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Geochemical ice-core constraints on the timing and climatic impact of Aniakchak II (1628 BCE) and Thera (Minoan) volcanic eruptions

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Pearson, Charlotte, Sigl, Michael, Burke, Andrea, Davies, Siwan, Kurbatov, Andrei, Severi, Mirko, Cole-Dai, Jihong, Innes, Helen +2 more·2022·PNAS Nexus

Abstract

Decades of research have focused on establishing the exact year and climatic impact of the Minoan eruption of Thera, Greece (c.1680 to 1500 BCE). Ice cores offer key evidence to resolve this controversy, but attempts have been hampered by a lack of multivolcanic event synchronization between records. In this study, Antarctic and Greenland ice-core records are synchronized using a double bipolar sulfate marker, and calendar dates are assigned to each eruption revealed within the ‘Thera period’. From this global-scale sequence of volcanic sulfate loading, we derive indications toward each eruption’s latitude and potential to disrupt the climate system. Ultrafine sampling for sulfur isotopes and tephra conclusively demonstrate a colossal eruption of Alaska’s Aniakchak II as the source of stratospheric sulfate in the now precisely dated 1628 BCE ice layer. These findings end decades of speculation that Thera was responsible for the 1628 BCE event, and place Aniakchak II (52 ± 17 Tg S) and an unknown volcano at 1654 BCE (50 ± 13 Tg S) as two of the largest Northern Hemisphere sulfur injections in the last 4,000 years. This opens possibilities to explore widespread climatic impacts for contemporary societies and, in pinpointing Aniakchak II, confirms that stratospheric sulfate can be globally distributed from eruptions outside the tropics. Dating options for Thera are reduced to a series of precisely dated, constrained stratospheric sulfur injection events at 1611 BCE, 1561/1558/1555BCE, and c.1538 BCE, which are all below 14 ± 5 Tg S, indicating a climatic forcing potential for Thera well below that of Tambora (1815 CE).

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Crossref · 10.1093/pnasnexus/pgac048

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  • If it is a valid assumption to integrate the Sofular Cave evidence, then this would help more firmly to exclude as plausible some dates for possible volcanic proxy evidence around 1561/1560, 1558, 1555/1554, 1546, 1544, 1539/1538 or 1524 BCE.

    “Most importantly, if it is a valid assumption to integrate the Sofular Cave evidence, then this would help more firmly to exclude as plausible some dates for possible volcanic proxy evidence that have been suggested as potentially relevant for the Thera eruption around 1561/1560, 1558, 1555/1554, 1546, 1544, 1539/1538 or 1524 BCE [13,14].”

    From Second Intermediate Period date for the Thera (Santorini) eruption and historical implications (2022) · cites this paper as [14]

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  • Two additional volcanic events identified at 1586 BCE (Greenland) and 1550 BCE (Antarctica) are currently considered less likely for Thera based on tephra / hemispheric deposition evidence.

    “Two additional volcanic events identified at 1586 BCE (Greenland) and 1550 BCE (Antarctica) are not shown as they are currently considered less likely for Thera based on tephra / hemispheric deposition evidence31, but should be further investigated.”

    From Olive shrub buried on Therasia supports a mid-16th century BCE date for the Thera eruption (2023) · cites this paper as [31]

    The Discussion (page unavailable) identifies the 1586 BCE event as a high-latitude Northern Hemisphere eruption distinct from Thera on tephra-geochemical grounds, and the 1551 BCE event as an unidentified Southern Hemisphere eruption. This supports treating both as less likely Thera candidates, but the source dates the second event to 1551 BCE, not 1550 BCE; the cited passage also does not specifically identify its deposition in Antarctica. (LLM, conf=0.87)

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  • The Thera eruption might well not be represented by one of the largest sulfur signals in polar ice sheets, and might instead be represented by one of the more modest volcanic signals in the ice or tree-ring records like ~1611/1610 BCE, 1597 BCE, 1586 BCE or 1584 BCE, or might not even offer a clear signal in one or more distant proxy records.

