The DOI matches its Crossref record; 54 of the 54 references it cites were found in a registry or an index.
Selective CO2 Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation
Open accessAbstract
Framework nitrogen atoms of carbon nitride (C 3 N 4 ) can coordinate with and activate metal sites for catalysis. In this study, C 3 N 4 was employed to harvest visible light and activate Co 2+ sites, without the use of additional ligands, in photochemical CO 2 reduction. Photocatalysts containing single Co 2+ sites on C 3 N 4 were prepared by a simple deposition method and demonstrated excellent activity and product selectivity toward CO formation. A turnover number of more than 200 was obtained for CO production using the synthesized photocatalyst under visible-light irradiation. Inactive cobalt oxides formed at relatively high cobalt loadings but did not alter product selectivity. Further studies with X-ray absorption spectroscopy confirmed the presence of single Co 2+ sites on C 3 N 4 and their important role in achieving selective CO 2 reduction.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
White, J. L., Baruch, M. F., Pander, J. E., Hu, Y., Fortmeyer, I. C., Park, J. E., Zhang, T., Liao, K., Gu, J., Yan, Y., et al. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00370 · Cited by 1,673
Wang, C., Xie, Z., deKrafft, K. E., & Lin, W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203564w · Cited by 1,547
Metal‐Containing Carbon Nitride Compounds: A New Functional Organic–Metal Hybrid Material
Wang, X., Chen, X., Thomas, A., Fu, X., & Antonietti, M. (2009) · Advanced Materials · doi:10.1002/adma.200802627 · Cited by 1,333
Zheng, Y., Jiao, Y., Zhu, Y., Cai, Q., Vasileff, A., Li, L. H., Han, Y., Chen, Y., & Qiao, S.-Z. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13100 · Cited by 1,250
Pan, Y., Lin, R., Chen, Y., Liu, S., Zhu, W., Cao, X., Chen, W., Wu, K., Cheong, W.-C., Wang, Y., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00814 · Cited by 1,242
Ju, W., Bagger, A., Hao, G.-P., Varela, A. S., Sinev, I., Bon, V., Roldan Cuenya, B., Kaskel, S., Rossmeisl, J., & Strasser, P. (2017) · Nature Communications · doi:10.1038/s41467-017-01035-z · Cited by 1,203
Gao, G., Jiao, Y., Waclawik, E. R., & Du, A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b02692 · Cited by 1,196
Photochemical and Photoelectrochemical Reduction of CO2
Kumar, B., Llorente, M., Froehlich, J., Dang, T., Sathrum, A., & Kubiak, C. P. (2012) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-032511-143759 · Cited by 1,089
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Exclusive Ni–N4 Sites Realize Near-Unity CO Selectivity for Electrochemical CO2 Reduction
Li, X., Bi, W., Chen, M., Sun, Y., Ju, H., Yan, W., Zhu, J., Wu, X., Chu, W., Wu, C., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b09074 · Cited by 932
Zhang, X., Wu, Z., Zhang, X., Li, L., Li, Y., Xu, H., Li, X., Yu, X., Zhang, Z., Liang, Y., et al. (2017) · Nature Communications · doi:10.1038/ncomms14675 · Cited by 898
A direct Z-scheme g-C3N4/SnS2 photocatalyst with superior visible-light CO2 reduction performance
Di, T., Zhu, B., Cheng, B., Yu, J., & Xu, J. (2017) · Journal of Catalysis · doi:10.1016/j.jcat.2017.06.006 · Cited by 862
Che, W., Cheng, W., Yao, T., Tang, F., Liu, W., Su, H., Huang, Y., Liu, Q., Liu, J., Hu, F., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11878 · Cited by 777
Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO2electroreduction
Yan, C., Li, H., Ye, Y., Wu, H., Cai, F., Si, R., Xiao, J., Miao, S., Xie, S., Yang, F., et al. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00133b · Cited by 768
Shi, H., Chen, G., Zhang, C., & Zou, Z. (2014) · ACS Catalysis · doi:10.1021/cs500848f · Cited by 650
Recent advances in hybrid photocatalysts for solar fuel production
