Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO2hydrogenation, and methane and alcohol reforming

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering

Huber, G. W., Iborra, S., & Corma, A. (2006) · Chemical Reviews · doi:10.1021/cr068360d · Cited by 7,664

Catalytic Properties of Ceria and CeO2-Containing Materials

TROVARELLI, A. (1996) · Catalysis Reviews · doi:10.1080/01614949608006464 · Cited by 3,495

A review of dry (CO2) reforming of methane over noble metal catalysts

Pakhare, D., & Spivey, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60395d · Cited by 2,159

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2

Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., et al. (2014) · Science · doi:10.1126/science.1253057 · Cited by 1,452

Catalysis by Ceria and Related Materials

Trovarelli, A., & Fornasiero, P. (2002) · Catalytic science series · doi:10.1142/9781860949654 · Cited by 1,148

Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment

Paier, J., Penschke, C., & Sauer, J. (2013) · Chemical Reviews · doi:10.1021/cr3004949 · Cited by 1,075

Activity of CeO x and TiO x Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction

Rodriguez, J. A., Ma, S., Liu, P., Hrbek, J., Evans, J., & Pérez, M. (2007) · Science · doi:10.1126/science.1150038 · Cited by 1,002

On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper

Gokhale, A. A., Dumesic, J. A., & Mavrikakis, M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja0768237 · Cited by 984

Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding

Farmer, J. A., & Campbell, C. T. (2010) · Science · doi:10.1126/science.1191778 · Cited by 964

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles

Vayssilov, G. N., Lykhach, Y., Migani, A., Staudt, T., Petrova, G. P., Tsud, N., Skála, T., Bruix, A., Illas, F., Prince, K. C., et al. (2011) · Nature Materials · doi:10.1038/nmat2976 · Cited by 889

A New Type of Strong Metal–Support Interaction and the Production of H2 through the Transformation of Water on Pt/CeO2(111) and Pt/CeOx/TiO2(110) Catalysts

Bruix, A., Rodriguez, J. A., Ramírez, P. J., Senanayake, S. D., Evans, J., Park, J. B., Stacchiola, D., Liu, P., Hrbek, J., & Illas, F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302070k · Cited by 839

Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation

Mattos, L. V., Jacobs, G., Davis, B. H., & Noronha, F. B. (2012) · Chemical Reviews · doi:10.1021/cr2000114 · Cited by 770

The surface chemistry of cerium oxide

Mullins, D. R. (2015) · Surface Science Reports · doi:10.1016/j.surfrep.2014.12.001 · Cited by 684

Methane Activation by Heterogeneous Catalysis

Horn, R., & Schlögl, R. (2015) · Catalysis Letters · doi:10.1007/s10562-014-1417-z · Cited by 650

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al2O3 Catalysts Induced by Strong Metal–Support Interactions

Lunkenbein, T., Schumann, J., Behrens, M., Schlögl, R., & Willinger, M. G. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201411581 · Cited by 608

Recent conceptual advances in the catalysis science of mixed metal oxide catalytic materials

Wachs, I. E. (2005) · Catalysis Today · doi:10.1016/j.cattod.2004.12.019 · Cited by 569

Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming

Llorca, J., Homs, N., Sales, J., & de la Piscina, P. R. (2002) · Journal of Catalysis · doi:10.1006/jcat.2002.3643 · Cited by 538

Morphology Dependence of Catalytic Properties of Ni/CeO2 Nanostructures for Carbon Dioxide Reforming of Methane

Du, X., Zhang, D., Shi, L., Gao, R., & Zhang, J. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp300543r · Cited by 513

Enhanced Carbon-Resistant Dry Reforming Fe-Ni Catalyst: Role of Fe

Theofanidis, S. A., Galvita, V. V., Poelman, H., & Marin, G. B. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00357 · Cited by 508

Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000$\bar 1$): Intrinsic Activity and Importance of Support Interactions

Rodriguez, J. A., Liu, P., Hrbek, J., Evans, J., & Pérez, M. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200603931 · Cited by 495

Gold catalysts for pure hydrogen production in the water–gas shift reaction: activity, structure and reaction mechanism

Burch, R. (2006) · Phys. Chem. Chem. Phys. · doi:10.1039/b607837k · Cited by 458

Redox properties of water on the oxidized and reduced surfaces of CeO2

Henderson, M. A., Perkins, C. L., Engelhard, M., Thevuthasan, S., & Peden, C. H. F. (2003) · Surface Science · doi:10.1016/s0039-6028(02)02657-2 · Cited by 434

Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity

Yoshihara, J., & Campbell, C. T. (1996) · Journal of Catalysis · doi:10.1006/jcat.1996.0240 · Cited by 417