    “the Thera eruption might well not be represented by one of the largest, or even larger, sulfur signals in polar ice sheets, and might instead be represented by one of the more modest volcanic, or potentially volcanic, signals in the ice or tree-ring records like one of those ~1611/1610 BCE, 1597 BCE, 1586 BCE or 1584 BCE [13,14], or, indeed, despite its cataclysmic relevance to the southern Aegean”

    From Second Intermediate Period date for the Thera (Santorini) eruption and historical implications (2022) · cites this paper as [14]

    Split into 2 atoms — 1 confirmed, 1 partially supported, 0 disputed, 0 misattributed, 0 unverifiable. Expand the claim to see per-atom verdicts.

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  • The most likely 68.3% hpd range in Fig 9, 1606-1589 BCE, does not correspond with most of the possible proxy volcanic eruption signals noted so far in ice-core, tree-ring and other records; only the bristlecone pine minima 1597 BCE overlaps, with other signals just outside this range: 1611/1610 BCE, 1586 BCE and 1584 BCE.

    “The most likely 68.3% hpd range in Fig 9, 1606-1589 BCE, does not in fact correspond with most of the possible proxy volcanic eruption signals noted so far in ice-core, tree-ring and other records-only the bristlecone pine minima 1597 BCE overlaps-with the other signals noted in this vicinity just outside this range: 1611/1610 BCE, 1586 BCE and 1584 BCE [12-14, 44, 70].”

    From Second Intermediate Period date for the Thera (Santorini) eruption and historical implications (2022) · cites this paper as [14]

    The Results table (page unavailable) dates ice-core volcanic signals to 1611 and 1586 BCE, both outside the citing paper’s stated 1606–1589 BCE range; it also lists an earlier chronology’s 1610 BCE date. Our copy does not identify a 1597 BCE bristlecone-pine minimum or a 1584 BCE signal, so it does not support the claim that 1597 is the only overlap or the full list of nearby signals. (LLM, conf=0.85)

    Experimental — accuracy not yet measured
  • Calendar dated ice-core sulfate layers at 1611 BCE, 1562-1555 BCE and c.1538 BCE have been highlighted as possible markers for the Thera eruption.

    “Figure 5 also shows calendar dated ice-core sulfate layers at 1611 BCE, 1562-1555 BCE and c.1538 BCE which have been highlighted as possible markers for the Thera eruption31.”

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Authors
Pearson, C., Sigl, M., Burke, A., Davies, S., Kurbatov, A., Severi, M., Cole-Dai, J., Innes, H., Albert, P. G., & Helmick, M.
Affiliations
  • University of Arizona (US)
  • University of Bern (CH)
  • University of St Andrews (GB)
  • Swansea University (GB)
  • University of Maine (US)
  • University of Florence (IT)
  • Department of Chemistry and Biochemistry, South Dakota State University , 1451 Stadium Rd, Brookings, SD 57007, USA
Corresponding author
Pearson, Charlotte
Venue
PNAS Nexus
Published
2022-04-29
Volume
1
Issue
2
Pages
pgac048-pgac048
ISSN
2752-6542 (ISSN-L)
OpenAlex
W4225137773
Cited by
45
References
14
Citations by year
2026: 7 · 2025: 10 · 2024: 14 · 2023: 10 · 2022: 4
FWCI
3.83
Type
journal article
Language
en
Open access
Locations
  • PNAS Nexus (publishedVersion, cc-by-nc-nd)
  • PubMed Central (publishedVersion, cc-by-nc-nd)
  • PubMed (publishedVersion)
  • Bern Open Repository and Information System (University of Bern) (submittedVersion, cc-by-nc-nd)
  • Florence Research (University of Florence) (submittedVersion)
  • St Andrews Research Repository (St Andrews Research Repository) (submittedVersion, cc-by-nc-nd)
  • Open Access CRIS of the University of Bern
Funders
  • European Research Council
  • Horizon 2020 Framework Programme (820047)
Topics
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
  • Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric aerosols and clouds
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Tree-ring climate responses
Keywords
Thera eruption, Minoan eruption, volcanic sulfate, stratospheric sulfur injection, sulfur isotopes, tephra, eruption dating

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