Enhanced electrocatalytic performance for the hydrogen evolution reaction through surface enrichment of platinum nanoclusters alloying with ruthenium in situ embedded in carbon

Solar Water Splitting Cells

Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388

Sustainable Hydrogen Production

Turner, J. A. (2004) · Science · doi:10.1126/science.1103197 · Cited by 6,602

Trends in the exchange current for hydrogen evolution

Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121

Alternative energy technologies

Dresselhaus, M. S., & Thomas, I. L. (2001) · Nature · doi:10.1038/35104599 · Cited by 4,894

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices

McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145

Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces

Stamenkovic, V. R., Mun, B. S., Arenz, M., Mayrhofer, K. J. J., Lucas, C. A., Wang, G., Ross, P. N., & Markovic, N. M. (2007) · Nature Materials · doi:10.1038/nmat1840 · Cited by 3,252

Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies

Li, H., Tsai, C., Koh, A. L., Cai, L., Contryman, A. W., Fragapane, A. H., Zhao, J., Han, H. S., Manoharan, H. C., Abild-Pedersen, F., et al. (2016) · Nature Materials · doi:10.1038/nmat4465 · Cited by 2,529

Recent Trends and Perspectives in Electrochemical Water Splitting with an Emphasis on Sulfide, Selenide, and Phosphide Catalysts of Fe, Co, and Ni: A Review

Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503

Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution

Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437

An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction

Mahmood, J., Li, F., Jung, S.-M., Okyay, M. S., Ahmad, I., Kim, S.-J., Park, N., Jeong, H. Y., & Baek, J.-B. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2016.304 · Cited by 1,685

CoSe 2 Nanoparticles Grown on Carbon Fiber Paper: An Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction

Kong, D., Wang, H., Lu, Z., & Cui, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501497n · Cited by 1,392

Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction

Xiao, P., Sk, M. A., Thia, L., Ge, X., Lim, R. J., Wang, J.-Y., Lim, K. H., & Wang, X. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00957f · Cited by 1,297

Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction

Zeng, M., & Li, Y. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02974k · Cited by 1,294

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen

Alayoglu, S., Nilekar, A. U., Mavrikakis, M., & Eichhorn, B. (2008) · Nature Materials · doi:10.1038/nmat2156 · Cited by 1,245

MoS2–Ni3S2 Heteronanorods as Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting

Yang, Y., Zhang, K., Lin, H., Li, X., Chan, H. C., Yang, L., & Gao, Q. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03192 · Cited by 1,150

High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst

Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Jaroniec, M., & Qiao, S.-Z. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11291 · Cited by 1,110

Infrared Regulating Smart Window Based on Organic Materials

Khandelwal, H., Schenning, A. P. H. J., & Debije, M. G. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602209 · Cited by 1,027

Instability of Supported Platinum Nanoparticles in Low-Temperature Fuel Cells

Shao-Horn, Y., Sheng, W. C., Chen, S., Ferreira, P. J., Holby, E. F., & Morgan, D. (2007) · Topics in Catalysis · doi:10.1007/s11244-007-9000-0 · Cited by 939

Highly active and durable non-precious-metal catalysts encapsulated in carbon nanotubes for hydrogen evolution reaction

Deng, J., Ren, P., Deng, D., Yu, L., Yang, F., & Bao, X. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00370e · Cited by 938

Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications

Chen, A., & Ostrom, C. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00324 · Cited by 879

Single layer graphene encapsulating non-precious metals as high-performance electrocatalysts for water oxidation

Cui, X., Ren, P., Deng, D., Deng, J., & Bao, X. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03316k · Cited by 791

Electrocatalytic properties of transition metal oxides for oxygen evolution reaction

Matsumoto, Y., & Sato, E. (1986) · Materials Chemistry and Physics · doi:10.1016/0254-0584(86)90045-3 · Cited by 717

Carbon-Supported Pt and PtRu Nanoparticles as Catalysts for a Direct Methanol Fuel Cell

Liu, Z., Ling, X. Y., Su, X., & Lee, J. Y. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp049422b · Cited by 688

RuP2‐Based Catalysts with Platinum‐like Activity and Higher Durability for the Hydrogen Evolution Reaction at All pH Values

Pu, Z., Amiinu, I. S., Kou, Z., Li, W., & Mu, S. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704911 · Cited by 671

Sub-Micron Polymeric Stomatocytes as Promising Templates for Confined Crystallization and Diffraction Experiments

