interactions
Jiang, Z., Xiao, Y., Kang, Y., Pan, M., Li, B., & Zhang, S. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b03624 · Cited by 157 · see citing works
Stretchable supramolecular hydrogels with triple shape memory effect
Le, X., Lu, W., Zheng, J., Tong, D., Zhao, N., Ma, C., Xiao, H., Zhang, J., Huang, Y., & Chen, T. (2016) · Chemical Science · doi:10.1039/c6sc02354a · Cited by 152 · see citing works
Yang, G., Wan, X., Liu, Y., Li, R., Su, Y., Zeng, X., & Tang, J. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b11476 · Cited by 144 · see citing works
4D printing with robust thermoplastic polyurethane hydrogel-elastomer trilayers
Baker, A. B., Bates, S. R. G., Llewellyn-Jones, T. M., Valori, L. P. B., Dicker, M. P. M., & Trask, R. S. (2018) · Materials & Design · doi:10.1016/j.matdes.2018.107544 · Cited by 138 · see citing works
High Performance Shape Memory Epoxy/Carbon Nanotube Nanocomposites
Liu, Y., Zhao, J., Zhao, L., Li, W., Zhang, H., Yu, X., & Zhang, Z. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b08766 · Cited by 132 · see citing works
Cellulose nanocrystals in smart and stimuli-responsive materials: a review
Nasseri, R., Deutschman, C. P., Han, L., Pope, M. A., & Tam, K. C. (2020) · Materials Today Advances · doi:10.1016/j.mtadv.2020.100055 · Cited by 132 · see citing works
Azammi, A. M. N., Ilyas, R. A., Sapuan, S. M., Ibrahim, R., Atikah, M. S. N., Asrofi, M., & Atiqah, A. (2020) · Elsevier eBooks · doi:10.1016/b978-0-08-102665-6.00003-0 · Cited by 124 · see citing works
Sikdar, P. P., Dip, T. M., Dhar, A. K., Bhattacharjee, M., Hoque, M. S., & Ali, S. B. (2022) · Journal of Applied Polymer Science · doi:10.1002/app.52832 · Cited by 116 · see citing works
Shape-Memory Polymers Hallmarks and Their Biomedical Applications in the Form of Nanofibers
Pisani, S., Genta, I., Modena, T., Dorati, R., Benazzo, M., & Conti, B. (2022) · International Journal of Molecular Sciences · doi:10.3390/ijms23031290 · Cited by 117 · see citing works
Guo, F., Zheng, X., Liang, C., Jiang, Y., Xu, Z., Jiao, Z., Liu, Y., Wang, H., Sun, H., Ma, L., et al. (2019) · ACS Nano · doi:10.1021/acsnano.9b00428 · Cited by 109 · see citing works
Recent Progress in Shape Memory Polymers for Biomedical Applications
Chen, H., Wang, L., & Zhou, S. (2018) · Chinese Journal of Polymer Science · doi:10.1007/s10118-018-2118-7 · Cited by 104 · see citing works
Biomimetic micro/nano structures for biomedical applications
Xiang, T., Hou, J., Xie, H. Q., Liu, X., Gong, T., & Zhou, S. (2020) · Nano Today · doi:10.1016/j.nantod.2020.100980 · Cited by 103 · see citing works
PH Responsive Polyurethane for the Advancement of Biomedical and Drug Delivery
Tan, R. Y. H., Lee, C. S., Pichika, M. R., Cheng, S. F., & Lam, K. Y. (2022) · Polymers · doi:10.3390/polym14091672 · Cited by 95 · see citing works
Shape memory polymer nanocomposite: a review on structure–property relationship
Bhanushali, H., Amrutkar, S. Y., Mestry, S. U., & Mhaske, S. T. (2021) · Polymer Bulletin · doi:10.1007/s00289-021-03686-x · Cited by 96 · see citing works
Applications of Cellulose Nanocrystals: A Review
Xie, S., Zhang, X., Walcott, M. P., & Lin, H. (2018) · Engineered Science · doi:10.30919/es.1803302 · Cited by 94 · see citing works
Tan, K. W., Heo, S., Foo, M. L., Chew, I. M., & Yoo, C. (2018) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2018.08.402 · Cited by 91 · see citing works
