The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Polydopamine-Coated, Nitrogen-Doped, Hollow Carbon–Sulfur Double-Layered Core–Shell Structure for Improving Lithium–Sulfur Batteries
Abstract
To better confine the sulfur/polysulfides in the electrode of lithium-sulfur (Li/S) batteries and improve the cycling stability, we developed a double-layered core-shell structure of polymer-coated carbon-sulfur. Carbon-sulfur was first prepared through the impregnation of sulfur into hollow carbon spheres under heat treatment, followed by a coating polymerization to give a double-layered core-shell structure. From the study of scanning transmission electron microscopy (STEM) images, we demonstrated that the sulfur not only successfully penetrated through the porous carbon shell but also aggregated along the inner wall of the carbon shell, which, for the first time, provided visible and convincing evidence that sulfur preferred diffusing into the hollow carbon rather than aggregating in/on the porous wall of the carbon. Taking advantage of this structure, a stable capacity of 900 mA h g(-1) at 0.2 C after 150 cycles and 630 mA h g(-1) at 0.6 C after 600 cycles could be obtained in Li/S batteries. We also demonstrated the feasibility of full cells using the sulfur electrodes to couple with the silicon film electrodes, which exhibited significantly improved cycling stability and efficiency. The remarkable electrochemical performance could be attributed to the desirable confinement of sulfur through the unique double-layered core-shell architectures.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Mussel-inspired surface chemistry for multifunctional coatings
Lee, H., Dellatore, S. M., Miller, W. M., & Messersmith, P. B. (2007) · Science · doi:10.1126/science.1147241 · Cited by 10,965
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Nanostructured materials for advanced energy conversion and storage devices
Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M., & van Schalkwijk, W. (2005) · Nature Materials · doi:10.1038/nmat1368 · Cited by 8,826
Lithium Batteries and Cathode Materials
Whittingham, M. S. (2004) · Chemical Reviews · doi:10.1021/cr020731c · Cited by 6,267
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
Ji, X., Lee, K. T., & Nazar, L. F. (2009) · Nature Materials · doi:10.1038/nmat2460 · Cited by 5,988
Challenges and Prospects of Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., & Su, Y.-S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300179v · Cited by 2,380
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
Guo, Y., Hu, J., & Wan, L. (2008) · Advanced Materials · doi:10.1002/adma.200800627 · Cited by 2,223
Wang, H., Yang, Y., Liang, Y., Robinson, J. T., Li, Y., Jackson, A., Cui, Y., & Dai, H. (2011) · Nano Letters · doi:10.1021/nl200658a · Cited by 2,119
Wei Seh, Z., Li, W., Cha, J. J., Zheng, G., Yang, Y., McDowell, M. T., Hsu, P.-C., & Cui, Y. (2013) · Nature Communications · doi:10.1038/ncomms2327 · Cited by 2,107
Ji, X., & Nazar, L. F. (2010) · Journal of Materials Chemistry · doi:10.1039/b925751a · Cited by 1,967
Porous Hollow Carbon@Sulfur Composites for High‐Power Lithium–Sulfur Batteries
Jayaprakash, N., Shen, J., Moganty, S. S., Corona, A., & Archer, L. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100637 · Cited by 1,811
Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
Ji, L., Rao, M., Zheng, H., Zhang, L., Li, Y., Duan, W., Guo, J., Cairns, E. J., & Zhang, Y. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206955k · Cited by 1,505
Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer
Su, Y.-S., & Manthiram, A. (2012) · Nature Communications · doi:10.1038/ncomms2163 · Cited by 1,458
New Approaches for High Energy Density Lithium–Sulfur Battery Cathodes
Evers, S., & Nazar, L. F. (2013) · Accounts of Chemical Research · doi:10.1021/ar3001348 · Cited by 1,324
Zheng, G., Yang, Y., Cha, J. J., Hong, S. S., & Cui, Y. (2011) · Nano Letters · doi:10.1021/nl2027684 · Cited by 1,295
Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium–Sulfur Batteries
Schuster, J., He, G., Mandlmeier, B., Yim, T., Lee, K. T., Bein, T., & Nazar, L. F. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107817 · Cited by 1,114
Xiao, L., Cao, Y., Xiao, J., Schwenzer, B., Engelhard, M. H., Saraf, L. V., Nie, Z., Exarhos, G. J., & Liu, J. (2012) · Advanced Materials · doi:10.1002/adma.201103392 · Cited by 1,016
Song, J., Xu, T., Gordin, M. L., Zhu, P., Lv, D., Jiang, Y., Chen, Y., Duan, Y., & Wang, D. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201302631 · Cited by 978
Improving the Performance of Lithium–Sulfur Batteries by Conductive Polymer Coating
Yang, Y., Yu, G., Cha, J. J., Wu, H., Vosgueritchian, M., Yao, Y., Bao, Z., & Cui, Y. (2011) · ACS Nano · doi:10.1021/nn203436j · Cited by 866
Stabilizing lithium–sulphur cathodes using polysulphide reservoirs
Ji, X., Evers, S., Black, R., & Nazar, L. F. (2011) · Nature Communications · doi:10.1038/ncomms1293 · Cited by 864
Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery
Liang, C., Dudney, N. J., & Howe, J. Y. (2009) · Chemistry of Materials · doi:10.1021/cm902050j · Cited by 862
Confining Sulfur in Double‐Shelled Hollow Carbon Spheres for Lithium–Sulfur Batteries
Zhang, C., Wu, H. B., Yuan, C., Guo, Z., & Lou, X. W. (. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201205292 · Cited by 800
Yolk–Shell Structure of Polyaniline-Coated Sulfur for Lithium–Sulfur Batteries
Zhou, W., Yu, Y., Chen, H., DiSalvo, F. J., & Abruña, H. D. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409508q · Cited by 782
Self-citationZheng, G., Zhang, Q., Cha, J. J., Yang, Y., Li, W., Seh, Z. W., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl304795g · Cited by 705
Li, W., Zhang, Q., Zheng, G., Seh, Z. W., Yao, H., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl403130h · Cited by 654
Wu, F., Chen, J., Chen, R., Wu, S., Li, L., Chen, S., & Zhao, T. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp1114724 · Cited by 520
Yin, L., Wang, J., Lin, F., Yang, J., & Nuli, Y. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03495f · Cited by 484
Tailoring Porosity in Carbon Nanospheres for Lithium–Sulfur Battery Cathodes
He, G., Evers, S., Liang, X., Cuisinier, M., Garsuch, A., & Nazar, L. F. (2013) · ACS Nano · doi:10.1021/nn404439r · Cited by 475
Lithium Sulfur Battery: Oxidation/Reduction Mechanisms of Polysulfides in THF Solutions
Yamin, H., Gorenshtein, A., Penciner, J., Sternberg, Y., & Peled, E. (1988) · Journal of The Electrochemical Society · doi:10.1149/1.2095868 · Cited by 471
A strategic approach to recharging lithium-sulphur batteries for long cycle life
Su, Y.-S., Fu, Y., Cochell, T., & Manthiram, A. (2013) · Nature Communications · doi:10.1038/ncomms3985 · Cited by 449
Chen, R., Zhao, T., Lu, J., Wu, F., Li, L., Chen, J., Tan, G., Ye, Y., & Amine, K. (2013) · Nano Letters · doi:10.1021/nl4016683 · Cited by 401
Manipulating surface reactions in lithium–sulphur batteries using hybrid anode structures
Huang, C., Xiao, J., Shao, Y., Zheng, J., Bennett, W. D., Lu, D., Saraf, L. V., Engelhard, M., Ji, L., Zhang, J., et al. (2014) · Nature Communications · doi:10.1038/ncomms4015 · Cited by 343
Lithium–Sulfur Battery Cathode Enabled by Lithium–Nitrile Interaction
Guo, J., Yang, Z., Yu, Y., Abruña, H. D., & Archer, L. A. (2013) · Journal of the American Chemical Society · doi:10.1021/ja309435f · Cited by 343
Lu, S., Cheng, Y., Wu, X., & Liu, J. (2013) · Nano Letters · doi:10.1021/nl400543y · Cited by 319
Lithium‐Sulfur Battery: Evaluation of Dioxolane‐Based Electrolytes
Peled, E., Sternberg, Y., Gorenshtein, A., & Lavi, Y. (1989) · Journal of The Electrochemical Society · doi:10.1149/1.2096981 · Cited by 289
Fu, Y., & Manthiram, A. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp300950m · Cited by 278
Ultrathin Multifunctional Oxide Coatings for Lithium Ion Batteries
Xiao, X., Lu, P., & Ahn, D. (2011) · Advanced Materials · doi:10.1002/adma.201101915 · Cited by 268
Self-citationAmylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of Lithium–Sulfur Battery
Zhou, W., Chen, H., Yu, Y., Wang, D., Cui, Z., DiSalvo, F. J., & Abruña, H. D. (2013) · ACS Nano · doi:10.1021/nn403237b · Cited by 190
Self-citationCarbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability
Brückner, J., Thieme, S., Böttger‐Hiller, F., Bauer, I., Grossmann, H. T., Strubel, P., Althues, H., Spange, S., & Kaskel, S. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201302169 · Cited by 184
Interface Chemistry Guided Long-Cycle-Life Li–S Battery
Wang, L., Dong, W., Zhang, F., & Jin, J. (2013) · Nano Letters · doi:10.1021/nl4018868 · Cited by 126
Capillary Absorption of Metal Nanodroplets by Single-Wall Carbon Nanotubes
Schebarchov, D., & Hendy, S. C. (2008) · Nano Letters · doi:10.1021/nl080875s · Cited by 73
The low-pressure phase diagram of sulfur
Ferreira, A. G. M., & Lobo, L. Q. (2010) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2010.07.007 · Cited by 64
Cited by
Polydopamine Surface Chemistry: A Decade of Discovery
Ryu, J. H., Messersmith, P. B., & Lee, H. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b19865 · Cited by 1,843
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Molecular-based design and emerging applications of nanoporous carbon spheres
Liu, J., Wickramaratne, N. P., Qiao, S. Z., & Jaroniec, M. (2015) · Nature Materials · doi:10.1038/nmat4317 · Cited by 954
Song, J., Yu, Z., Gordin, M. L., & Wang, D. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b03217 · Cited by 561
Pei, F., An, T., Zang, J., Zhao, X., Fang, X., Zheng, M., Dong, Q., & Zheng, N. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502539 · Cited by 555
Metadata
- Authors
- Zhou, W., Xiao, X., Cai, M., & Yang, L.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-08-29
- Volume
- 14
- Issue
- 9
- Pages
- 5250-5256
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2332640839
- Cited by
- 382
- References
- 42
- FWCI
- 28.30
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
