The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
The Key to High Performance Low Pt Loaded Electrodes
Open accessAbstract
The effect of ionomer distribution on the oxygen mass transport resistance, the proton resistivity of the cathode catalyst layer, and the H 2 /air fuel cell performance was investigated for catalysts with surface modified carbon supports. By introducing nitrogen containing surface groups, it was shown that the ionomer distribution in the cathodic electrode can be optimized to decrease mass transport related voltage losses at high current density. The in house prepared catalysts were fully characterized by TEM, TGA, elemental analysis, and XPS. Thin-film rotating disk electrode measurements showed that the carbon support modification did not affect the oxygen reduction activity of the catalysts, but exclusively affects the ionomer distribution in the electrode during electrode preparation. Limiting current measurements were used to determine the pressure independent oxygen transport resistance – primarily attributed to oxygen transport in the ionomer film – which decreases for catalysts with surface modified carbon support. Systematically lowering the ionomer to carbon ratio (I/C) from 0.65 to 0.25 revealed a maximum performance at I/C = 0.4, where an optimum between ionomer thickness and proton conductivity within the catalyst layer is obtained. From this work, it can be concluded that not only ionomer film thickness, but more importantly ionomer distribution is the key to high performance low Pt loaded electrodes.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“One approach for achieving a homogenous distribution is by modifying the carbon support with N functional groups [186].”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [186]
Citations
Cites
Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876
Self-citationRecommendations for the characterization of porous solids (Technical Report)
Rouquerol, J., Avnir, D., Fairbridge, C. W., Everett, D. H., Haynes, J. M., Pernicone, N., Ramsay, J. D. F., Sing, K. S. W., & Unger, K. K. (1994) · Pure and Applied Chemistry · doi:10.1351/pac199466081739 · Cited by 3,984
Handbook of fuel cells: fundamentals, technology, and applications
(2003) · Focus on Catalysts · doi:10.1016/s1351-4180(03)00850-x · Cited by 3,332
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism
Durst, J., Siebel, A., Simon, C., Hasché, F., Herranz, J. S., & Gasteiger, H. A. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00440j · Cited by 1,705
Self-citationKongkanand, A., & Mathias, M. F. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00216 · Cited by 1,202
Mayrhofer, K. J. J., Strmcnik, D. S., Blizanac, B. B., Stamenković, V. R., Arenz, M., & Marković, N. M. (2007) · Electrochimica Acta · doi:10.1016/j.electacta.2007.11.057 · Cited by 980
Kundu, S., Wang, Y., Xia, W., & Muhler, M. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp804413a · Cited by 952
XPS of nitrogen-containing functional groups on activated carbon
Jansen, R. J. J., & van Bekkum, H. (1995) · Carbon · doi:10.1016/0008-6223(95)00030-h · Cited by 886
Quenched solid density functional theory and pore size analysis of micro-mesoporous carbons
Neimark, A. V., Lin, Y., Ravikovitch, P. I., & Thommes, M. (2009) · Carbon · doi:10.1016/j.carbon.2009.01.050 · Cited by 869
Handbook of fuel cells. Fundamentals technology and applications
Patrick, J. W. (2003) · Fuel · doi:10.1016/j.fuel.2003.09.012 · Cited by 747
The surface analytical characterization of carbon fibers functionalized by H2SO4/HNO3 treatment
Zhang, G., Sun, S., Yang, D., Dodelet, J., & Sacher, E. (2007) · Carbon · doi:10.1016/j.carbon.2007.11.002 · Cited by 580
Review—Electromobility: Batteries or Fuel Cells?