A multi-responsive hydrogel with a triple shape memory effect based on reversible switches
He, X., Lü, W., Le, X., Ma, C., Li, Z., Zheng, J., Zhang, J., Huang, Y., & Chen, T. (2016) · Chemical Communications · doi:10.1039/c6cc06813h · Cited by 90 · see citing works
Stimuli-responsive cellulose nanomaterials for smart applications
Zhu, Q., Liu, S., Sun, J., Liu, J., Kirubaharan, C. J., Chen, H., Xu, W., & Wang, Q. (2020) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2020.115933 · Cited by 91 · see citing works
Xiang, Z., Chu, C., Xie, H. Q., Xiang, T., & Zhou, S. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c18396 · Cited by 90 · see citing works
Bioinspired design toward nanocellulose-based materials
Zhao, X., Bhagia, S., Gomez‐Maldonado, D., Tang, X., Wasti, S., Lu, S., Zhang, S., Parit, M., Rencheck, M. L., Korey, M., et al. (2023) · Materials Today · doi:10.1016/j.mattod.2023.04.010 · Cited by 76 · see citing works
Thermo- and pH-responsive poly(ionic liquid) membranes
Chen, F., Guo, J., Xu, D., & Yan, F. (2016) · Polymer Chemistry · doi:10.1039/c5py01927c · Cited by 76 · see citing works
Recent Progress on Cellulose-Based Electro-Active Paper, Its Hybrid Nanocomposites and Applications
Khan, A., Abas, Z., Kim, H. S., & Kim, J. (2016) · Sensors · doi:10.3390/s16081172 · Cited by 73 · see citing works
Self-healing and shape memory metallopolymers: state-of-the-art and future perspectives
Искаковна, Д. Г., Yadav, B. C., Singh, S., & Uflyand, I. Е. (2020) · Dalton Transactions · doi:10.1039/c9dt04360h · Cited by 71 · see citing works
Wang, Y., Pan, Y. M., Zheng, Z., & Ding, X. (2018) · Macromolecular Rapid Communications · doi:10.1002/marc.201800128 · Cited by 70 · see citing works
Lu, C., Liu, Y., Liu, X., Wang, C., Wang, J., & Chu, F. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b00329 · Cited by 69 · see citing works
A review of shape memory polymers based on the intrinsic structures of their responsive switches
Yang, L., Lou, J., Yuan, J., & Deng, J. (2021) · RSC Advances · doi:10.1039/d1ra04434f · Cited by 68 · see citing works
Applications of Shape Memory Polymers in Kinetic Buildings
Li, J., Duan, Q., Zhang, E., & Wang, J. (2018) · Advances in Materials Science and Engineering · doi:10.1155/2018/7453698 · Cited by 67 · see citing works
pH- and Thermal-Responsive Multishape Memory Hydrogel
Gong, X., Xiao, Y., Pan, M., Kang, Y., Li, B., & Zhang, S. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b09605 · Cited by 67 · see citing works
Supramolecular Polymer Nanocomposites Derived from Plant Oils and Cellulose Nanocrystals
Song, L., Wang, Z., Lamm, M. E., Yuan, L., & Tang, C. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01691 · Cited by 63 · see citing works
Du, B., Yin, H. H., Chen, Y., Lin, W., Wang, Y., Zhao, D., Wang, G., He, X., Li, J., Li, Z., et al. (2020) · Journal of Materials Chemistry B · doi:10.1039/d0tb00656d · Cited by 63 · see citing works
Production, Processes and Modification of Nanocrystalline Cellulose from Agro-Waste: A Review
Ilyas, R. A., Sapuan, S. M., Ibrahim, R., Atikah, M. S. N., Atiqah, A., Ansari, M. N. M., & Norrrahim, M. N. F. (2019) · IntechOpen eBooks · doi:10.5772/intechopen.87001 · Cited by 61 · see citing works
Oberlintner, A., Likozar, B., & Novak, U. (2021) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2021.117742 · Cited by 60 · see citing works