Dry Reforming of Methane on a Highly‐Active Ni‐CeO2 Catalyst: Effects of Metal‐Support Interactions on C−H Bond Breaking

Liu, Z., Grinter, D. C., Lustemberg, P. G., Nguyen‐Phan, T., Zhou, Y., Luo, S., Waluyo, I., Crumlin, E. J., Stacchiola, D. J., Zhou, J., et al. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602489 · Cited by 412

Supported metal oxide and other catalysts for ethane conversion: a review

Bañares, M. Á. (1999) · Catalysis Today · doi:10.1016/s0920-5861(99)00053-x · Cited by 393

H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts

Frusteri, F., Freni, S., Spadaro, L., Chiodo, V., Bonura, G., Donato, S., & Cavallaro, S. (2004) · Catalysis Communications · doi:10.1016/j.catcom.2004.07.015 · Cited by 321

Importance of the Metal–Oxide Interface in Catalysis: In Situ Studies of the Water–Gas Shift Reaction by Ambient‐Pressure X‐ray Photoelectron Spectroscopy

Mudiyanselage, K., Senanayake, S. D., Feria, L., Kundu, S., Baber, A. E., Graciani, J., Vidal, A. B., Agnoli, S., Evans, J., Chang, R., et al. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201210077 · Cited by 321

Water‐Gas Shift Reaction on a Highly Active Inverse CeOx/Cu(111) Catalyst: Unique Role of Ceria Nanoparticles

Rodriguez, J. A., Graciani, J., Evans, J., Park, J. B., Yang, F., Stacchiola, D., Senanayake, S. D., Ma, S., Pérez, M., Liu, P., et al. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200903918 · Cited by 303

Use of biofuels to produce hydrogen (reformation processes)

Piscina, P. R. D. L., & Homs, N. (2008) · Chemical Society Reviews · doi:10.1039/b712181b · Cited by 288

High catalytic activity of Au/CeO x /TiO 2 (110) controlled by the nature of the mixed-metal oxide at the nanometer level

Park, J. B., Graciani, J., Evans, J., Stacchiola, D., Ma, S., Liu, P., Nambu, A., Sanz, J. F., Hrbek, J., & Rodriguez, J. A. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0812604106 · Cited by 268

Kinetics and mechanism of the water-gas shift reaction catalysed by the clean and Cs-promoted Cu(110) surface: a comparison with Cu(111)

Nakamura, J., Campbell, J. M., & Campbell, C. T. (1990) · Journal of the Chemical Society, Faraday Transactions · doi:10.1039/ft9908602725 · Cited by 267

Ordered cerium oxide thin films grown on Ru(0001) and Ni(111)

Mullins, D. R., Radulovic, P. V., & Overbury, S. H. (1999) · Surface Science · doi:10.1016/s0039-6028(99)00369-6 · Cited by 266

Gold, Copper, and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level

Park, J. B., Graciani, J., Evans, J., Stacchiola, D., Senanayake, S. D., Barrio, L., Liu, P., Sanz, J. F., Hrbek, J., & Rodriguez, J. A. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9087677 · Cited by 260

In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO2 Catalyst: Importance of Strong Metal–Support Interactions for the Cleavage of O–H Bonds

Carrasco, J., López‐Durán, D., Liu, Z., Duchoň, T., Evans, J., Senanayake, S. D., Crumlin, E. J., Matolín, V., Rodríguez, J. A., & Ganduglia‐Pirovano, M. V. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410697 · Cited by 259

Structural and Redox Properties of Ceria in Alumina-Supported Ceria Catalyst Supports

Martínez-Arias, A., Fernández-García, M., Salamanca, L. N., Valenzuela, R. X., Conesa, J. C., & Soria, J. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp992796y · Cited by 225

Hydrogenation of CO2 to Methanol on CeOx/Cu(111) and ZnO/Cu(111) Catalysts: Role of the Metal–Oxide Interface and Importance of Ce3+ Sites

Senanayake, S. D., Ramírez, P. J., Waluyo, I., Kundu, S., Mudiyanselage, K., Liu, Z., Liu, Z., Axnanda, S., Stacchiola, D. J., Evans, J., et al. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b12012 · Cited by 223

Water Dissociation on CeO2(100) and CeO2(111) Thin Films

Mullins, D. R., Albrecht, P. M., Chen, T.-L., Calaza, F. C., Biegalski, M. D., Christen, H. M., & Overbury, S. H. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp306444h · Cited by 216

Room-Temperature Activation of Methane and Dry Re-forming with CO2 on Ni-CeO2(111) Surfaces: Effect of Ce3+ Sites and Metal–Support Interactions on C–H Bond Cleavage

