Understanding the hydrogen bonds in ionic liquids and their roles in properties and reactions

The nature of the chemical bond—1992

Pauling, L. (1992) · Journal of Chemical Education · doi:10.1021/ed069p519 · Cited by 13,218

Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2

Hallett, J. P., & Welton, T. (2011) · Chemical Reviews · doi:10.1021/cr1003248 · Cited by 12,578

The Hydrogen Bond in the Solid State

Steiner, T. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020104)41:1<48::aid-anie48>3.0.co;2-u · Cited by 6,247

Dissolution of Cellose with Ionic Liquids

Swatloski, R. P., Spear, S. K., Holbrey, J. D., & Rogers, R. D. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025790m · Cited by 4,728

Ionic-liquid materials for the electrochemical challenges of the future

Armand, M., Endres, F., MacFarlane, D. R., Ohno, H., & Scrosati, B. (2009) · Nature Materials · doi:10.1038/nmat2448 · Cited by 4,619

Biomass Recalcitrance: Engineering Plants and Enzymes for Biofuels Production

Himmel, M. E., Ding, S.-Y., Johnson, D. K., Adney, W. S., Nimlos, M. R., Brady, J. W., & Foust, T. D. (2007) · Science · doi:10.1126/science.1137016 · Cited by 4,533

Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts

Bonhôte, P., Dias, A.-P., Papageorgiou, N., Kalyanasundaram, K., & Grätzel, M. (1996) · Inorganic Chemistry · doi:10.1021/ic951325x · Cited by 4,358

Ionic Liquids--Solvents of the Future?

Rogers, R. D., & Seddon, K. R. (2003) · Science · doi:10.1126/science.1090313 · Cited by 4,130

Perturbation Theory Approach to Intermolecular Potential Energy Surfaces of van der Waals Complexes

Jeziorski, B., Moszynski, R., & Szalewicz, K. (1994) · Chemical Reviews · doi:10.1021/cr00031a008 · Cited by 2,818

Ionic Liquids in Synthesis

(2007) · Wiley eBooks · doi:10.1002/9783527621194 · Cited by 2,768

Protic Ionic Liquids: Properties and Applications

Greaves, T. L., & Drummond, C. J. (2008) · Chemical Reviews · doi:10.1021/cr068040u · Cited by 2,442

CO2 Capture by a Task-Specific Ionic Liquid

Bates, E. D., Mayton, R. D., Ntai, I., & Davis, J. H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja017593d · Cited by 2,270

室温イオン液体 合成溶媒および触媒反応 2

Jason, P. H., & Tom, W. (2011) · Chemical Reviews · Cited by 2,270

Definition of the hydrogen bond (IUPAC Recommendations 2011)

Arunan, E., Desiraju, G. R., Klein, R. A., Sadlej, J., Scheiner, S., Alkorta, I., Clary, D. C., Crabtree, R. H., Dannenberg, J. J., Hobza, P., et al. (2011) · Pure and Applied Chemistry · doi:10.1351/pac-rec-10-01-02 · Cited by 1,886

Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids

Wilkes, J. S., & Zaworotko, M. J. (1992) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39920000965 · Cited by 1,883

Valency and Bonding: A Natural Bond Orbital Donor-Acceptor Perspective

Weinhold, F., & Landis, C. R. (2005) · Cited by 1,858

Nanostructural Organization in Ionic Liquids

Canongia Lopes, J. N. A., & Pádua, A. A. H. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp056006y · Cited by 1,856

Blue-Shifting Hydrogen Bonds

Hobza, P., & Havlas, Z. (2000) · Chemical Reviews · doi:10.1021/cr990050q · Cited by 1,817

Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials

Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558

Deconstruction of lignocellulosic biomass with ionic liquids

Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557

Ionic Liquids and Their Interaction with Cellulose

Pinkert, A., Marsh, K. N., Pang, S., & Staiger, M. P. (2009) · Chemical Reviews · doi:10.1021/cr9001947 · Cited by 1,508

