Cited by 258Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Pre‐Rate‐Determining Selectivity in the Terpolymerization of Epoxides, Cyclic Anhydrides, and CO2: A One‐Step Route to Diblock Copolymers

Jeske, Ryan C., Rowley, John M., Coates, Geoffrey W.·2008·Angewandte Chemie International Edition

Abstract

Catching a second wind: In kinetic resolution polymerization, one monomer is consumed faster than the other, which creates diblock copolymers that only slowly approach 100 % conversion and contain tapering. In the title reaction, the opposite is true: the first block forms cleanly, followed by a second block that has an even higher rate of polymerization. This unique reaction allows for the programmed self-assembly of diblock polymers that display little tapering.

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Registry

Crossref · 10.1002/anie.200801415

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27 of 27 references verified0 citation errors · 0 not checkable

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  • This selectivity is attributed to the faster rate of anhydride insertion than CO2 insertion into the metal-alkoxide intermediate.

    “This selectivity is attributed to the faster rate of anhydride insertion than CO2 insertion into the metal-alkoxide intermediate.367”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [367]

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Authors
Jeske, R. C., Rowley, J. M., & Coates, G. W.
Affiliations
Cornell University (US)
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2008-07-22
Volume
47
Issue
32
Pages
6041-6044
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2168009396
Cited by
258
References
27
Citations by year
2026: 8 · 2025: 16 · 2024: 24 · 2023: 27 · 2022: 32 · 2021: 27 · 2020: 12 · 2019: 8 · 2018: 21 · 2017: 11 · 2016: 11 · 2015: 12 · 2014: 12 · 2013: 9 · 2012: 10
FWCI
2.98
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords
terpolymerization, epoxides, cyclic anhydrides, carbon dioxide, diblock copolymers, tapering, polymerization kinetics
MeSH terms
Anhydrides, Carbon Dioxide, Catalysis, Epoxy Compounds, Kinetics, Polymers, Zinc

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