Physical modification of biochar to expose the inner pores and their functional groups to enhance lead adsorption
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Biochars have been successfully used to treat wastewater and contaminated soils.
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The smaller pore sizes and lower porosity of the biochar surface shell were likely due to collisions between grains during mixing with sand, causing collapse and compression of the biochar's exterior walls and/or attached fine mineral, volatile matter, and ash after pyrolysis.
“This was likely due to collisions between grains during the mixing process with sand, causing the collapse and compression of the biochar's exterior walls and/or the attached fine mineral, volatile matter, and ash after pyrolysis (Fahmi et al., 2018) (Fig. 3(c)− (d), Fig. 4, Figure S14).”
From Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals (2025) · cites this paper as Fahmi et al., 2018
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Experimental — accuracy not yet measuredIf macropores become partially blocked, the adsorption rate and pollutant Re % significantly decrease.
“If these macropores become partially blocked, the adsorption rate and pollutant Re % significantly decrease (Fahmi et al., 2018; Mohanty et al., 2018; Pritchard et al., 2023).”
From Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals (2025) · cites this paper as Fahmi et al., 2018
The Introduction (page unavailable) says that blocked macropores reduce biochar’s heavy-metal adsorption capacity by limiting access to inner pores. It does not establish that partial blockage significantly decreases the adsorption rate or pollutant removal percentage; the Methods (page unavailable) calculates Pb removal percentage at equilibrium, not a rate of decrease caused by blockage. (LLM, conf=0.86)
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Self-citation
- Authors
- Fahmi, A. H., Samsuri, A. W., Jol, H., & Singh, D.
- Affiliations
- Universiti Putra Malaysia (MY)
- Department of Land Management
- Corresponding author
- Samsuri, Abd Wahid
- Venue
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2018
- Volume
- 8
- Issue
- 67
- Pages
- 38270-38280
- ISSN
- 2046-2069 (ISSN-L)
- PMC
- PMC9092441
- OpenAlex
- W2901528246
- Cited by
- 143
- References
- 48
- Citations by year
- 2026: 29 · 2025: 19 · 2024: 29 · 2023: 15 · 2022: 19 · 2021: 20 · 2020: 9 · 2019: 3
- FWCI
- 3.51
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- RSC Advances (publishedVersion, cc-by-nc)
- PubMed Central (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Universiti Putra Malaysia Institutional Repository (Universiti Putra Malaysia) (acceptedVersion)
- Funders
- Research Grants Council, University Grants Committee (UPM/IPS/9575800 Research Grant)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Keywords
- biochar, lead adsorption, empty fruit bunch, oil palm, particle size, pore structure, oxygen-containing functional groups, heavy metal biosorption, surface area, cation exchange capacity, zeta potential, wastewater treatment
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