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Cited by 481

The DOI matches its Crossref record; 235 of the 235 references it cites were found in a registry or an index.

Dehydrogenation of Ammonia Borane by Metal Nanoparticle Catalysts

Zhan, Wen-Wen, Zhu, Qi-Long, Xu, Qiang·2016·ACS Catalysis

Abstract

Ammonia borane (AB), having a high hydrogen density of 19.6 wt %, has attracted much attention as a promising chemical hydrogen storage material. In the past few years, a number of highly active metal nanoparticle (NP) catalysts, which are easy to handle and separate, have been developed for AB dehydrogenation. In this Perspective, we summarize new progress in the development of metal NP catalysts, which are categorized into monometallic and heterometallic catalysts, with excellent activity and high recyclability for different AB dehydrogenation pathways, including solvolysis (hydrolysis and methanolysis) in protic solvents and dehydrocoupling in nonprotic solvents, and we survey the corresponding methods for the regeneration of AB. Moreover, the merits and drawbacks of solvolysis and dehydrocoupling are discussed.

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Crossref · 10.1021/acscatal.6b02209

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Metadata

Authors
Zhan, W.-W., Zhu, Q.-L., & Xu, Q.
Venue
ACS Catalysis
Published
2016-09-15
Volume
6
Issue
10
Pages
6892-6905
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2507423338
Cited by
481
References
235
FWCI
26.92
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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