Ansari, M., Golzar, M., Baghani, M., & Soleimani, M. (2018) · Polymer Testing · doi:10.1016/j.polymertesting.2018.04.032 · Cited by 60 · see citing works
Review of Magnetic Shape Memory Polymers and Magnetic Soft Materials
van Vilsteren, S. J. M., Yarmand, H., & Ghodrat, S. (2021) · Magnetochemistry · doi:10.3390/magnetochemistry7090123 · Cited by 57 · see citing works
Shape memory polymer and composites for space applications: A review
Yadav, A., Singh, S. K., Das, S., Kumar, S., & Kumar, A. (2025) · Polymer Composites · doi:10.1002/pc.29707 · Cited by 59 · see citing works
Noormohammadi, F., Nourany, M., Sadeghi, G. M. M., Wang, P., & Shahsavarani, H. (2020) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2020.117219 · Cited by 54 · see citing works
Polyurethane as smart biocoatings: Effects of hard segments on phase structures and properties
Wang, Y., Wang, L., Liu, H., He, S., Liu, X., Liu, W., Huang, M., & Zhu, C. (2020) · Progress in Organic Coatings · doi:10.1016/j.porgcoat.2020.106000 · Cited by 53 · see citing works
Wu, G., Gu, Y., Hou, X., Li, R., Ke, H., & Xiao, X. (2019) · Polymers · doi:10.3390/polym11101586 · Cited by 53 · see citing works
Bi, H., Ye, G., Yang, H., Sun, H. Y., Ren, Z., Guo, R., Xu, M., Cai, L., & Huang, Z. (2020) · European Polymer Journal · doi:10.1016/j.eurpolymj.2020.109920 · Cited by 54 · see citing works
Application of Shape Memory and Self-Healable Polymers/Composites in the Biomedical Field: A Review
Tadge, T. S., Devidas, S. G., Saxena, V., & Raichur, A. M. (2023) · ACS Omega · doi:10.1021/acsomega.3c04569 · Cited by 52 · see citing works
Polyurethane with an ionic liquid crosslinker: a new class of super shape memory-like polymers
Behera, P. K., Mondal, P., & Singha, N. K. (2018) · Polymer Chemistry · doi:10.1039/c8py00549d · Cited by 51 · see citing works
Recent developments in stimuli-responsive poly(ionic liquid)s
Banerjee, P., Anas, M., Jana, S., & Mandal, T. K. (2020) · Journal of Polymer Research · doi:10.1007/s10965-020-02091-8 · Cited by 48 · see citing works
Bi, H., Ren, Z., Ye, G., Sun, H. Y., Guo, R., Jia, X., & Xu, M. (2020) · Cellulose · doi:10.1007/s10570-020-03328-x · Cited by 48 · see citing works
Updates on polyurethane and its multifunctional applications in biomedical engineering
Miri, Z., Farè, S., Ma, Q., & Haugen, H. J. (2023) · Progress in Biomedical Engineering · doi:10.1088/2516-1091/acef84 · Cited by 47 · see citing works
Yang, J., Zheng, Y., Sheng, L., Chen, H. M., Zhao, L., Yu, W., Zhao, K., & Hu, P. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.8b03230 · Cited by 46 · see citing works
Cao, L., Huang, J., Fan, J., Gong, Z., Xu, C., & Chen, Y. (2021) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1080/15583724.2021.2001004 · Cited by 43 · see citing works
Parameswaranpillai, J., Ramanan, S. P., Jose, S., Siengchin, S., Magueresse, A., Janke, A., & Pionteck, J. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03676 · Cited by 43 · see citing works
Wang, W., Liu, D., Lu, L., Chen, H., Gong, T., Lv, J., & Zhou, S. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta00930a · Cited by 40 · see citing works
Wu, G., Panahi‐Sarmad, M., Vlierberghe, S. V., Xu, R., Hou, X., Cui, Z., & Xiao, X. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.138253 · Cited by 39 · see citing works
Chu, C., Xiang, Z., Wang, J., Xie, H. Q., Xiang, T., & Zhou, S. (2020) · Journal of Materials Chemistry B · doi:10.1039/d0tb01237h · Cited by 37 · see citing works
