Mechanism studies of terpolymerization of phthalic anhydride, propylene epoxide, and carbon dioxide catalyzed by ZnGA
Abstract
Monomer reactivity ratios of CO 2 and phthalic anhydride (PA) are evaluated and a mechanism is discussed for ZnGA catalyzed PA/CO 2 /PO terpolymerizations.
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While these heterogeneous catalysts can show good reactivities, they lack sufficient control on the polymerizations and the structures of the active species are ill-defined.
“While these catalysts can show good reactivities, they lack sufficient control on the polymerizations and the structures of the active species are ill-defined.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [354]
Early studies focused on heterogeneous catalysts such as zinc glutarate and double metal cyanides.
“Early studies focused on heterogeneous catalysts such as zinc glutarate 353,354 and double metal cyanides 355,356 .”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [354]
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Catalysis as an Enabling Science for Sustainable Polymers
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Chemoselective Polymerizations from Mixtures of Epoxide, Lactone, Anhydride, and Carbon Dioxide
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- Authors
- Liu, Y., Xiao, M., Wang, S., Xia, L., Hang, D., Cui, G., & Meng, Y.
- Affiliations
- Sun Yat-sen University (CN)
- Corresponding author
- Xiao, Min
- Meng, Yuezhong
- Venue
- RSC Adv.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 4
- Issue
- 19
- Pages
- 9503-9508
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W2162569538
- Cited by
- 60
- References
- 31
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 4 · 2023: 4 · 2022: 7 · 2021: 8 · 2020: 3 · 2019: 4 · 2018: 8 · 2017: 5 · 2016: 6 · 2015: 3 · 2014: 2
- FWCI
- 2.19
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- RSC Advances (publishedVersion)
- Funders
- National Natural Science Foundation of China (21376276)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
- Keywords
- terpolymerization, phthalic anhydride, carbon dioxide, reaction mechanism, reactivity ratios, CO2 polymerization
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