Tran, P. D., Wong, L. H., Barber, J., & Loo, J. S. C. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02849b · Cited by 613
Weng, Z., Jiang, J., Wu, Y., Wu, Z., Guo, X., Materna, K. L., Liu, W., Batista, V. S., Brudvig, G. W., & Wang, H. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04746 · Cited by 567
Kuehnel, M. F., Orchard, K. L., Dalle, K. E., & Reisner, E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00369 · Cited by 535
Pan, F., Zhang, H., Liu, K., Cullen, D., More, K., Wang, M., Feng, Z., Wang, G., Wu, G., & Li, Y. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00398 · Cited by 512
Kuriki, R., Matsunaga, H., Nakashima, T., Wada, K., Yamakata, A., Ishitani, O., & Maeda, K. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01997 · Cited by 482
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie · doi:10.1002/ange.201311111 · Cited by 425
Photochemical Reduction of CO2 by Graphitic Carbon Nitride Polymers
Lin, J., Pan, Z., & Wang, X. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc4004295 · Cited by 409
Sato, S., Morikawa, T., Saeki, S., Kajino, T., & Motohiro, T. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000613 · Cited by 366
Cao, Y., Chen, S., Luo, Q., Yan, H., Lin, Y., Liu, W., Cao, L., Lu, J., Yang, J., Yao, T., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706467 · Cited by 359
Bi, W., Li, X., You, R., Chen, M., Yuan, R., Huang, W., Wu, X., Chu, W., Wu, C., & Xie, Y. (2018) · Advanced Materials · doi:10.1002/adma.201706617 · Cited by 356
Reaction Pathway for Oxygen Reduction on FeN4 Embedded Graphene
Kattel, S., & Wang, G. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz402717r · Cited by 351
Pan, F., Deng, W., Justiniano, C., & Li, Y. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.01.001 · Cited by 340
Mao, Z., Chen, J., Yang, Y., Wang, D., Bie, L., & Fahlman, B. D. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b00370 · Cited by 329
Zhang, G., Huang, C., & Wang, X. (2015) · Small · doi:10.1002/smll.201402636 · Cited by 328
Covalent Immobilization of a Molecular Catalyst on Cu2O Photocathodes for CO2 Reduction
Schreier, M., Luo, J., Gao, P., Moehl, T., Mayer, M. T., & Grätzel, M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12157 · Cited by 318
Kattel, S., & Wang, G. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta12142a · Cited by 276
Polymer coordination promotes selective CO2reduction by cobalt phthalocyanine
Kramer, W. W., & McCrory, C. C. L. (2016) · Chemical Science · doi:10.1039/c5sc04015a · Cited by 263
Cobalt-doped graphitic carbon nitride photocatalysts with high activity for hydrogen evolution
Chen, P.-W., Li, K., Yu, Y.-X., & Zhang, W.-D. (2017) · Applied Surface Science · doi:10.1016/j.apsusc.2016.09.086 · Cited by 256
Reuillard, B., Ly, K. H., Rosser, T. E., Kuehnel, M. F., Zebger, I., & Reisner, E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06269 · Cited by 246
Matsuoka, S., Yamamoto, K., Ogata, T., Kusaba, M., Nakashima, N., Fujita, E., & Yanagida, S. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00055a032 · Cited by 233
Cometto, C., Kuriki, R., Chen, L., Maeda, K., Lau, T.-C., Ishitani, O., & Robert, M. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04007 · Cited by 214
Photocatalytic CO2conversion by polymeric carbon nitrides
Fang, Y., & Wang, X. (2018) · Chemical Communications · doi:10.1039/c8cc02046a · Cited by 174
Ogata, T., Yanagida, S., Brunschwig, B. S., & Fujita, E. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00130a009 · Cited by 173
Windle, C. D., Pastor, E., Reynal, A., Whitwood, A. C., Vaynzof, Y., Durrant, J. R., Perutz, R. N., & Reisner, E. (2015) · Chemistry - A European Journal · doi:10.1002/chem.201405041 · Cited by 165