Nanostructure-Controlled Shape Memory Effect in Polyurethanes
Biswas, A., Aswal, V. K., Ray, B., & Maiti, P. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b02824 · Cited by 38 · see citing works
3D Printed Shape Memory Polymers Produced via Direct Pellet Extrusion
Cersoli, T., Cresanto, A., Herberger, C., MacDonald, E. W., & Cortes, P. (2021) · Micromachines · doi:10.3390/mi12010087 · Cited by 38 · see citing works
Idumah, C. I., Odera, R. S., Ezeani, E. O., Low, J. H., Tanjung, F. A., Damiri, F., & Luing, W. S. (2023) · Polymer-Plastics Technology and Materials · doi:10.1080/25740881.2023.2204936 · Cited by 39 · see citing works
A Multiple Shape Memory Hydrogel Induced by Reversible Physical Interactions at Ambient Condition
Xiao, H., Ma, C., Le, X., Wang, L., Lü, W., Théato, P., Hu, T., Zhang, J., & Chen, T. (2017) · Polymers · doi:10.3390/polym9040138 · Cited by 37 · see citing works
PEG-ran-PPG Modified Epoxy Thermosets: A Simple Approach To Develop Tough Shape Memory Polymers
Parameswaranpillai, J., Ramanan, S. P., George, J. J., Jose, S., Zachariah, A. K., Siengchin, S., Yorseng, K., Janke, A., & Pionteck, J. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b04872 · Cited by 37 · see citing works
Lü, Y., Zhang, P., Fan, M., Jiang, P., Bao, Y., Gao, X., & Xia, J. (2019) · Polymer · doi:10.1016/j.polymer.2019.121832 · Cited by 37 · see citing works
Three-dimensional graphene coated shape memory polyurethane foam with fast responsive performance
Wang, T., Zhao, J., Weng, C., Wang, T., Liu, Y., Han, Z., & Zhang, Z. (2021) · Journal of Materials Chemistry C · doi:10.1039/d1tc01315g · Cited by 36 · see citing works
Gupta, A., & Mekonnen, T. H. (2021) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2021.11.174 · Cited by 37 · see citing works
Wu, X., Han, Y., Zhou, Z., Zhang, X., & Lu, C. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02238 · Cited by 36 · see citing works
Conductive shape‐memory polyurethane/multiwall carbon nanotube nanocomposite aerogels
Teymouri, M., Kokabi, M., & Alamdarnejad, G. (2019) · Journal of Applied Polymer Science · doi:10.1002/app.48602 · Cited by 36 · see citing works
A Mini-Review of Shape-Memory Polymer-Based Materials
Haskew, M. J., & Hardy, J. G. (2019) · Johnson Matthey Technology Review · doi:10.1595/205651319x15754757916993 · Cited by 36 · see citing works
Zhao, L.-M., Gong, M., Wang, R., Yuan, Q., Zhang, Y., Pi, J.-K., Lv, X., Xie, Y., & Xie, H. (2021) · Regenerative Biomaterials · doi:10.1093/rb/rbaa056 · Cited by 36 · see citing works
Vyas, J., Shah, I. T., Singh, S. K., & Prajapati, B. G. (2023) · Frontiers in Bioengineering and Biotechnology · doi:10.3389/fbioe.2023.1234340 · Cited by 35 · see citing works
A Tailorable Series of Elastomeric‐To‐Rigid, Selfhealable, Shape Memory Bismaleimide
Li, Y., Zhang, F., Liu, Y., & Leng, J. (2023) · Small · doi:10.1002/smll.202307244 · Cited by 35 · see citing works
Guo, X., Sheng, P., Hu, J., Liu, J., Wang, S.-L., Ma, Q., Yu, Z., & Ding, Y. H. (2024) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.4c00569 · Cited by 35 · see citing works
Mechanical, Thermal, and Shape Memory Properties of Three-Dimensional Printing Biomass Composites
Bi, H., Xu, M., Ye, G., Guo, R., Cai, L., & Ren, Z. (2018) · Polymers · doi:10.3390/polym10111234 · Cited by 34 · see citing works
Shape memory behavior of unidirectional pultruded laminate