Molecular states of water in room temperature ionic liquidsElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b106900d/

Cammarata, L., Kazarian, S. G., Salter, P. A., & Welton, T. (2001) · Physical Chemistry Chemical Physics · doi:10.1039/b106900d · Cited by 1,441

Ionic Liquids at Electrified Interfaces

Fedorov, M. V., & Kornyshev, A. A. (2014) · Chemical Reviews · doi:10.1021/cr400374x · Cited by 1,398

Ionic liquid processing of cellulose

Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369

Molecular Ordering of Organic Molten Salts Triggered by Single-Walled Carbon Nanotubes

Fukushima, T., Kosaka, A., Ishimura, Y., Yamamoto, T., Takigawa, T., Ishii, N., & Aida, T. (2003) · Science · doi:10.1126/science.1082289 · Cited by 1,353

Ionogels, ionic liquid based hybrid materials

Le Bideau, J., Viau, L., & Vioux, A. (2011) · Chem. Soc. Rev. · doi:10.1039/c0cs00059k · Cited by 1,285

Nanoscale Segregation in Room Temperature Ionic Liquids

Triolo, A., Russina, O., Bleif, H.-J., & Di Cola, E. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp067705t · Cited by 1,282

Room Temperature Ionic Liquids from 20 Natural Amino Acids

Fukumoto, K., Yoshizawa, M., & Ohno, H. (2005) · Journal of the American Chemical Society · doi:10.1021/ja043451i · Cited by 1,236

Electrochemical Reactivity in Room-Temperature Ionic Liquids

Hapiot, P., & Lagrost, C. (2008) · Chemical Reviews · doi:10.1021/cr0680686 · Cited by 1,185

Characterization of a Dihydrogen Bond on the Basis of the Electron Density

Popelier, P. L. A. (1998) · The Journal of Physical Chemistry A · doi:10.1021/jp9805048 · Cited by 1,132

Ionic Liquids: Ion Mobilities, Glass Temperatures, and Fragilities

Xu, W., Cooper, E. I., & Angell, C. A. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp0275894 · Cited by 1,062

Ionic Liquids in Separations

Han, X., & Armstrong, D. W. (2007) · Accounts of Chemical Research · doi:10.1021/ar700044y · Cited by 1,024

High-Pressure Phase Behavior of Ionic Liquid/CO2 Systems

Blanchard, L. A., Gu, Z., & Brennecke, J. F. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp003309d · Cited by 1,018

Valency and Bonding: A Natural Bond Orbital Donor-Acceptor Perspective

Weinhold, F., & Landis, C. R. (2003) · Cambridge University Press eBooks · doi:10.1017/cbo9780511614569 · Cited by 999

Ionic Liquids by Proton Transfer: Vapor Pressure, Conductivity, and the Relevance of Δp Ka from Aqueous Solutions

Yoshizawa, M., Xu, W., & Angell, C. A. (2003) · Journal of the American Chemical Society · doi:10.1021/ja035783d · Cited by 946

Equimolar CO2 Absorption by Anion-Functionalized Ionic Liquids

Gurkan, B. E., de la Fuente, J. C., Mindrup, E. M., Ficke, L. E., Goodrich, B. F., Price, E. A., Schneider, W. F., & Brennecke, J. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja909305t · Cited by 914

On the solid, liquid and solution structural organization of imidazolium ionic liquids

Dupont, J. (2004) · Journal of the Brazilian Chemical Society · doi:10.1590/s0103-50532004000300002 · Cited by 846

Hydrogen bonding in ionic liquids

Hunt, P. A., Ashworth, C. R., & Matthews, R. P. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00278d · Cited by 836

Solvent–solute interactions in ionic liquids

Crowhurst, L., Mawdsley, P. R., Perez-Arlandis, J. M., Salter, P. A., & Welton, T. (2003) · Phys. Chem. Chem. Phys. · doi:10.1039/b303095d · Cited by 776

Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

Remsing, R. C., Swatloski, R. P., Rogers, R. D., & Moyna, G. (2006) · Chemical Communications · doi:10.1039/b600586c · Cited by 711

Tuning the Basicity of Ionic Liquids for Equimolar CO2 Capture

Wang, C., Luo, X., Luo, H., Jiang, D., Li, H., & Dai, S. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201008151 · Cited by 691

Quantitative Structure–Property Relationship Modeling of Diverse Materials Properties

Le, T., Epa, V. C., Burden, F. R., & Winkler, D. A. (2012) · Chemical Reviews · doi:10.1021/cr200066h · Cited by 565

Ionicity in ionic liquids: correlation with ionic structure and physicochemical properties

Ueno, K., Tokuda, H., & Watanabe, M. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/b921462n · Cited by 562

Protic Ionic Liquids: Preparation, Characterization, and Proton Free Energy Level Representation

Belieres, J.-P., & Angell, C. A. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp067589u · Cited by 545

A Refined Force Field for Molecular Simulation of Imidazolium-Based Ionic Liquids

Liu, Z., Huang, S., & Wang, W. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp048369o · Cited by 542

Ionic liquids as amphiphile self-assembly media

Greaves, T. L., & Drummond, C. J. (2008) · Chemical Society Reviews · doi:10.1039/b801395k · Cited by 532

Structure of molten 1,3-dimethylimidazolium chloride using neutron diffraction

Hardacre, C., Holbrey, J. D., McMath, S. E. J., Bowron, D. T., & Soper, A. K. (2003) · The Journal of Chemical Physics · doi:10.1063/1.1523917 · Cited by 504

Temperature and Composition Dependence of the Density and Viscosity of Binary Mixtures of Water + Ionic Liquid

Rodríguez, H., & Brennecke, J. F. (2006) · Journal of Chemical & Engineering Data · doi:10.1021/je0602824 · Cited by 479

Ionic liquid-based green processes for energy production

Zhang, S., Sun, J., Zhang, X., Xin, J., Miao, Q., & Wang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60409h · Cited by 471

Characterising the Electronic Structure of Ionic Liquids: An Examination of the 1‐Butyl‐3‐Methylimidazolium Chloride Ion Pair

Hunt, P. A., Kirchner, B., & Welton, T. (2006) · Chemistry – A European Journal · doi:10.1002/chem.200600103 · Cited by 468

Effects of anionic structure and lithium salts addition on the dissolution of cellulose in 1-butyl-3-methylimidazolium-based ionic liquid solvent systems

Xu, A., Wang, J., & Wang, H. (2010) · Green Chem. · doi:10.1039/b916882f · Cited by 439

Strong, Localized, and Directional Hydrogen Bonds Fluidize Ionic Liquids

Fumino, K., Wulf, A., & Ludwig, R. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803446 · Cited by 439

Advances on biomass pretreatment using ionic liquids: An overview

Tadesse, H., & Luque, R. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00667j · Cited by 434

From Molten Salts to Ionic Liquids: A “Nano” Journey

Dupont, J. (2011) · Accounts of Chemical Research · doi:10.1021/ar2000937 · Cited by 431

Extraction of lignin from lignocellulose at atmospheric pressure using alkylbenzenesulfonate ionic liquid

Tan, S. S. Y., MacFarlane, D. R., Upfal, J., Edye, L. A., Doherty, W. O. S., Patti, A. F., Pringle, J. M., & Scott, J. L. (2009) · Green Chemistry · doi:10.1039/b815310h · Cited by 429

Electronic Structure of Stable Carbenes, Silylenes, and Germylenes

Boehme, C., & Frenking, G. (1996) · Journal of the American Chemical Society · doi:10.1021/ja9527075 · Cited by 421

Dissolution or extraction of crustacean shells using ionic liquids to obtain high molecular weight purified chitin and direct production of chitin films and fibers

Qin, Y., Lu, X., Sun, N., & Rogers, R. D. (2010) · Green Chemistry · doi:10.1039/c003583a · Cited by 394

Why Does a Reduction in Hydrogen Bonding Lead to an Increase in Viscosity for the 1-Butyl-2,3-dimethyl-imidazolium-Based Ionic Liquids?

