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3D Graphene–Cobalt Oxide Electrode for High-Performance Supercapacitor and Enzymeless Glucose Detection
Abstract
Using a simple hydrothermal procedure, cobalt oxide (Co(3)O(4)) nanowires were in situ synthesized on three-dimensional (3D) graphene foam grown by chemical vapor deposition. The structure and morphology of the resulting 3D graphene/Co(3)O(4) composites were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Raman spectroscopy. The 3D graphene/Co(3)O(4) composite was used as the monolithic free-standing electrode for supercapacitor application and for enzymeless electrochemical detection of glucose. We demonstrate that it is capable of delivering high specific capacitance of ∼1100 F g(-1) at a current density of 10 A g(-1) with excellent cycling stability, and it can detect glucose with a ultrahigh sensitivity of 3.39 mA mM(-1) cm(-2) and a remarkable lower detection limit of <25 nM (S/N = 8.5).
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Self-citation
Metadata
- Authors
- Dong, X.-C., Xu, H., Wang, X.-W., Huang, Y.-X., Chan-Park, M. B., Zhang, H., Wang, L.-H., Huang, W., & Chen, P.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-23
- Volume
- 6
- Issue
- 4
- Pages
- 3206-3213
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1989236464
- Cited by
- 1,595
- References
- 45
- FWCI
- 62.78
- Type
- journal article
- Language
- en
- Open access
- closed
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