Korotkov, R. F., Vedernikov, A., Gusev, S., Alajarmeh, O., Akhatov, I., & Safonov, A. A. (2021) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2021.106609 · Cited by 35 · see citing works
Luminescent two-way reversible shape memory polymers prepared by hydroxyl–yne click polymerization
Wang, K., Si, H., Wan, Q., Wang, Z., Qin, A., & Tang, B. Z. (2020) · Journal of Materials Chemistry C · doi:10.1039/d0tc03888a · Cited by 34 · see citing works
Nanocellulose-Based Thermoplastic Polyurethane Biocomposites with Shape Memory Effect
Gorbunova, М. А., Grunin, L. Y., Morris, R. H., & Imamutdinova, A. M. (2023) · Journal of Composites Science · doi:10.3390/jcs7040168 · Cited by 35 · see citing works
Photoresponsive Movement in 3D Printed Cellulose Nanocomposites
Müller, L., Demongeot, A., Vaucher, J., Leterrier, Y., Avaro, J. T., Liebi, M., Neels, A., Burgert, I., Zimmermann, T., Nyström, G., et al. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c02154 · Cited by 33 · see citing works
Direct‐Ink Written Shape‐Morphing Film with Rapid and Programmable Multimotion
Mao, Z., Zhu, K., Pan, L., Liu, G., Tang, T., He, Y., Huang, J., Hu, J., Chan, K. W. Y., & Lü, J. (2020) · Advanced Materials Technologies · doi:10.1002/admt.201900974 · Cited by 32 · see citing works
Ganeson, K., May, C., Abdullah, A. A., Ramakrishna, S., & Vigneswari, S. (2023) · Pharmaceutics · doi:10.3390/pharmaceutics15092356 · Cited by 31 · see citing works
Facile fabrication of a CD/PVA composite polymer to access light-responsive shape-memory effects
Wu, S., Li, W., Sun, Y., Pang, X., Zhang, X., Zhuang, J., Zhang, H., Hu, C., Lei, B., & Liu, Y. (2020) · Journal of Materials Chemistry C · doi:10.1039/d0tc00910e · Cited by 31 · see citing works
Next-Generation Smart Carbon–Polymer Nanocomposites: Advances in Sensing and Actuation Technologies
Mubasshira, Rahman, M. M., Uddin, M. N., Rhaman, M., Roy, S., & Sarker, M. S. (2025) · Processes · doi:10.3390/pr13092991 · Cited by 30 · see citing works
Mo, K., Zhang, T., Yan, W., & Chang, C. (2018) · Cellulose · doi:10.1007/s10570-018-2025-7 · Cited by 30 · see citing works
Cai, C., Wei, Z., Huang, Y., Wang, P., Song, J., Deng, L., & Fu, Y. (2020) · Composites Science and Technology · doi:10.1016/j.compscitech.2020.108524 · Cited by 28 · see citing works
Tailored nanocellulose-grafted polymer brush applications
Geurds, L., Lauko, J., Rowan, A. E., & Amiralian, N. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta03264j · Cited by 30 · see citing works
Magnetically Actuated Shape Memory Polymers for On-Demand Drug Delivery
Vakil, A. U., Ramezani, M., & Monroe, M. B. B. (2022) · Materials · doi:10.3390/ma15207279 · Cited by 30 · see citing works
Li, X., Liu, W., Li, Y., Lan, W., Zhao, D., Wu, H., Feng, Y. P., He, X., Li, Z., Li, J., et al. (2020) · Journal of Materials Chemistry B · doi:10.1039/d0tb00798f · Cited by 29 · see citing works
Foo, M. L., Ooi, C. W., Tan, K. W., & Chew, I. M. L. (2020) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2020.104058 · Cited by 29 · see citing works
Rotini‐like MXene@LCE Actuator with Diverse and Programmable Actuation Based on Dual‐mode Synergy
Liang, Z., Jin, B., Zhao, H., He, Z., Jiang, Z., & Jiang, S. (2023) · Small · doi:10.1002/smll.202305371 · Cited by 29 · see citing works
Zhang, Q., Wei, H., Liu, Y., Leng, J., & Du, S. (2016) · RSC Advances · doi:10.1039/c5ra24247a · Cited by 28 · see citing works