Gröger, O., Gasteiger, H. A., & Suchsland, J. (2015) · Journal of The Electrochemical Society · doi:10.1149/2.0211514jes · Cited by 544
Self-citationAnalysis of Oxygen-Transport Diffusion Resistance in Proton-Exchange-Membrane Fuel Cells
Nonoyama, N., Okazaki, S., Weber, A. Z., Ikogi, Y., & Yoshida, T. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3546038 · Cited by 530
Measurement of Oxygen Transport Resistance in PEM Fuel Cells by Limiting Current Methods
Baker, D. R., Caulk, D. A., Neyerlin, K. C., & Murphy, M. W. (2009) · Journal of The Electrochemical Society · doi:10.1149/1.3152226 · Cited by 515
Determination of Catalyst Unique Parameters for the Oxygen Reduction Reaction in a PEMFC
Neyerlin, K. C., Gu, W., Jorné, J., & Gasteiger, H. A. (2006) · Journal of The Electrochemical Society · doi:10.1149/1.2266294 · Cited by 441
Self-citationImpact of Platinum Loading and Catalyst Layer Structure on PEMFC Performance
Owejan, J. P., Owejan, J. E., & Gu, W. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.072308jes · Cited by 433
The Impact of Platinum Loading on Oxygen Transport Resistance
Greszler, T. A., Caulk, D. A., & Sinha, P. K. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.061212jes · Cited by 433
Gor, G. Y., Thommes, M., Cychosz, K. A., & Neimark, A. V. (2011) · Carbon · doi:10.1016/j.carbon.2011.11.037 · Cited by 432
Three-dimensional analysis of Nafion layers in fuel cell electrodes
Lopez-Haro, M., Guétaz, L., Printemps, T., Morin, A., Escribano, S., Jouneau, P.-H., Bayle-Guillemaud, P., Chandezon, F., & Gebel, G. (2014) · Nature Communications · doi:10.1038/ncomms6229 · Cited by 402
Park, Y.-C., Tokiwa, H., Kakinuma, K., Watanabe, M., & Uchida, M. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.02.091 · Cited by 389
Kundu, S., Xia, W., Busser, W., Becker, M. J., Schmidt, D. A., Havenith, M., & Muhler, M. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/b923651a · Cited by 372
Unexplained transport resistances for low-loaded fuel-cell catalyst layers
Weber, A. Z., & Kusoglu, A. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta02952f · Cited by 334
Transient analysis of polymer electrolyte fuel cells
Wang, Y., & Wang, C.-Y. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2004.08.022 · Cited by 310
Liu, Y., Murphy, M. W., Baker, D. R., Gu, W., Ji, C., Jorné, J., & Gasteiger, H. A. (2009) · Journal of The Electrochemical Society · doi:10.1149/1.3143965 · Cited by 290
Self-citationAmination and ammoxidation of activated carbons
Jansen, R. J. J., & van Bekkum, H. (1994) · Carbon · doi:10.1016/0008-6223(94)90146-5 · Cited by 275
Cathode Catalyst Utilization for the ORR in a PEMFC
Neyerlin, K. C., Gu, W., Jorné, J., Clark, A., & Gasteiger, H. A. (2007) · Journal of The Electrochemical Society · doi:10.1149/1.2400626 · Cited by 252
Self-citationNgo, T. T., Yu, T. L., & Lin, H.-L. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.10.055 · Cited by 231
Spontaneous Functionalization of Carbon Black by Reaction with 4-Nitrophenyldiazonium Cations
Toupin, M., & Bélanger, D. (2008) · Langmuir · doi:10.1021/la702556n · Cited by 214
Ohma, A., Mashio, T., Sato, K., Iden, H., Ono, Y., Sakai, K., Akizuki, K., Takaichi, S., & Shinohara, K. (2011) · Electrochimica Acta · doi:10.1016/j.electacta.2011.04.058 · Cited by 209
Shinozaki, K., Morimoto, Y., Pivovar, B. S., & Kocha, S. S. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.06.062 · Cited by 194
Pt-Oxide Coverage-Dependent Oxygen Reduction Reaction (ORR) Kinetics
Subramanian, N. P., Greszler, T. A., Zhang, J., Gu, W., & Makharia, R. R. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.088205jes · Cited by 183
Effects of Catalyst Carbon Support on Proton Conduction and Cathode Performance in PEM Fuel Cells
Liu, Y., Ji, C., Gu, W., Jorné, J., & Gasteiger, H. A. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3562945 · Cited by 132
Self-citationZihrul, P., Hartung, I., Kirsch, S., Hübner, G., Hasché, F., & Gasteiger, H. A. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0561606jes · Cited by 118
Self-citationThe Analysis of Performance Loss with Low Platinum Loaded Cathode Catalyst Layers
Ono, Y., Mashio, T., Takaichi, S., Ohma, A., Kanesaka, H., & Shinohara, K. (2010) · ECS Transactions · doi:10.1149/1.3496614 · Cited by 104
Experimental Method to Determine the Mass Transport Resistance of a Polymer Electrolyte Fuel Cell
Beuscher, U. (2006) · Journal of The Electrochemical Society · doi:10.1149/1.2218760 · Cited by 98
Kudo, K., Suzuki, T., & Morimoto, Y. (2010) · ECS Transactions · doi:10.1149/1.3484642 · Cited by 96
Liu, Y., Ji, C., Gu, W., Baker, D. R., Jorné, J., & Gasteiger, H. A. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3435323 · Cited by 86