Adawy, A., Amghouz, Z., van Hest, J. C. M., & Wilson, D. A. (2017) · Small · doi:10.1002/smll.201700642 · Cited by 629

Amorphous Molybdenum Sulfides as Hydrogen Evolution Catalysts

Morales-Guio, C. G., & Hu, X. (2014) · Accounts of Chemical Research · doi:10.1021/ar5002022 · Cited by 605

Non-precious alloy encapsulated in nitrogen-doped graphene layers derived from MOFs as an active and durable hydrogen evolution reaction catalyst

Yang, Y., Lun, Z., Xia, G., Zheng, F., He, M., & Chen, Q. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02460a · Cited by 562

Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values

Liu, T., Ma, X., Liu, D., Hao, S., Du, G., Ma, Y., Asiri, A. M., Sun, X., & Chen, L. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b02849 · Cited by 511

Supramolecular Adaptive Nanomotors with Magnetotaxis Behavior

Peng, F., Tu, Y., Men, Y., van Hest, J. C. M., & Wilson, D. A. (2017) · Advanced Materials · doi:10.1002/adma.201604996 · Cited by 505

A general approach to cobalt-based homobimetallic phosphide ultrathin nanosheets for highly efficient oxygen evolution in alkaline media

Xiao, X., He, C.-T., Zhao, S., Li, J., Lin, W., Yuan, Z., Zhang, Q., Wang, S., Dai, L., & Yu, D. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03145e · Cited by 450

Towards identifying the active sites on RuO2(110) in catalyzing oxygen evolution

Rao, R. R., Kolb, M. J., Halck, N. B., Pedersen, A. F., Mehta, A., You, H., Stoerzinger, K. A., Feng, Z., Hansen, H. A., Zhou, H., et al. (2017) · Energy & Environmental Science · doi:10.1039/c7ee02307c · Cited by 447

Dissolution of Platinum: Limits for the Deployment of Electrochemical Energy Conversion?

Topalov, A. A., Katsounaros, I., Auinger, M., Cherevko, S., Meier, J. C., Klemm, S. O., & Mayrhofer, K. J. J. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207256 · Cited by 428

A reversible lithium–CO2 battery with Ru nanoparticles as a cathode catalyst

Yang, S., Qiao, Y., He, P., Liu, Y., Cheng, Z., Zhu, J.-J., & Zhou, H. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03770d · Cited by 421

Free-Standing Two-Dimensional Ru Nanosheets with High Activity toward Water Splitting

Kong, X., Xu, K., Zhang, C., Dai, J., Norooz Oliaee, S., Li, L., Zeng, X., Wu, C., & Peng, Z. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02730 · Cited by 324

Nanosized Metal Phosphides Embedded in Nitrogen‐Doped Porous Carbon Nanofibers for Enhanced Hydrogen Evolution at All pH Values

Wang, M., Ye, C., Liu, H., Xu, M., & Bao, S. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710150 · Cited by 320

A New Core/Shell NiAu/Au Nanoparticle Catalyst with Pt-like Activity for Hydrogen Evolution Reaction

Lv, H., Xi, Z., Chen, Z., Guo, S., Yu, Y., Zhu, W., Li, Q., Zhang, X., Pan, M., Lu, G., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01100 · Cited by 313

Enhancing electrocatalytic total water splitting at few layer Pt-NiFe layered double hydroxide interfaces

Anantharaj, S., Karthick, K., Venkatesh, M., Simha, T. V. S. V., Salunke, A. S., Ma, L., Liang, H., & Kundu, S. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.06.027 · Cited by 291

Tungsten Carbide Microspheres as a Noble‐Metal‐Economic Electrocatalyst for Methanol Oxidation

Ganesan, R., & Lee, J. S. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501272 · Cited by 268

Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst

Brankovic, S. R., Wang, J. X., & Adžić, R. R. (2001) · Electrochemical and Solid-State Letters · doi:10.1149/1.1414943 · Cited by 210

Trimetallic TriStar Nanostructures: Tuning Electronic and Surface Structures for Enhanced Electrocatalytic Hydrogen Evolution

Du, N., Wang, C., Wang, X., Lin, Y., Jiang, J., & Xiong, Y. (2016) · Advanced Materials · doi:10.1002/adma.201504785 · Cited by 204

Ultrafine Pt Nanoclusters Confined in a Calixarene-Based {Ni24} Coordination Cage for High-Efficient Hydrogen Evolution Reaction