Hunt, P. A. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp067182p · Cited by 385

Improving enzymatic hydrolysis of wheat straw using ionic liquid 1-ethyl-3-methyl imidazolium diethyl phosphate pretreatment

Li, Q., He, Y.-C., Xian, M., Jun, G., Xu, X., Yang, J.-M., & Li, L.-Z. (2009) · Bioresource Technology · doi:10.1016/j.biortech.2009.02.040 · Cited by 360

Why Is the Partial Molar Volume of CO2 So Small When Dissolved in a Room Temperature Ionic Liquid? Structure and Dynamics of CO2 Dissolved in [Bmim+] [PF6-]

Huang, X., Margulis, C. J., Li, Y., & Berne, B. J. (2005) · Journal of the American Chemical Society · doi:10.1021/ja055315z · Cited by 353

Understanding the Interactions of Cellulose with Ionic Liquids: A Molecular Dynamics Study

Liu, H., Sale, K. L., Holmes, B. M., Simmons, B. A., & Singh, S. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp9117437 · Cited by 350

The influence of hydrogen bonding on the physical properties of ionic liquids

Fumino, K., Peppel, T., Geppert-Rybczyńska, M., Zaitsau, D. H., Lehmann, J. K., Verevkin, S. P., Köckerling, M., & Ludwig, R. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp20732f · Cited by 326

Lignin Extraction from Straw by Ionic Liquids and Enzymatic Hydrolysis of the Cellulosic Residues

Fu, D., Mazza, G., & Tamaki, Y. (2010) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf903616y · Cited by 315

Are There Stable Ion-Pairs in Room-Temperature Ionic Liquids? Molecular Dynamics Simulations of 1-n-Butyl-3-methylimidazolium Hexafluorophosphate

Zhao, W., Leroy, F., Heggen, B., Zahn, S., Kirchner, B., Balasubramanian, S., & Müller-Plathe, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja906337p · Cited by 313

Towards a Molecular Understanding of Cation–Anion Interactions—Probing the Electronic Structure of Imidazolium Ionic Liquids by NMR Spectroscopy, X‐ray Photoelectron Spectroscopy and Theoretical Calculations

Cremer, T., Kolbeck, C., Lovelock, K. R. J., Paape, N., Wölfel, R., Schulz, P. S., Wasserscheid, P., Weber, H., Thar, J., Kirchner, B., et al. (2010) · Chemistry – A European Journal · doi:10.1002/chem.201001032 · Cited by 305

Comparative sugar recovery and fermentation data following pretreatment of poplar wood by leading technologies

Wyman, C. E., Dale, B. E., Elander, R. T., Holtzapple, M., Ladisch, M. R., Lee, Y. Y., Mitchinson, C., & Saddler, J. N. (2009) · Biotechnology Progress · doi:10.1002/btpr.142 · Cited by 299

Hydrogen Bonds: A Structural Insight into Ionic Liquids

Dong, K., & Zhang, S. (2012) · Chemistry – A European Journal · doi:10.1002/chem.201101645 · Cited by 291

Identification of 1,3-Dialkylimidazolium Salt Supramolecular Aggregates in Solution

Consorti, C. S., Suarez, P. A. Z., de Souza, R. F., Burrow, R. A., Farrar, D. H., Lough, A. J., Loh, W., da Silva, L. H. M., & Dupont, J. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0452709 · Cited by 290

Pretreatment of rice straw with ammonia and ionic liquid for lignocellulose conversion to fermentable sugars

