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Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation
Abstract
Ordered carbon molecular sieves exhibiting Bragg diffraction of X-ray lines have been synthesized for the first time, using mesoporous silica molecular sieves as the template. Sucrose was converted to carbon inside the mesopores of the silica molecular sieves through a mild carbonization process using a sulfuric acid catalyst. The carbon molecular sieves were obtained after the removal of the silica framework using an aqueous solution of sodium hydroxide. The X-ray diffraction, transmission electron microscopy, and pore size analysis showed that the structure of the carbon molecular sieves consisted of a three-dimensional regular array of uniform mesopores 3 nm in diameter. The structure was not simply a negative replica of the used silica template, but the synthesis mechanism involved the unique transformation into a new ordered array that was triggered by the removal of the silica frameworks. The highly ordered mesoporous texture suggested its scientific and technological importance as a new shape-selective catalyst, adsorbent, sensor, and electrode material.
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Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
Thomas, A., Fischer, A., Goettmann, F., Antonietti, M., Müller, J.-O., Schlögl, R., & Carlsson, J. M. (2008) · Journal of Materials Chemistry · doi:10.1039/b800274f · Cited by 3,419
Carbon materials for chemical capacitive energy storage
Zhai, Y., Dou, Y., Zhao, D., Fulvio, P. F., Mayes, R. T., & Dai, S. (2011) · Advanced Materials · doi:10.1002/adma.201100984 · Cited by 2,964
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371
Ordered mesoporous materials in catalysis
Taguchi, A., & Schüth, F. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2004.06.030 · Cited by 2,119
Mesoporous carbon materials: Synthesis and modification
Liang, C., Li, Z., & Dai, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702046 · Cited by 1,935
Adsorption of VOCs onto engineered carbon materials: A review
Zhang, X., Gao, B., Creamer, A. E., Cao, C., & Li, Y. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2017.05.013 · Cited by 1,479
Carbon supports for low-temperature fuel cell catalysts
Antolini, E. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2008.09.030 · Cited by 1,295
Support materials for PEMFC and DMFC electrocatalysts—A review
Sharma, S., & Pollet, B. G. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.02.011 · Cited by 1,206
Nanostructured carbon for energy storage and conversion
Candelaria, S. L., Shao, Y., Zhou, W., Li, X., Xiao, J., Zhang, J.-G., Wang, Y., Liu, J., Li, J., & Cao, G. (2012) · Nano Energy · doi:10.1016/j.nanoen.2011.11.006 · Cited by 975
Molecular-based design and emerging applications of nanoporous carbon spheres
Liu, J., Wickramaratne, N. P., Qiao, S. Z., & Jaroniec, M. (2015) · Nature Materials · doi:10.1038/nmat4317 · Cited by 954
Challenges and breakthroughs in recent research on self-assembly
Ariga, K., Hill, J. P., Lee, M. V., Vinu, A., Charvet, R., & Acharya, S. (2008) · Science and Technology of Advanced Materials · doi:10.1088/1468-6996/9/1/014109 · Cited by 759
Templated nanocarbons for energy storage
Nishihara, H., & Kyotani, T. (2012) · Advanced Materials · doi:10.1002/adma.201201715 · Cited by 745
Superior electric double layer capacitors using ordered mesoporous carbons
Xing, W., Qiao, S. Z., Ding, R. G., Li, F., Lu, G. Q., Yan, Z. F., & Cheng, H. M. (2006) · Carbon · doi:10.1016/j.carbon.2005.07.029 · Cited by 746
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Zhu, C., Du, D., Eychmüller, A., & Lin, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00255 · Cited by 672
Mesoporous materials and electrochemistry
Walcarius, A. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35322a · Cited by 623
