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Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators
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Abstract The electrochemical instability of semiconductors in aqueous electrolytes has impeded the development of robust sunlight-driven water-splitting systems. We review the use of protective thin films to improve the electrochemical stability of otherwise unstable semiconductor photoelectrodes (e.g., Si and GaAs). We first discuss the origins of instability and various strategies for achieving stable and functional photoelectrosynthetic interfaces. We then focus specifically on the use of thin protective films on photoanodes and photocathodes for photosynthetic reactions that include oxygen evolution, halide oxidation, and hydrogen evolution. Finally, we provide an outlook for the future development of thin-layer protection strategies to enable semiconductor-based solar-driven fuel production.
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Self-citationPHOTO-ELECTROCHEMICAL BEHAVIORS OF SEMICONDUCTOR ELECTRODES COATED WITH THIN METAL FILMS
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Metadata
- Authors
- Hu, S., Lewis, N. S., Ager, J. W., Yang, J., McKone, J. R., & Strandwitz, N. C.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-19
- Volume
- 119
- Issue
- 43
- Pages
- 24201-24228
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1868286378
- Cited by
- 290
- References
- 134
- FWCI
- 10.07
- Type
- journal article
- Language
- en
- Open access
- hybrid
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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Data sources
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.