Nguyen, T.-A. D., Kim, K.-R., Han, S. J., Cho, H. Y., Kim, J. W., Park, S. M., Park, J. C., & Sim, S. J. (2010) · Bioresource Technology · doi:10.1016/j.biortech.2010.04.053 · Cited by 286

On the application of ionic liquids for rechargeable Li batteries: High voltage systems

Borgel, V., Markevich, E., Aurbach, D., Semrau, G., & Schmidt, M. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.08.099 · Cited by 281

Force Fields for Studying the Structure and Dynamics of Ionic Liquids: A Critical Review of Recent Developments

Dommert, F., Wendler, K., Berger, R., Delle Site, L., & Holm, C. (2012) · ChemPhysChem · doi:10.1002/cphc.201100997 · Cited by 277

Water as an efficient medium for the synthesis of cyclic carbonate

Sun, J., Ren, J., Zhang, S., & Cheng, W. (2009) · Tetrahedron Letters · doi:10.1016/j.tetlet.2008.11.034 · Cited by 273

A Simple AIMD Approach to Derive Atomic Charges for Condensed Phase Simulation of Ionic Liquids

Zhang, Y., & Maginn, E. J. (2012) · The Journal of Physical Chemistry B · doi:10.1021/jp3037999 · Cited by 271

Evaluation of Cation−Anion Interaction Strength in Ionic Liquids

Fernandes, A. M., Rocha, M. A. A., Freire, M. G., Marrucho, I. M., Coutinho, J. A. P., & Santos, L. M. N. B. F. (2011) · The Journal of Physical Chemistry B · doi:10.1021/jp201084x · Cited by 266

How to Predict the Physical Properties of Ionic Liquids: A Volume‐Based Approach

Slattery, J. M., Daguenet, C., Dyson, P. J., Schubert, T. J. S., & Krossing, I. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200700941 · Cited by 263

Novel renewable ionic liquids as highly effective solvents for pretreatment of rice straw biomass by selective removal of lignin

Hou, X., Smith, T. J., Li, N., & Zong, M. (2012) · Biotechnology and Bioengineering · doi:10.1002/bit.24522 · Cited by 262

Factors governing dissolution process of lignocellulosic biomass in ionic liquid: Current status, overview and challenges

Badgujar, K. C., & Bhanage, B. M. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2014.09.138 · Cited by 256

Transition of Ionic Liquid [bmim][PF6] from Liquid to High-Melting-Point Crystal When Confined in Multiwalled Carbon Nanotubes

Chen, S., Wu, G., Sha, M., & Huang, S. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067972c · Cited by 252

Probing molecular interaction in ionic liquids by low frequency spectroscopy: Coulomb energy, hydrogen bonding and dispersion forces

Fumino, K., Reimann, S., & Ludwig, R. (2014) · Phys. Chem. Chem. Phys. · doi:10.1039/c4cp01476f · Cited by 249

Cation does matter: how cationic structure affects the dissolution of cellulose in ionic liquids

Lu, B., Xu, A., & Wang, J. (2014) · Green Chem. · doi:10.1039/c3gc41733f · Cited by 248

Side reaction of cellulose with common 1-alkyl-3-methylimidazolium-based ionic liquids

Ebner, G., Schiehser, S., Potthast, A., & Rosenau, T. (2008) · Tetrahedron Letters · doi:10.1016/j.tetlet.2008.10.052 · Cited by 247

Gaseous Supramolecules of Imidazolium Ionic Liquids: “Magic” Numbers and Intrinsic Strengths of Hydrogen Bonds

Gozzo, F. C., Santos, L. S., Augusti, R., Consorti, C. S., Dupont, J., & Eberlin, M. N. (2004) · Chemistry – A European Journal · doi:10.1002/chem.200305742 · Cited by 246

Deposition of metal films on an ionic liquid as a basis for a lunar telescope

Borra, E. F., Seddiki, O., Angel, R., Eisenstein, D., Hickson, P., Seddon, K. R., & Worden, S. P. (2007) · Nature · doi:10.1038/nature05909 · Cited by 234