Wang, S., Gao, X., Hang, X., Zhu, X., Han, H., Liao, W., & Chen, W. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11218 · Cited by 202

Ultrahigh stable carbon riveted Pt/TiO2–C catalyst prepared by in situ carbonized glucose for proton exchange membrane fuel cell

Jiang, Z.-Z., Wang, Z.-B., Chu, Y.-Y., Gu, D.-M., & Yin, G.-P. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00475h · Cited by 201

Vapor–solid synthesis of monolithic single-crystalline CoP nanowire electrodes for efficient and robust water electrolysis

Li, W., Gao, X., Xiong, D., Xia, F., Liu, J., Song, W.-G., Xu, J., Thalluri, S. M., Cerqueira, M. F., Fu, X., et al. (2017) · Chemical Science · doi:10.1039/c6sc05167g · Cited by 173

Carbon Monoxide Hydrogenation on the Ru(001) Surface at Low Temperature Using Gas-Phase Atomic Hydrogen: Spectroscopic Evidence for the Carbonyl Insertion Mechanism on a Transition Metal Surface

Mitchell, W. J., Xie, J., Jachimowski, T. A., & Weinberg, W. H. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00114a025 · Cited by 165

A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate

Machan, C. W., Sampson, M. D., & Kubiak, C. P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03913 · Cited by 160

Unraveling Thermodynamics, Stability, and Oxygen Evolution Activity of Strontium Ruthenium Perovskite Oxide

Kim, B., Abbott, D. F., Cheng, X., Fabbri, E., Nachtegaal, M., Bozza, F., Castelli, I. E., Lebedev, D., Schäublin, R. E., Copéret, C., et al. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03171 · Cited by 158

A CO 2 adsorption-enhanced semiconductor/metal-complex hybrid photoelectrocatalytic interface for efficient formate production

Huang, X., Shen, Q., Liu, J., Yang, N., & Zhao, G. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00968a · Cited by 155

Enhanced Activity for Hydrogen Evolution Reaction over CoFe Catalysts by Alloying with Small Amount of Pt

Chen, J., Yang, Y., Su, J., Jiang, P., Xia, G., & Chen, Q. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b12065 · Cited by 146

Excavated octahedral Pt-Co alloy nanocrystals built with ultrathin nanosheets as superior multifunctional electrocatalysts for energy conversion applications

Chen, Q., Cao, Z., Du, G., Kuang, Q., Huang, J. S., Xie, Z., & Zheng, L. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.07.041 · Cited by 142

Mechanism of Catalyst Degradation in Proton Exchange Membrane Fuel Cells

Virkar, A. V., & Zhou, Y. (2007) · Journal of The Electrochemical Society · doi:10.1149/1.2722563 · Cited by 133

Facet-controlled hollow Rh 2 S 3 hexagonal nanoprisms as highly active and structurally robust catalysts toward hydrogen evolution reaction

Yoon, D., Seo, B., Lee, J., Nam, K. S., Kim, B., Park, S. H., Baik, H., Joo, S. H., & Lee, K. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03456f · Cited by 129

PdCu@Pd Nanocube with Pt-like Activity for Hydrogen Evolution Reaction

Li, J., Li, F., Guo, S., Zhang, J., & Ma, J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b01241 · Cited by 129

High Performance Electrocatalytic Reaction of Hydrogen and Oxygen on Ruthenium Nanoclusters

Ye, R., Liu, Y., Peng, Z., Wang, T., Jalilov, A. S., Yakobson, B. I., Wei, S., & Tour, J. M. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b15725 · Cited by 120

Catalysis in Electrochemistry: From Fundamentals to Strategies for Fuel Cell Development

(2011) · Wiley eBooks · doi:10.1002/9780470929421 · Cited by 103

Preparation and surface composition of tungsten carbide powders with high specific surface area

Ribeiro, F. H., BETTA, R. A. D., Guskey, G. J., et al. (1991) · Chemistry of Materials · doi:10.1021/cm00017a015 · Cited by 100

Ruthenium/Graphene-like Layered Carbon Composite as an Efficient Hydrogen Evolution Reaction Electrocatalyst

Chen, Z., Lu, J., Ai, Y., Ji, Y., Adschiri, T., & Wan, L. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b09331 · Cited by 98

Highly active and stable Pt electrocatalysts promoted by antimony-doped SnO2 supports for oxygen reduction reactions

Yin, M., Xu, J., Li, Q., Jensen, J. O., Huang, Y. J., Cleemann, L. N., Bjerrum, N. J., & Xing, W. (2013) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2013.07.007 · Cited by 95

