Remarkable Stereocontrol in the Polymerization of Racemic Lactide Using Aluminum Initiators Supported by Tetradentate Aminophenoxide Ligands

Stereochemistry of Lactide Polymerization with Chiral Catalysts: New Opportunities for Stereocontrol Using Polymer Exchange Mechanisms

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Stereoselective Ring-Opening Polymerization of meso-Lactide: Synthesis of Syndiotactic Poly(lactic acid)

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Stereoselective Polymerization of a Racemic Monomer with a Racemic Catalyst: Direct Preparation of the Polylactic Acid Stereocomplex from Racemic Lactide

Radano, C. P., Baker, G. L., & Smith, M. R. (2000) · Journal of the American Chemical Society · doi:10.1021/ja9930519 · Cited by 403

Controlled Ring-Opening Polymerization of Lactide and Glycolide

Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257

Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures

Thomas, C. M. (2010) · Chem. Soc. Rev. · doi:10.1039/b810065a · Cited by 853

Recent developments in main group metal complexes catalyzed/initiated polymerization of lactides and related cyclic esters

WU, J., YU, T., CHEN, C., & LIN, C. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.07.010 · Cited by 779

Biocompatible Initiators for Lactide Polymerization

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Synthesis of Poly(Lactic Acid): A Review

Mehta, R., Kumar, V., Bhunia, H., & Upadhyay, S. N. (2005) · Journal of Macromolecular Science, Part C: Polymer Reviews · doi:10.1080/15321790500304148 · Cited by 510

Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization

Wheaton, C. A., Hayes, P. G., & Ireland, B. J. (2009) · Dalton Transactions · doi:10.1039/b819107g · Cited by 438

A circular economy approach to plastic waste

Payne, J., McKeown, P., & Jones, M. D. (2019) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2019.05.014 · Cited by 385

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring‐Opening Polymerization of Cyclic Esters

Guillaume, S. M., Kirillov, E., Sarazin, Y., & Carpentier, J. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500613 · Cited by 251

Yttrium Phosphasalen Initiators for rac-Lactide Polymerization: Excellent Rates and High Iso-Selectivities

Bakewell, C., Cao, T.-P.-A., Long, N., Le Goff, X. F., Auffrant, A., & Williams, C. K. (2012) · Journal of the American Chemical Society · doi:10.1021/ja310003v · Cited by 226

Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and β-Butyrolactone with Amino-alkoxy-bis(phenolate)–Yttrium Complexes

Bouyahyi, M., Ajellal, N., Kirillov, E., Thomas, C. M., & Carpentier, J. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201002779 · Cited by 217

Yttrium complexes as catalysts for living and immortal polymerization of lactide to highly heterotactic PLA

Amgoune, A., Thomas, C. M., & Carpentier, J. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200600862 · Cited by 195

Metal‐Size Influence in Iso‐Selective Lactide Polymerization

Bakewell, C., White, A. J. P., Long, N. J., & Williams, C. K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403643 · Cited by 178

Ring-Opening Polymerization of rac-Lactide by Bis(phenolate)amine-Supported Samarium Borohydride Complexes: An Experimental and DFT Study

Dyer, H. E., Huijser, S., Susperregui, N., Bonnet, F., Schwarz, A. D., Duchateau, R., Maron, L., & Mountford, P. (2010) · Organometallics · doi:10.1021/om100513j · Cited by 158

Synthesis, Characterization, and Metal Coordinating Ability of Multifunctional Carbohydrate-Containing Compounds for Alzheimer's Therapy

Storr, T., Merkel, M., Song-Zhao, G. X., Scott, L. E., Green, D. E., Bowen, M. L., Thompson, K. H., Patrick, B. O., Schugar, H. J., & Orvig, C. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068965r · Cited by 156

Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters

Wei, Y., Wang, S., & Zhou, S. (2016) · Dalton Transactions · doi:10.1039/c5dt04240b · Cited by 122

Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide

Wang, H., & Ma, H. (2013) · Chemical Communications · doi:10.1039/c3cc44980g · Cited by 120

Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac -lactide

Jones, M. D., Hancock, S. L., McKeown, P., Schäfer, P. M., Buchard, A., Thomas, L. H., Mahon, M. F., & Lowe, J. P. (2014) · Chem. Commun. · doi:10.1039/c4cc07871c · Cited by 109

Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System

Robert, C., Schmid, T. E., Richard, V., Haquette, P., Raman, S. K., Rager, M.-N., Gauvin, R. M., Morin, Y., Trivelli, X., Guérineau, V., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01749 · Cited by 101

Breaking the Paradox between Catalytic Activity and Stereoselectivity: rac-Lactide Polymerization by Trinuclear Salen–Al Complexes

Pang, X., Duan, R., Li, X., Hu, C., Wang, X., & Chen, X. (2018) · Macromolecules · doi:10.1021/acs.macromol.7b02662 · Cited by 100

Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

Ligny, R., Hänninen, M. M., Guillaume, S. M., & Carpentier, J.-F. (2018) · Chemical Communications · doi:10.1039/c8cc03842b · Cited by 88

Roles of Monomer Binding and Alkoxide Nucleophilicity in Aluminum-Catalyzed Polymerization of ε - Caprolactone

Ding, K., Miranda, M. O., Moscato-Goodpaster, B., Ajellal, N., Breyfogle, L. E., Hermes, E. D., Schaller, C. P., Roe, S. E., Cramer, C. J., Hillmyer, M. A., et al. (2012) · Macromolecules · doi:10.1021/ma301130b · Cited by 87

Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Functional Racemic β-Lactones

Ligny, R., Hänninen, M. M., Guillaume, S. M., & Carpentier, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704283 · Cited by 77

Redox Control of Aluminum Ring-Opening Polymerization: A Combined Experimental and DFT Investigation

Wei, J., Riffel, M. N., & Diaconescu, P. L. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02402 · Cited by 76

Discrete Divalent Rare-Earth Cationic ROP Catalysts: Ligand-Dependent Redox Behavior and Discrepancies with Alkaline-Earth Analogues in a Ligand-Assisted Activated Monomer Mechanism

Liu, B., Roisnel, T., Maron, L., Carpentier, J., & Sarazin, Y. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201204340 · Cited by 74

Polymerization of rac‐Lactide Using Achiral Iron Complexes: Access to Thermally Stable Stereocomplexes

Marin, P., Tschan, M. J. ‐., Isnard, F., Robert, C., Haquette, P., Trivelli, X., Chamoreau, L., Guérineau, V., del Rosal, I., Maron, L., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201903224 · Cited by 74

Bimetallic salen aluminum complexes: cooperation between reactive centers in the ring-opening polymerization of lactides and epoxides

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Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations

Wang, L., Kefalidis, C. E., Sinbandhit, S., Dorcet, V., Carpentier, J., Maron, L., & Sarazin, Y. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201301751 · Cited by 65

Bis(pyrrolidene) Schiff Base Aluminum Complexes as Isoselective-Biased Initiators for the Controlled Ring-Opening Polymerization of rac-Lactide: Experimental and Theoretical Studies

Tabthong, S., Nanok, T., Sumrit, P., Kongsaeree, P., Prabpai, S., Chuawong, P., & Hormnirun, P. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01381 · Cited by 64

Comparative Study of Aluminum Complexes Bearing N,O- and N,S-Schiff Base in Ring-Opening Polymerization of ε-Caprolactone and l-Lactide

Chang, M.-C., Lu, W.-Y., Chang, H.-Y., Lai, Y.-C., Chiang, M. Y., Chen, H.-Y., & Chen, H.-Y. (2015) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5b01858 · Cited by 61

Well-defined sterically hindered zinc aryloxides: Excellent catalysts for ring-opening polymerization of ɛ-caprolactone and l-lactide

Huang, B.-H., Lin, C.-N., Hsueh, M.-L., Athar, T., & Lin, C.-C. (2006) · Polymer · doi:10.1016/j.polymer.2006.07.015 · Cited by 61

A closer look at ε-caprolactone polymerization catalyzed by alkyl aluminum complexes: the effect of induction period on overall catalytic activity

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Synthesis and structural characterization of well-defined anionic aluminium alkoxide complexes supported by NON-type diamido ether tridentate ligands and their use for the controlled ROP of lactide

Hild, F., Haquette, P., Brelot, L., & Dagorne, S. (2010) · Dalton Trans. · doi:10.1039/b911802k · Cited by 51

Exploring Steric Effects in Diastereoselective Synthesis of Chiral Aminophenolate Zinc Complexes and Stereoselective Ring-Opening Polymerization of rac-Lactide

