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Cited by 502

The DOI matches its Crossref record; 88 of the 88 references it cites were found in a registry or an index.

50th Anniversary Perspective: A Perspective on Polyelectrolyte Solutions

Open access
Muthukumar, M.·2017·Macromolecules
DOI 10.1021/acs.macromol.7b01929
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Abstract

From the beginning of life with the information-containing polymers until the present era of a plethora of water-based materials in health care industry and biotechnology, polyelectrolytes are ubiquitous with a broad range of structural and functional properties. The main attribute of polyelectrolyte solutions is that all molecules are strongly correlated both topologically and electrostatically in their neutralizing background of charged ions in highly polarizable solvent. These strong correlations and the necessary use of numerous variables in experiments on polyelectrolytes have presented immense challenges toward fundamental understanding of the various behaviors of charged polymeric systems. This Perspective presents the author's subjective summary of several conceptual advances and the remaining persistent challenges in the contexts of charge and size of polymers, structures in homogeneous solutions, thermodynamic instability and phase transitions, structural evolution with oppositely charged polymers, dynamics in polyelectrolyte solutions, kinetics of phase separation, mobility of charged macromolecules between compartments, and implications to biological systems.

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Metadata

Authors
Muthukumar, M.
Venue
Macromolecules
Publisher
American Chemical Society (ACS)
Published
2017-12-14
Volume
50
Issue
24
Pages
9528-9560
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
DOI
10.1021/acs.macromol.7b01929
OpenAlex
W2772283214
Cited by
502
References
88
FWCI
25.38
Type
journal article
Language
en
Open access
hybrid

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

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