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Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?
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Engineering the shape and size of catalyst particles and the interface between different components of heterogeneous catalysts at the nanometer level can radically alter their performances. This is particularly true with CeO 2 -based catalysts, where the precise control of surface atomic arrangements can modify the reactivity of Ce 4+ /Ce 3+ ions, changing the oxygen release/uptake characteristics of ceria, which, in turn, strongly affects catalytic performance in several reactions like CO, soot, and VOC oxidation, WGS, hydrogenation, acid–base reactions, and so on. Despite the fact that many of these catalysts are polycrystalline with rather ill-defined morphologies, experimental and theoretical studies on well-defined nanocrystals have clearly established that the exposure of specific facets can increase/decrease surface oxygen reactivity and metal–support interaction (for supported metal nanoparticles), consequently affecting catalytic reactions. Here, we want to address the most recent developments in this area, showing that shape (and size) modification, surface/face reconstruction, and faceting of ceria at the nanoscale level can offer an important tool to govern activity and stability in several reactions and imagine how this could contribute to future developments.
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Metadata
- Authors
- Trovarelli, A., & Llorca, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-16
- Volume
- 7
- Issue
- 7
- Pages
- 4716-4735
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2623795207
- Cited by
- 781
- References
- 115
- FWCI
- 30.04
- Type
- journal article
- Language
- en
- Open access
- green
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.