Lustemberg, P. G., Ramírez, P. J., Liu, Z., Gutiérrez, R. A., Grinter, D. G., Carrasco, J., Senanayake, S. D., Rodriguez, J. A., & Ganduglia-Pirovano, M. V. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02360 · Cited by 206

Catalytic oxidation of CO by platinum group metals: from ultrahigh vacuum to elevated pressures

Santra, A. K., & Goodman, D. W. (2002) · Electrochimica Acta · doi:10.1016/s0013-4686(02)00330-4 · Cited by 190

Morphology and defect structure of the CeO2(111) films grown on Ru(0001) as studied by scanning tunneling microscopy

Lu, J.-L., Gao, H.-J., Shaikhutdinov, S., & Freund, H.-J. (2006) · Surface Science · doi:10.1016/j.susc.2006.08.023 · Cited by 174

Inverse Oxide/Metal Catalysts in Fundamental Studies and Practical Applications: A Perspective of Recent Developments

Rodriguez, J. A., Liu, P., Graciani, J., Senanayake, S. D., Grinter, D. C., Stacchiola, D., Hrbek, J., & Fernández-Sanz, J. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00499 · Cited by 168

Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies

Rodríguez, J. A., & Hrbek, J. (2009) · Surface Science · doi:10.1016/j.susc.2009.11.038 · Cited by 154

Growth of Pt Nanoparticles on Reducible CeO2(111) Thin Films: Effect of Nanostructures and Redox Properties of Ceria

Zhou, Y., Perket, J. M., & Zhou, J. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1007279 · Cited by 136

High Activity of Ce1−xNixO2−y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal–Oxide Interactions

Zhou, G., Barrio, L., Agnoli, S., Senanayake, S. D., Evans, J., Kubacka, A., Estrella, M. A., Hanson, J. C., Martínez-Arias, A., Fernández–García, M., et al. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004966 · Cited by 136

Water Chemistry on Model Ceria and Pt/Ceria Catalysts

Lykhach, Y., Johánek, V., Aleksandrov, H. A., et al. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp302229x · Cited by 132

Water–Gas Shift and CO Methanation Reactions over Ni–CeO2(111) Catalysts

Senanayake, S. D., Evans, J., Agnoli, S., Barrio, L., Chen, T.-L., Hrbek, J., & Rodríguez, J. A. (2011) · Topics in Catalysis · doi:10.1007/s11244-011-9645-6 · Cited by 125

Theoretical Studies of the Adsorption of CO and C on Ni(111) and Ni/CeO2(111): Evidence of a Strong Metal–Support Interaction

Carrasco, J., Barrio, L., Liu, P., Rodríguez, J. A., & Ganduglia-Pirovano, M. V. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp400430r · Cited by 124

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO 2 (111) catalysts: an in situ study of C–C and O–H bond scission

Liu, Z., Duchoň, T., Wang, H., Grinter, D. C., Waluyo, I., Zhou, J., Liu, Q., Jeong, B., Crumlin, E. J., Matolín, V., et al. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp01212d · Cited by 114

Gold supported on well-ordered ceria films: nucleation, growth and morphology in CO oxidation reaction

Lu, J., Gao, H., Shaikhutdinov, S. K., & Freund, H. ‐. (2007) · Catalysis Letters · doi:10.1007/s10562-007-9039-3 · Cited by 113

Effects of Reaction Temperature and Support Composition on the Mechanism of Water–Gas Shift Reaction over Supported-Pt Catalysts

Kalamaras, C. M., Gonzalez‐Jimenez, I. D., Navarro, R. M., Fierro, J. L. G., & Efstathiou, A. M. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp201773a · Cited by 102

The growth, structure and stability of ceria overlayers on Pd(111)

Alexandrou, M., & Nix, R. M. (1994) · Surface Science · doi:10.1016/0039-6028(94)90025-6 · Cited by 96

Cerium oxides and cerium-platinum surface alloys on Pt(111) single-crystal surfaces studied by scanning tunneling microscopy

Berner, U., & Schierbaum, K. D. (2002) · Physical review. B, Condensed matter · doi:10.1103/physrevb.65.235404 · Cited by 91

Modeling Ceria-Based Nanomaterials for Catalysis and Related Applications

Bruix, A., & Neyman, K. M. (2016) · Catalysis Letters · doi:10.1007/s10562-016-1799-1 · Cited by 83

Mechanism for the water–gas shift reaction on monofunctional platinum and cause of catalyst deactivation

