The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Design Principles of Bipolar Electrochemical Co-Electrolysis Cells for Efficient Reduction of Carbon Dioxide from Gas Phase at Low Temperature
Open accessAbstract
Cell designs for the electrochemical reduction of CO 2 from gas phase were developed and investigated, and the critical elements for an efficient process were identified. Various types of polymeric membrane were used to build membrane electrode assembly adapted for CO 2 reduction in gas phase: protonic and anion exchange membrane (AEM), bipolar membrane and a modified bipolar like membrane configuration. Configurations using anion exchange ionomer in the cathodic catalytic layer in contact with an AEM allow for a great enhancement of the cathode reaction selectivity toward CO. However, a severe problem was identified when co-electrolysis is performed using only an AEM: this type of membrane acts as a CO 2 "pump" meaning that for each molecule of CO 2 reduced at the cathode, one or two CO 2 molecules are produced at the anode by oxidation of the carbonate/bicarbonate anion transported in the membrane. A bipolar membrane system was shown to soften this problem, but only a newly developed cell design was able to fully prevent the parasitic CO 2 pumping. Using this new cell configuration, the faradaic efficiency of an alkaline environment is maintained, the parasitic CO 2 pumping to the anode side is completely suppressed, and the overall cell voltage efficiency is highly improved.
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Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
Ma, S., Sadakiyo, M., Luo, R., Heima, M., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.09.124 · Cited by 488
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Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH
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Electrolysis of CO2 to Syngas in Bipolar Membrane-Based Electrochemical Cells
Li, Y. C., Zhou, D., Yan, Z., Gonçalves, R. H., Salvatore, D. A., Berlinguette, C. P., & Mallouk, T. E. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00475 · Cited by 313
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Tailoring gas-phase CO 2 electroreduction selectivity to hydrocarbons at Cu nanoparticles
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Electrochemical generation of syngas from water and carbon dioxide at industrially important rates
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A pH-differential dual-electrolyte microfluidic electrochemical cells for CO2 utilization
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Cited by
Bipolar membranes: A review on principles, latest developments, and applications
Pärnamäe, R., Mareev, S., Nikonenko, V., Melnikov, S., Sheldeshov, N., Zabolotskii, V., Hamelers, H. V. M., & Tedesco, M. (2021) · Journal of Membrane Science · doi:10.1016/j.memsci.2020.118538 · Cited by 610
Towards membrane-electrode assembly systems for CO2 reduction: a modeling study
Weng, L.-C., Bell, A. T., & Weber, A. Z. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00909d · Cited by 452
Kale, M. B., Borse, R. A., Gomaa Abdelkader Mohamed, A., & Wang, Y. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202101313 · Cited by 281
Metadata
- Authors
- Pătru, A., Binninger, T., Pribyl, B., & Schmidt, T. J.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2019
- Volume
- 166
- Issue
- 2
- Pages
- F34-F43
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2906783778
- Cited by
- 160
- References
- 10
- FWCI
- 4.84
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Pătru, A., Binninger, T., Pribyl, B., & Schmidt, T. J. (2019). Design Principles of Bipolar Electrochemical Co-Electrolysis Cells for Efficient Reduction of Carbon Dioxide from Gas Phase at Low Temperature. Journal of The Electrochemical Society. https://doi.org/10.1149/2.1221816jes
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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