Self-citationDispersion of Rod-like Particles of Nafion in Salt-Free Water/1-Propanol and Water/Ethanol Solutions
Yamaguchi, M., Matsunaga, T., Amemiya, K., Ohira, A., Hasegawa, N., Shinohara, K., Ando, M., & Yoshida, T. (2014) · The Journal of Physical Chemistry B · doi:10.1021/jp506814m · Cited by 81
An Experimental Study of the Effects of Operational History on Activity Changes in a PEMFC
Jomori, S., Komatsubara, K., Nonoyama, N., Kato, M., & Yoshida, T. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.103309jes · Cited by 81
Orfanidi, A., Daletou, M. K., & Neophytides, S. G. (2011) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2011.05.043 · Cited by 69
Self-citationDetermination of Electrode Sheet Resistance in Cathode Catalyst Layer by AC Impedance
Liu, Y., Murphy, M., Baker, D. R., Gu, W., Ji, C., Jorné, J., & Gasteiger, H. A. (2007) · ECS Transactions · doi:10.1149/1.2780961 · Cited by 61
Self-citation(Plenary) Electrochemical Diagnostics and Modeling in Developing the PEMFC Cathode
Kongkanand, A., Yarlagadda, V., Garrick, T. R., Moylan, T. E., & Gu, W. (2016) · ECS Transactions · doi:10.1149/07514.0025ecst · Cited by 47
Yamaguchi, T., Nakahara, E., & Koda, S. (2014) · The Journal of Physical Chemistry B · doi:10.1021/jp502631q · Cited by 44
Influence of the Gas Diffusion Layer Compression on the Oxygen Mass Transport in PEM Fuel Cells
Simon, C., Hasché, F., Müller, D. C., & Gasteiger, H. A. (2015) · ECS Transactions · doi:10.1149/06917.1293ecst · Cited by 40
Self-citationStudies on interactions between Nafion and organic vapours by quartz crystal microbalance
Sun, L. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00585-8 · Cited by 35
Miyazaki, K., Sugimura, N., Kawakita, K.-I., Abe, T., Nishio, K., Nakanishi, H., Matsuoka, M., & Ogumi, Z. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3483105 · Cited by 20
(Plenary) Doing More with Less: Challenges for Catalyst Layer Design
Putz, A. M. V., Susac, D., Berejnov, V., Wu, J., Hitchcock, A. P., & Stumper, J. (2016) · ECS Transactions · doi:10.1149/07514.0003ecst · Cited by 8
Xin, L., Kang, Y., Yang, F., Uzunoğlu, A., Rockward, T., Ferreira, P. J., Borup, R. L., Ilavský, J., Stanciu, L., & Xie, J. (2016) · ECS Meeting Abstracts · doi:10.1149/ma2016-02/38/2584 · Cited by 3
Research works printed but not linked: 1
- Gu W. Baker D. R. Liu Y. Gasteiger H. A. , in Handbook of Fuel Cells: Advances in Electrocatalysis, Materials, Diagnostics and Durability (editors: Vielstich W. Gasteiger H. A. Yokokawa H. ), John Wiley & Sons, UK Chichester, 631 (2009).
Cited by
Sorted by citations
Ott, S., Orfanidi, A., Schmies, H., Anke, B., Nong, H. N., Hübner, J., Gernert, U., Gliech, M., Lerch, M., & Strasser, P. (2020) · Nature Materials · doi:10.1038/s41563-019-0487-0 · Cited by 727
Self-citationFan, J., Chen, M., Zhao, Z., Zhang, Z., Ye, S., Xu, S., Wang, H., & Li, H. (2021) · Nature Energy · doi:10.1038/s41560-021-00824-7 · Cited by 635
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X. M., Yan, Z. W., Potsi, G., Selhorst, R. C., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 557
Lazaridis, T., Stühmeier, B. M., Gasteiger, H. A., & El-Sayed, H. A. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00776-5 · Cited by 396
Self-citationAdvancements in cathode catalyst and cathode layer design for proton exchange membrane fuel cells
Sun, Y., Polani, S., Luo, F., Ott, S., Strasser, P., & Dionigi, F. (2021) · Nature Communications · doi:10.1038/s41467-021-25911-x · Cited by 369
Metadata
- Authors
- Orfanidi, A., Madkikar, P., El-Sayed, H. A., Harzer, G. S., Kratky, T., & Gasteiger, H. A.
- Affiliations
- Technical University of Munich (DE)
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2017
- Volume
- 164
- Issue
- 4
- Pages
- F418-F426
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2592493147
- Cited by
- 276
- References
- 48
- Citations by year
- 2026: 21 · 2025: 39 · 2024: 35 · 2023: 38 · 2022: 47 · 2021: 33 · 2020: 27 · 2019: 18 · 2018: 14 · 2017: 4
- FWCI
- 7.16
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- Journal of The Electrochemical Society (publishedVersion, cc-by)
- mediaTUM – the media and publications repository of the Technical University Munich (Technical University Munich) (submittedVersion, other-oa)
- Funders
- Greenerity GmbH and German Federal Ministry of Economy (03ET2058C)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
- Keywords
- low platinum catalysts, oxygen reduction reaction, ionomer distribution, cathode catalyst layer, proton conductivity, nitrogen-doped carbon support, ionomer-to-carbon ratio, hydrogen-air fuel cells, voltage loss
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review