Flaherty, D. W., Yu, W., Pozun, Z. D., Henkelman, G., & Mullins, C. B. (2011) · Journal of Catalysis · doi:10.1016/j.jcat.2011.06.024 · Cited by 70

Ultrathin ordered CeO2 overlayers on Pt(111): interaction with NO2, NO, H2O and CO

Berner, U., Schierbaum, K. D., Jones, G., Wincott, P. L., Haq, S., & Thornton, G. (2000) · Surface Science · doi:10.1016/s0039-6028(00)00770-6 · Cited by 69

Effect of Ceria on Gold–Titania Catalysts for the Water–Gas Shift Reaction: Fundamental Studies for Au/CeOx/TiO2(110) and Au/CeOx/TiO2 Powders

Si, R., Tao, J., Evans, J., Park, J. B., Barrio, L., Hanson, J. C., Zhu, Y., Hrbek, J., & Rodríguez, J. A. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3089325 · Cited by 67

WGS and CO-PrOx reactions using gold promoted copper-ceria catalysts: “Bulk CuO CeO2 vs. CuO CeO2/Al2O3 with low mixed oxide content”

Reina, T. R., Ivanova, S., Laguna, O. H., Centeno, M. Á., & Odriozola, J. A. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.03.022 · Cited by 64

Cu Deposited on CeOx-Modified TiO2(110): Synergistic Effects at the Metal–Oxide Interface and the Mechanism of the WGS Reaction

Plata, J. J., Graciani, J., Evans, J., Rodríguez, J. A., & Sanz, J. F. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00948 · Cited by 55

Nanopattering in CeOx/Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity

Senanayake, S. D., Sadowski, J. T., Evans, J., Kundu, S., Agnoli, S., Yang, F., Stacchiola, D. J., Flege, J. I., Hrbek, J., & Rodríguez, J. A. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz300159p · Cited by 44

Active gold-ceria and gold-ceria/titania catalysts for CO oxidation: From single-crystal model catalysts to powder catalysts

Rodríguez, J. A., Si, R., Evans, J., et al. (2014) · Catalysis Today · doi:10.1016/j.cattod.2014.06.033 · Cited by 30

Reduction of thin-film ceria on Pt(111) by supported Pd nanoparticles probed with resonant photoemission

Matharu, J., Cabailh, G., Lindsay, R., et al. (2011) · Surface Science · doi:10.1016/j.susc.2011.03.005 · Cited by 25

Experimental and Theoretical Study on the Electronic Interaction between Rh Adatoms and CeOx Substrate in Dependence on a Degree of Cerium Oxide Reduction

Ševčíková, K., Szabová, L., Kettner, M., Homola, P., Tsud, N., Fabris, S., Matolín, V., & Nehasil, V. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b11431 · Cited by 24

Interaction of tungsten with CeO2(111) layers as a function of temperature: a photoelectron spectroscopy study

Škála, T., Tsud, N., Prince, K. C., & Matolín, V. (2011) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/23/21/215001 · Cited by 19

In situ growth, structure, and real-time chemical reactivity of well-defined CeOx-Ru(0001) model surfaces

Grinter, D. C., Senanayake, S. D., & Flege, J. I. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.02.043 · Cited by 19

The Mechanism of Hydrocarbon Oxygenate Reforming: CC Bond Scission, Carbon Formation, and Noble‐Metal‐Free Oxide Catalysts

Lykhach, Y., Neitzel, A., Ševčíková, K., Johánek, V., Tsud, N., Škála, T., Prince, K. C., Matolín, V., & Libuda, J. (2013) · ChemSusChem · doi:10.1002/cssc.201301000 · Cited by 12

Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?

Trovarelli, A., & Llorca, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01246 · Cited by 781

Structure of the catalytically active copper–ceria interfacial perimeter

Chen, A., Yu, X., Zhou, Y., Miao, S., Li, Y., Kuld, S., Sehested, J., Liu, J., Aoki, T., Hong, S., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0226-6 · Cited by 655

Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal–Support Interaction

Li, S., Xu, Y., Chen, Y., Li, W., Lin, L., Li, M., Deng, Y., Wang, X., Ge, B., Yang, C., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201705002 · Cited by 523

State of art review on conventional and advanced pyrolysis of macroalgae and microalgae for biochar, bio-oil and bio-syngas production

Lee, X. J., Ong, H. C., Gan, Y. Y., Chen, W.-H., & Mahlia, T. M. I. (2020) · Energy Conversion and Management · doi:10.1016/j.enconman.2020.112707 · Cited by 465

CO2 Hydrogenation to Methanol over ZrO2-Containing Catalysts: Insights into ZrO2 Induced Synergy

Li, K., & Chen, J. G. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01943 · Cited by 440