Shi, G., Yang, L., Liu, Z., Chen, X., Zhou, J., & Yu, Y. (2018) · Applied Surface Science · doi:10.1016/j.apsusc.2017.08.148 · Cited by 162
Won, D.-I., Lee, J.-S., Ji, J.-M., Jung, W.-J., Son, H.-J., Pac, C., & Kang, S. O. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08890 · Cited by 158
Li, H., Gao, Y., Xiong, Z., Liao, C., & Shih, K. (2018) · Applied Surface Science · doi:10.1016/j.apsusc.2018.01.071 · Cited by 156
Abdellah, M. A., El‐Zohry, A. M., Antila, L. J., Windle, C. D., Reisner, E., & Hammarström, L. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11308 · Cited by 152
Xu, Q., Jiang, C., Cheng, B., & Yu, J. (2017) · Dalton Transactions · doi:10.1039/c7dt00629b · Cited by 152
Toward Solar-Driven Photocatalytic CO2 Reduction Using Water as an Electron Donor
Sato, S., Arai, T., & Morikawa, T. (2015) · Inorganic Chemistry · doi:10.1021/ic502766g · Cited by 129
Akimov, A. V., Asahi, R., Jinnouchi, R., & Prezhdo, O. V. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b07454 · Cited by 118
Photochemical CO 2 reduction using structurally controlled g-C 3 N 4
Walsh, J. J., Jiang, C., Tang, J., & Cowan, A. J. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp04525a · Cited by 115
Ultrafine Cobalt Catalysts on Covalent Carbon Nitride Frameworks for Oxygenic Photosynthesis
Zhang, G., Zang, S., Lin, L., Lan, Z., Li, G., & Wang, X. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b11167 · Cited by 114
Self-citationPhotocatalytic CO 2 reduction using a molecular cobalt complex deposited on TiO 2 nanoparticles
Jin, T., Liu, C., & Li, G. (2014) · Chemical Communications · doi:10.1039/c4cc00503a · Cited by 59
Self-citationMaeda, K., An, D., Ranasinghe, C. S. K., Uchiyama, T., Kuriki, R., Kanazawa, T., Lu, D., Nozawa, S., Yamakata, A., Uchimoto, Y., et al. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta03245a · Cited by 43
Jin, T., He, D., Li, W., Stanton, C. J., Pantovich, S. A., Majetich, G., Schaefer, H. F., Agarwal, J., Wang, D., & Li, G. (2016) · Chemical Communications · doi:10.1039/c6cc08240h · Cited by 34
Self-citationElectrocatalysis of CO2 Reduction in Brush Polymer Ion Gels
McNicholas, B. J., Blakemore, J. D., Chang, A. B., Bates, M. W., Kramer, W. W., Grubbs, R. H., & Gray, H. B. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08795 · Cited by 32
Solar CO2Reduction Using Surface-Immobilized Molecular Catalysts
Louis, M. E., Fenton, T. G., Rondeau, J., Jin, T., & Li, G. (2015) · Comments on Inorganic Chemistry · doi:10.1080/02603594.2015.1088008 · Cited by 26
Self-citation
Cited by
Chemical Synthesis of Single Atomic Site Catalysts
Ji, S., Chen, Y., Wang, X., Zhang, Z., Wang, D., & Li, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00818 · Cited by 1,444
Single-Atom Catalysts across the Periodic Table
Kaiser, S. K., Chen, Z., Faust Akl, D., Mitchell, S., & Pérez-Ramírez, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00576 · Cited by 1,367
Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications
Gao, C., Low, J., Long, R., Kong, T., Zhu, J., & Xiong, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00840 · Cited by 1,050
Fang, S., Rahaman, M., Bharti, J., Reisner, E., Robert, M., Ozin, G. A., & Hu, Y. H. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00243-w · Cited by 834
Zhong, W., Sa, R., Li, L., He, Y., Li, L., Bi, J., Zhuang, Z., Yu, Y., & Zou, Z. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02997 · Cited by 769
Metadata
- Authors
- Huang, P., Huang, J., Pantovich, S. A., Carl, A. D., Fenton, T. G., Caputo, C. A., Grimm, R. L., Frenkel, A. I., & Li, G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-11-10
- Volume
- 140
- Issue
- 47
- Pages
- 16042-16047
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2900060043
- Cited by
- 391
- References
- 54
- FWCI
- 8.71
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
