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Metal-Free Photocatalyst for H2 Evolution in Visible to Near-Infrared Region: Black Phosphorus/Graphitic Carbon Nitride
Abstract
In the drive toward green and sustainable chemistry, exploring efficient and stable metal-free photocatalysts with broadband solar absorption from the UV to near-infrared region for the photoreduction of water to H 2 remains a big challenge. To this end, a binary nanohybrid (BP/CN) of two-dimensional (2D) black phosphorus (BP) and graphitic carbon nitride (CN) was designed and used as a metal-free photocatalyst for the first time. During irradiation of BP/CN in water with >420 and >780 nm light, solid H 2 gas was generated, respectively. Owing to the interfacial interaction between BP and CN, efficient charge transfer occurred, thereby enhancing the photocatalytic performance. The efficient charge-trapping and transfer processes were thoroughly investigated with time-resolved diffuse reflectance spectroscopic measurement. The present results show that BP/CN is a metal-free photocatalyst for artificial photosynthesis and renewable energy conversion.
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Self-citation
Metadata
- Authors
- Zhu, M., Kim, S., Mao, L., Fujitsuka, M., Zhang, J., Wang, X., & Majima, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-09-08
- Volume
- 139
- Issue
- 37
- Pages
- 13234-13242
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2752901269
- Cited by
- 1,040
- References
- 49
- FWCI
- 35.65
- Type
- journal article
- Language
- en
- Open access
- closed
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