Carbon as catalyst and support for electrochemical energy conversion
Trogadas, P., Fuller, T. F., & Strasser, P. (2014) · Carbon · doi:10.1016/j.carbon.2014.04.005 · Cited by 522
Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes
Ji, X., Lee, K. T., Holden, R., Zhang, L., Zhang, J., Botton, G. A., Couillard, M., & Nazar, L. F. (2010) · Nature Chemistry · doi:10.1038/nchem.553 · Cited by 500
Wang, R., Wang, P., Yan, X., Lang, J., Peng, C., & Xue, Q. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am302077c · Cited by 475
Large-pore ordered mesoporous materials templated from non-pluronic amphiphilic block copolymers
Deng, Y., Wei, J., Sun, Z., & Zhao, D. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35426h · Cited by 447
Diatomaceous Lessons in Nanotechnology and Advanced Materials
Losic, D., Mitchell, J. G., & Voelcker, N. H. (2009) · Advanced Materials · doi:10.1002/adma.200803778 · Cited by 414
Deng, Y., Yu, T., Wan, Y., Shi, Y., Meng, Y., Gu, D., Zhang, L., Huang, Y., Liu, C., Wu, X., et al. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067379v · Cited by 402
New developments in ordered mesoporous materials for drug delivery
Manzano, M., & Vallet-Regí, M. (2010) · Journal of Materials Chemistry · doi:10.1039/b922651f · Cited by 359
Mixed matrix proton exchange membranes for fuel cells: State of the art and perspectives
Bakangura, E., Wu, L., Ge, L., Yang, Z., & Xu, T. (2016) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2015.11.004 · Cited by 319
Ma, Z., Kyotani, T., Liu, Z., Terasaki, O., & Tomita, A. (2001) · Chemistry of Materials · doi:10.1021/cm010730l · Cited by 317
Yoon, S. B., Chai, G. S., Kang, S. K., Yu, J.-S., Gierszal, K. P., & Jaroniec, M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0423466 · Cited by 271
Tailored design of functional nanoporous carbon materials toward fuel cell applications
Tang, J., Liu, J., Torad, N. L., Kimura, T., & Yamauchi, Y. (2014) · Nano Today · doi:10.1016/j.nantod.2014.05.003 · Cited by 266
Starbons: New Starch‐Derived Mesoporous Carbonaceous Materials with Tunable Properties
Budarin, V., Clark, J. H., Hardy, J. J. E., Luque, R., Milkowski, K., Tavener, S. J., & Wilson, A. J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200600460 · Cited by 263
Starbons: New Starch‐Derived Mesoporous Carbonaceous Materials with Tunable Properties
Budarin, V., Clark, J. H., Hardy, J. J. E., Luque, R., Milkowski, K., Tavener, S. J., & Wilson, A. J. (2006) · Angewandte Chemie · doi:10.1002/ange.200600460 · Cited by 255
Controlled synthesis and functionalization of ordered large-pore mesoporous carbons
Deng, Y., Cai, Y., Sun, Z., Gu, D., Wei, J., Li, W., Guo, X., Yang, J., & Zhao, D. (2010) · Advanced Functional Materials · doi:10.1002/adfm.201001202 · Cited by 139
Deng, Y., Liu, J., Liu, C., Gu, D., Sun, Z., Wei, J., Zhang, J., Zhang, L., Tu, B., & Zhao, D. (2008) · Chemistry of Materials · doi:10.1021/cm802413q · Cited by 126
Deng, Y., Liu, C., Gu, D., Yu, T., Tu, B., & Zhao, D. (2008) · J. Mater. Chem. · doi:10.1039/b713310c · Cited by 100
Xing, X., Alharbi, N. S., Ren, X., & Chen, C. (2022) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2022.107325 · Cited by 79
Bimodal, templated mesoporous carbons for capacitor applications
Banham, D., Feng, F., Burt, J., Alsrayheen, E., & Birss, V. (2010) · Carbon · doi:10.1016/j.carbon.2009.11.025 · Cited by 56
Synthesis of ordered mesoporous carbon by soft template method
Chauhan, S. (2023) · Materials Today: Proceedings · doi:10.1016/j.matpr.2021.04.257 · Cited by 34
Metadata
- Authors
- Ryoo, R., Joo, S. H., & Jun, S.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-08-27
- Volume
- 103
- Issue
- 37
- Pages
- 7743-7746
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2028755877
- Cited by
- 2,450
- References
- 0
- FWCI
- 18.58
- Type
- journal article
- Language
- en
- Open access
- closed
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