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Raman Spectrum of Graphite
Abstract
Raman spectra are reported from single crystals of graphite and other graphite materials. Single crystals of graphite show one single line at 1575 cm−1. For the other materials like stress-annealed pyrolitic graphite, commercial graphites, activated charcoal, lampblack, and vitreous carbon another line is detected at 1355 cm−1. The Raman intensity of this band is inversely proportional to the crystallite size and is caused by a breakdown of the k-selection rule. The intensity of this band allows an estimate of the crystallite size in the surface layer of any carbon sample. Two in-plane force constants are calculated from the frequencies.
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Metadata
- Authors
- Tuinstra, F., & Koenig, J. L.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1970-08-01
- Volume
- 53
- Issue
- 3
- Pages
- 1126-1130
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2058272047
- Cited by
- 10,717
- References
- 0
- FWCI
- 3.78
- Type
- journal article
- Language
- en
- Open access
- closed
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