Reflections on ionic liquids

Rogers, R. D. (2007) · Nature · doi:10.1038/447917a · Cited by 225

Raman and ab Initio Studies of Simple and Binary 1-Alkyl-3-methylimidazolium Ionic Liquids

Berg, R. W., Deetlefs, M., Seddon, K. R., Shim, I., & Thompson, J. M. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp050691r · Cited by 225

Competitive pi interactions and hydrogen bonding within imidazolium ionic liquids

Matthews, R. P., Welton, T., & Hunt, P. A. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54672a · Cited by 218

Quaternary ammonium zinc- or tin-containing ionic liquids: water insensitive, recyclable catalysts for Diels–Alder reactions

Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2002) · Green Chemistry · doi:10.1039/b108431c · Cited by 217

Structural Characterization of the 1-Butyl-3-methylimidazolium Chloride Ion Pair Using ab Initio Methods

Hunt, P. A., & Gould, I. R. (2006) · The Journal of Physical Chemistry A · doi:10.1021/jp0547865 · Cited by 209

Hydrogen-bond acceptor abilities of tetrachlorometalate(II) complexes in ionic liquids

Hitchcock, P. B., Seddon, K. R., & Welton, T. (1993) · Journal of the Chemical Society, Dalton Transactions · doi:10.1039/dt9930002639 · Cited by 196

How Water Dissolves in Protic Ionic Liquids

Hayes, R., Imberti, S., Warr, G. G., & Atkin, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201973 · Cited by 193

Acid-free, organocatalytic acetalization

Kotke, M., & Schreiner, P. R. (2006) · Tetrahedron · doi:10.1016/j.tet.2005.09.079 · Cited by 192

Intermolecular Forces in an Ionic Liquid ([Mmim][Cl]) versus Those in a Typical Salt (NaCl)

Zahn, S., Uhlig, F., Thar, J., Spickermann, C., & Kirchner, B. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705526 · Cited by 189

Analyzing the interaction energies between cation and anion in ionic liquids: The subtle balance between Coulomb forces and hydrogen bonding

Fumino, K., & Ludwig, R. (2014) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2013.07.009 · Cited by 188

Imidazolium Salt Ion Pairs in Solution

Stassen, H. K., Ludwig, R., Wulf, A., & Dupont, J. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500239 · Cited by 179

Structure of Ionic Liquid−Benzene Mixtures

Deetlefs, M., Hardacre, C., Nieuwenhuyzen, M., Sheppard, O., & Soper, A. K. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp047742p · Cited by 167

Transport properties in a family of dialkylimidazolium ionic liquids

Every, H. A., Bishop, A. G., MacFarlane, D. R., Orädd, G., & Forsyth, M. (2004) · Phys. Chem. Chem. Phys. · doi:10.1039/b315813f · Cited by 163

Nature of Hydrogen Bonding in Charged Hydrogen-Bonded Complexes and Imidazolium-Based Ionic Liquids

Izgorodina, E. I., & MacFarlane, D. R. (2011) · The Journal of Physical Chemistry B · doi:10.1021/jp208150b · Cited by 158

Reversible CO2 Capture by Unexpected Plastic-, Resin-, and Gel-like Ionic Soft Materials Discovered during the Combi-Click Generation of a TSIL Library

Soutullo, M. D., Odom, C. I., Wicker, B. F., Henderson, C. N., Stenson, A. C., & Davis, J. H. (2007) · Chemistry of Materials · doi:10.1021/cm0705690 · Cited by 157

On the Molecular Origins of Biomass Recalcitrance: The Interaction Network and Solvation Structures of Cellulose Microfibrils

Gross, A. S., & Chu, J. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp106452m · Cited by 157

Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates

Wang, J., Sun, J. Q., Cheng, W., Dong, K., Zhang, X., & Zhang, S. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp41698k · Cited by 155