Influence of water on elementary reaction steps in electrocatalysis

Gohda, Y., Schnur, S., & Groß, A. (2008) · Faraday Discussions · doi:10.1039/b802270d · Cited by 84

Facile solvothermal synthesis of Pt 76 Co 24 nanomyriapods for efficient electrocatalysis

Jiang, L., Huang, X.-Y., Wang, A., Li, X., Yuan, J., & Feng, J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta01976a · Cited by 64

Surface Confinement Etching and Polarization Matter: A New Approach To Prepare Ultrathin PtAgCo Nanosheets for Hydrogen-Evolution Reactions

Mahmood, A., Lin, H., Xie, N., & Wang, X. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b01598 · Cited by 61

Facile solvothermal synthesis of monodisperse Pt 2.6 Co 1 nanoflowers with enhanced electrocatalytic activity towards oxygen reduction and hydrogen evolution reactions

Jiang, L., Lin, X., Wang, A., Yuan, J., Feng, J., & Li, X. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.12.123 · Cited by 60

Platinum nanoparticles partially-embedded into carbon sphere surfaces: a low metal-loading anode catalyst with superior performance for direct methanol fuel cells

Li, K., Jin, Z., Ge, J., Liu, C., & Xing, W. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta06700c · Cited by 58

Cooperative water oxidation catalysis in a series of trinuclear metallosupramolecular ruthenium macrocycles

Kunz, V., Lindner, J. O., Schulze, M., Röhr, M. I. S., Schmidt, D., Mitrić, R., & Würthner, F. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01557g · Cited by 53

Double Nanoporous Structure with Nanoporous PtFe Embedded in Graphene Nanopores: Highly Efficient Bifunctional Electrocatalysts for Hydrogen Evolution and Oxygen Reduction

Zhong, X., Wang, L., Zhuang, Z., Chen, X., Zheng, J. H., Zhou, Y., Zhuang, G., Li, X., & Wang, J. (2016) · Advanced Materials Interfaces · doi:10.1002/admi.201601029 · Cited by 47

Kinetic analysis of the hydrogen electrode reaction in unbuffered media. Theory and studies on Pt microelectrodes

Arce, M. D., Bonazza, H. L., & Fernández, J. L. (2013) · Electrochimica Acta · doi:10.1016/j.electacta.2013.05.135 · Cited by 28

Micelle‐Assisted Electrodeposition of Mesoporous Fe–Pt Smooth Thin Films and their Electrocatalytic Activity towards the Hydrogen Evolution Reaction

Isarain‐Chávez, E., Baró, M. D., Alcantara, C., Pané, S., Sort, J., & Pellicer, E. (2017) · ChemSusChem · doi:10.1002/cssc.201701938 · Cited by 27

Erratum: Ruthenium-cobalt nanoalloys encapsulated in nitrogen-doped graphene as active electrocatalysts for producing hydrogen in alkaline media

Su, J., Yang, Y., Xia, G., Chen, J., Jiang, P., & Chen, Q. (2017) · Nature Communications · doi:10.1038/ncomms16029 · Cited by 20

Metallic nanostructures with low dimensionality for electrochemical water splitting

Li, L., Wang, P., Shao, Q., & Huang, X. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00013b · Cited by 1,049

Recent Advances and Prospective in Ruthenium-Based Materials for Electrochemical Water Splitting

Yu, J., He, Q., Yang, G., Zhou, W., Shao, Z., & Ni, M. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02457 · Cited by 789

Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction

Jiang, K., Liu, B., Luo, M., Ning, S., Peng, M., Zhao, Y., Lu, Y.-R., Chan, T.-S., de Groot, F. M. F., & Tan, Y. (2019) · Nature Communications · doi:10.1038/s41467-019-09765-y · Cited by 670

CoP‐Doped MOF‐Based Electrocatalyst for pH‐Universal Hydrogen Evolution Reaction

Liu, T., Li, P., Yao, N., Cheng, G., Chen, S., Luo, W., & Yin, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901409 · Cited by 606

Ruthenium anchored on carbon nanotube electrocatalyst for hydrogen production with enhanced Faradaic efficiency

Kweon, D. H., Okyay, M. S., Kim, S.-J., Jeon, J.-P., Noh, H.-J., Park, N., Mahmood, J., & Baek, J.-B. (2020) · Nature Communications · doi:10.1038/s41467-020-15069-3 · Cited by 546