Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 1,210

The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.

Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics

Open access
Zhang, Jian, Wang, Tao, Liu, Pan, Liao, Zhongquan, Liu, Shaohua, Zhuang, Xiaodong, Chen, Mingwei, Zschech, Ehrenfried, Feng, Xinliang·2017·Nature Communications
DOI 10.1038/ncomms15437
Open this paper in CoChat — free account

Abstract

Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report a MoNi 4 electrocatalyst supported by MoO 2 cuboids on nickel foam (MoNi 4/MoO 2@Ni), which is constructed by controlling the outward diffusion of nickel atoms on annealing precursor NiMoO 4 cuboids on nickel foam. Experimental and theoretical results confirm that a rapid Tafel-step-decided hydrogen evolution proceeds on MoNi 4 electrocatalyst. As a result, the MoNi 4 electrocatalyst exhibits zero onset overpotential, an overpotential of 15 mV at 10 mA cm−2 and a low Tafel slope of 30 mV per decade in 1 M potassium hydroxide electrolyte, which are comparable to the results for platinum and superior to those for state-of-the-art platinum-free electrocatalysts. Benefiting from its scalable preparation and stability, the MoNi 4 electrocatalyst is promising for practical water-alkali electrolysers.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1038/ncomms15437

Cites

18 of 18 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Research works printed but not linked: 28

  1. Turner, J. et al. Renewable hydrogen production. Int. J. Energy Res. 32, 379–407 (2008). · DOI · Paper page
  2. Dunn, S. Hydrogen futures: toward a sustainable energy system. Int. J. Hydrog. Energy 27, 235–264 (2002). · DOI · Paper page
  3. Holladay, J. D., Hu, J., King, D. L. & Wang, Y. An overview of hydrogen production technologies. Catal. Today 139, 244–260 (2009). · DOI · Paper page
  4. Kudo, A. & Miseki, Y. Heterogeneous photocatalyst materials for water splitting. Chem. Soc. Rev. 38, 253–278 (2009). · DOI · Paper page
  5. Lewis, N. S. & Nocera, D. G. Powering the planet: chemical challenges in solar energy utilization. Proc. Natl Acad. Sci. USA 103, 15729–15735 (2006). · DOI · Paper page
  6. McKone, J. R., Marinescu, S. C., Brunschwig, B. S., Winkler, J. R. & Gray, H. B. Earth-abundant hydrogen evolution electrocatalysts. Chem. Sci. 5, 865–878 (2014). · DOI · Paper page
  7. Safizadeh, F., Ghali, E. & Houlachi, G. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions—a review. Int. J. Hydrog. Energy 40, 256–274 (2015). · DOI · Paper page
  8. Carmo, M., Fritz, D. L., Mergel, J. & Stolten, D. A comprehensive review on PEM water electrolysis. Int. J. Hydrog. Energy 38, 4901–4934 (2013). · DOI · Paper page
  9. Zheng, Y., Jiao, Y., Jaroniec, M. & Qiao, S. Z. Advancing the electrochemistry of the hydrogen-evolution reaction through combining experiment and theory. Angew. Chem. Int. Ed. 54, 52–65 (2015). · DOI · Paper page
  10. Subbaraman, R. et al. Trends in activity for the water electrolyser reactions on 3d M (Ni, Co, Fe, Mn) hydr (oxy) oxide catalysts. Nat. Mater. 11, 550–557 (2012). · DOI · Paper page
  11. Fajín, J. L. C., Cordeiro, M. N. D. S. & Gomes, J. R. B. Density functional theory study of the water dissociation on platinum surfaces: general trends. J. Phys. Chem. A 118, 5832–5840 (2014). · DOI
  12. Caban-Acevedo, M. et al. Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide. Nat. Mater. 14, 1245–1251 (2015). · DOI · Paper page
  13. Li, J.-S. et al. Coupled molybdenum carbide and reduced graphene oxide electrocatalysts for efficient hydrogen evolution. Nat. Commun. 7, 11204–11211 (2016). · DOI · Paper page
  14. Shi, Y. & Zhang, B. Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem. Soc. Rev. 45, 1529–1541 (2016). · DOI · Paper page
  15. Tran, P. D. et al. Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide. Nat. Mater. 15, 640–646 (2016). · DOI · Paper page
  16. Ng, J. W. D. et al. Gold-supported cerium-doped NiOx catalysts for water oxidation. Nat. Energy 1, 16053–16060 (2016). · DOI · Paper page
  17. Gong, M. et al. Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis. Nat. Commun. 5, 4695–4700 (2014). · DOI · Paper page
  18. Zhou, H. et al. Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam. Nat. Commun. 7, 12765–12771 (2016). · DOI · Paper page
  19. Wang, D.-Y. et al. Highly active and stable hybrid catalyst of cobalt-doped FeS2 nanosheets–carbon nanotubes for hydrogen evolution reaction. J. Am. Chem. Soc. 137, 1587–1592 (2015). · DOI · Paper page
  20. Li, H. et al. Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies. Nat. Mater. 15, 48–53 (2015). · DOI · Paper page
  21. Staszak-Jirkovsky, J. et al. Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. Nat. Mater. 15, 197–203 (2015). · DOI · Paper page
  22. Gong, Q. et al. Ultrasmall and phase-pure W2C nanoparticles for efficient electrocatalytic and photoelectrochemical hydrogen evolution. Nat. Commun. 7, 13216–13223 (2016). · DOI · Paper page
  23. Li, Y. H. et al. Local atomic structure modulations activate metal oxide as electrocatalyst for hydrogen evolution in acidic water. Nat. Commun. 6, 8064–8070 (2015). · DOI · Paper page
  24. Konkena, B. et al. Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation. Nat. Commun. 7, 12269–12276 (2016). · DOI · Paper page
  25. Zhang, J. et al. Interface engineering of MoS2/Ni3S2 heterostructures for highly enhanced electrochemical overall-water-splitting activity. Angew. Chem. Int. Ed. 128, 6814–6819 (2016). · DOI · Paper page
  26. Xie, J. et al. Defect-rich MoS2 ultrathin nanosheets with additional active edge sites for enhanced electrocatalytic hydrogen evolution. Adv. Mater. 25, 5807–5813 (2013). · DOI · Paper page
  27. Birry, L. & Lasia, A. Studies of the hydrogen evolution reaction on raney nickel–molybdenum electrodes. J. Appl. Electrochem. 34, 735–749 (2004). · DOI · Paper page
  28. Peng, S., Li, L., Wu, H., Madhavi, S. & Lou, X. Controlled growth of NiMoO4 nanosheet and nanorod arrays on various conductive substrates as advanced electrodes for asymmetric supercapacitors. Adv. Energy Mater. 5, 1401172–1401178 (2015). · DOI · Paper page

Cited by

See all 1,210

Metadata

Authors
Zhang, J., Wang, T., Liu, P., Liao, Z., Liu, S., Zhuang, X., Chen, M., Zschech, E., & Feng, X.
Venue
Nature Communications
Publisher
Springer Science and Business Media LLC
Published
2017-05-17
Volume
8
Issue
1
Pages
15437-15437
ISSN
2041-1723 (ISSN-L)
DOI
10.1038/ncomms15437
OpenAlex
W2614702079
Cited by
1,210
References
18
FWCI
29.18
Type
journal article
Language
en
Open access
gold
Licence

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.