Self-citationZhang, Z.-X., Qi, X., Li, S.-T., Yang, J., Zhang, N., Huang, T. K., & Wang, Y. (2017) · European Polymer Journal · doi:10.1016/j.eurpolymj.2017.11.031 · Cited by 27 · see citing works
Mehrbakhsh, E., Rezaei, M., Babaie, A., Mohammadi, A., & Sofla, R. L. M. (2021) · Journal of the mechanical behavior of biomedical materials/Journal of mechanical behavior of biomedical materials · doi:10.1016/j.jmbbm.2021.104336 · Cited by 28 · see citing works
Idumah, C. I. (2023) · Polymer Engineering and Science · doi:10.1002/pen.26331 · Cited by 28 · see citing works
Zhang, Y., Li, W., Wu, R., & Wang, W. (2017) · RSC Advances · doi:10.1039/c7ra05206e · Cited by 27 · see citing works
Fang, H., Chen, X., Wang, S., Cheng, S., & Ding, Y. (2019) · Cellulose · doi:10.1007/s10570-019-02742-0 · Cited by 27 · see citing works
Mondal, P., Behera, P. K., Voit, B. I., Böhme, F., & Singha, N. K. (2020) · Macromolecular Materials and Engineering · doi:10.1002/mame.202000142 · Cited by 26 · see citing works
Li, Y., Zhang, F., Liu, Y., & Leng, J. (2024) · Chemical Engineering Journal · doi:10.1016/j.cej.2024.152196 · Cited by 25 · see citing works
Li, W., Jiang, X. F., Wu, R., & Wang, W. (2016) · Polymer Journal · doi:10.1038/pj.2016.98 · Cited by 25 · see citing works
Eco-friendly biodegradable polyurethane based coating for antibacterial and antifouling performance
Ali, A., Amin, B. U., Yu, W., Gui, T., Cong, W., Zhang, K., Tong, Z., Hu, J., Zhan, X., & Zhang, Q. (2022) · Chinese Journal of Chemical Engineering · doi:10.1016/j.cjche.2022.09.004 · Cited by 24 · see citing works
Reconfigurable scaffolds for adaptive tissue regeneration
Peng, M., Zhao, Q., Wang, M., & Du, X. (2023) · Nanoscale · doi:10.1039/d3nr00281k · Cited by 24 · see citing works
Reprocessable and Multiple Shape Memory Thermosets with Reconfigurability
Wang, Y., Pan, Y. M., Zheng, Z., & Ding, X. (2019) · Macromolecular Rapid Communications · doi:10.1002/marc.201900001 · Cited by 24 · see citing works
Classification of Shape-Memory Polymers, Polymer Blends, and Composites
Strzelec, K., Sienkiewicz, N., & Szmechtyk, T. (2019) · Advanced structured materials · doi:10.1007/978-981-13-8574-2_2 · Cited by 22 · see citing works
- Authors
- Li, Y., Chen, H., Liu, D., Wang, W., Liu, Y., & Zhou, S.
- Affiliations
- Southwest Jiaotong University (CN)
- Corresponding author
- Zhou, Shaobing
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-02
- Volume
- 7
- Issue
- 23
- Pages
- 12988-12999
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2462962971
- Cited by
- 206
- References
- 60
- Citations by year
- 2026: 13 · 2025: 18 · 2024: 15 · 2023: 19 · 2022: 19 · 2021: 26 · 2020: 33 · 2019: 20 · 2018: 18 · 2017: 11 · 2016: 13 · 2015: 1
- FWCI
- 14.08
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Applied Materials & Interfaces (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Ministry of Education of the People's Republic of China (20120184110029)
- Ministry of Science and Technology of the People's Republic of China (2012BAI17B06, 2012CB933600)
- National Natural Science Foundation of China (51173150, 51373138)
- Sichuan Province (14TD0050)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Keywords
- cellulose nanocrystals, pyridine functionalization, hydrogen bonding, carboxyl functionalization, TEMPO-mediated oxidation, percolation network, mechanical properties, stimuli-responsive polymers
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