How Strong Is Hydrogen Bonding in Ionic Liquids? Combined X-ray Crystallographic, Infrared/Raman Spectroscopic, and Density Functional Theory Study

Katsyuba, S. A., Vener, M. V., Zvereva, E. E., Fei, Z., Scopelliti, R., Laurenczy, G., Yan, N., Păunescu, E., & Dyson, P. J. (2013) · The Journal of Physical Chemistry B · doi:10.1021/jp405255w · Cited by 151

Electrical double layer in ionic liquids: Structural transitions from multilayer to monolayer structure at the interface

Kirchner, K., Kirchner, T., Ivaništšev, V., & Fedorov, M. V. (2013) · Electrochimica Acta · doi:10.1016/j.electacta.2013.05.049 · Cited by 146

Dissecting Force Interactions in Cellulose Deconstruction Reveals the Required Solvent Versatility for Overcoming Biomass Recalcitrance

Cho, H. M., Gross, A. S., & Chu, J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2046155 · Cited by 146

Thermal effect on C–H stretching vibrations of the imidazolium ring in ionic liquids

Yokozeki, A., Kasprzak, D. J., & Shiflett, M. B. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b706497g · Cited by 138

Structure and Dynamics of 1-Ethyl-3-methylimidazolium Acetate via Molecular Dynamics and Neutron Diffraction

Bowron, D. T., D’Agostino, C., Gladden, L. F., Hardacre, C., Holbrey, J. D., Lagunas, M. C., McGregor, J., Mantle, M. D., Mullan, C. L., & Youngs, T. G. A. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp102180q · Cited by 135

Neutron diffraction, NMR and molecular dynamics study of glucose dissolved in the ionic liquid 1-ethyl-3-methylimidazolium acetate

Youngs, T. G. A., Holbrey, J. D., Mullan, C. L., Norman, S. E., Lagunas, M. C., D’Agostino, C., Mantle, M. D., Gladden, L. F., Bowron, D. T., & Hardacre, C. (2011) · Chemical Science · doi:10.1039/c1sc00241d · Cited by 135

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Gupta, K. M., Hu, Z., & Jiang, J. (2013) · RSC Advances · doi:10.1039/c3ra40807h · Cited by 84

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Matsumoto, K., Hagiwara, R., Mazej, Z., Benkič, P., & Žemva, B. (2006) · Solid State Sciences · doi:10.1016/j.solidstatesciences.2005.12.018 · Cited by 77

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Allen, M., Evans, D. F., & Lumry, R. W. (1985) · Journal of Solution Chemistry · doi:10.1007/bf00649520 · Cited by 67

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He, H., Chen, H., Zheng, Y.-Z., Zhang, S., & Yu, Z. (2014) · Chemical Engineering Science · doi:10.1016/j.ces.2014.07.024 · Cited by 44

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Yao, Y., Li, Y., Liu, X., Zhang, X., Wang, J., Yao, X., & Zhang, S. (2015) · Chinese Journal of Chemical Engineering · doi:10.1016/j.cjche.2015.07.018 · Cited by 43

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Zhu, A., Liu, R., Li, L., Li, L., Wang, L., & Wang, J. (2012) · Catalysis Today · doi:10.1016/j.cattod.2012.06.006 · Cited by 40

Characterization of lyotropic liquid crystals formed in the mixtures of 1-alkyl-3-methylimidazolium bromide/p-xylene/water

Li, X., Zhang, J., Dong, B., Zheng, L., & Tung, C. (2008) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2008.10.031 · Cited by 40

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Lauw, Y., Horne, M. D., Rodopoulos, T., Webster, N. A. S., Minofar, B., & Nelson, A. R. J. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b916046a · Cited by 39

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Mamontov, E., Baker, G. A., Luo, H., & Dai, S. (2011) · ChemPhysChem · doi:10.1002/cphc.201001017 · Cited by 37

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