Wang, H., Yang, Y., & Ma, H. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b00378 · Cited by 50

Bimetallic aluminum complexes with cyclic β-ketiminato ligands: the cooperative effect improves their capability in polymerization of lactide and ε-caprolactone

Huang, H.-C., Wang, B., Zhang, Y.-P., & Li, Y.-S. (2016) · Polymer Chemistry · doi:10.1039/c6py01092j · Cited by 49

Synergistic Empirical and Theoretical Study on the Stereoselective Mechanism for the Aluminum Salalen Complex Mediated Polymerization of rac‐Lactide

Vieira, I. D. S., Whitelaw, E. L., Jones, M. D., & Herres‐Pawlis, S. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201203973 · Cited by 47

Mechanism of the Polymerization of rac-Lactide by Fast Zinc Alkoxide Catalysts

Stasiw, D. E., Luke, A. M., Rosen, T., League, A. B., Mandal, M., Neisen, B. D., Cramer, C. J., Kol, M., & Tolman, W. B. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b02544 · Cited by 46

Tuning the Thiolen: Al(III) and Fe(III) Thiolen Complexes for the Isoselective ROP of rac-Lactide

Stewart, J. A., McKeown, P., Driscoll, O. J., Mahon, M. F., Ward, B. D., & Jones, M. D. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01205 · Cited by 40

Ring-opening polymerization and copolymerization of cyclic esters catalyzed by amidinate aluminum complexes

Osorio Meléndez, D., Castro‐Osma, J. A., Lara‐Sánchez, A., Rojas, R. S., & Otero, A. (2017) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.28629 · Cited by 38

Highly Stereocontrolled Ring-Opening Polymerization of Racemic Alkyl β-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes

Jaffredo, C. G., Chapurina, Y., Kirillov, E., Carpentier, J., & Guillaume, S. M. (2016) · Chemistry – A European Journal · doi:10.1002/chem.201600223 · Cited by 37

Iron(III) Salalen Complexes for the Polymerisation of Lactide

Driscoll, O. J., Leung, C. K. C., Mahon, M. F., McKeown, P., & Jones, M. D. (2018) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201801239 · Cited by 32

Aluminium complexes containing salicylbenzothiazole ligands and their application in the ring-opening polymerisation of rac-lactide and ε-caprolactone

Nakonkhet, C., Nanok, T., Wattanathana, W., Chuawong, P., & Hormnirun, P. (2017) · Dalton Transactions · doi:10.1039/c7dt02435e · Cited by 31

Selective Transesterification to Control Copolymer Microstructure in the Ring-Opening Copolymerization of Lactide and ε-Caprolactone by Lanthanum Complexes

Beament, B., Britton, D., Malcomson, T., Akien, G. R., Halcovitch, N. R., Coogan, M. P., & Platel, R. H. (2024) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03120 · Cited by 27

Enhanced Catalytic Activity of Aluminum Complexes for the Ring-Opening Polymerization of ε-Caprolactone

Kosuru, S. R., Sun, T.-H., Wang, L.-F., Vandavasi, J. K., Lu, W.-Y., Lai, Y.-C., Hsu, S. C. N., Chiang, M. Y., & Chen, H.-Y. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b00763 · Cited by 26

Titanium complexes containing bidentate benzotriazole ligands as catalysts for the ring opening polymerization of lactide

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Zirconium amine tris(phenolate): A more effective initiator for biomedical lactide

Jones, M. D., Wu, X., Chaudhuri, J., Davidson, M. G., & Ellis, M. J. (2017) · Materials Science and Engineering: C · doi:10.1016/j.msec.2017.03.242 · Cited by 23

Investigation of the dinuclear effect of aluminum complexes in the ring-opening polymerization of ε-caprolactone

Hsu, C.-Y., Tseng, H.-C., Vandavasi, J. K., Lu, W.-Y., Wang, L.-F., Chiang, M. Y., Lai, Y.-C., Chen, H.-Y., & Chen, H.-Y. (2017) · RSC Advances · doi:10.1039/c7ra02136d · Cited by 20

Mechanistic Insight into the Ring-Opening Polymerization of ε-Caprolactone and L-Lactide Using Ketiminate-Ligated Aluminum Catalysts

Lin, Y.-F., & Jheng, N.-Y. (2019) · Polymers · doi:10.3390/polym11091530 · Cited by 11