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Ultrastable In‐Plane 1T–2H MoS2 Heterostructures for Enhanced Hydrogen Evolution Reaction

Wang, Shuai, Zhang, Di, Li, Bin, Zhang, Chao, Du, Zhiguo, Yin, Haoming, Bi, Xiaofang, Yang, Shubin·2018·Advanced Energy Materials

Abstract

Metallic 1T MoS 2 is highly desirable for catalyzing electrochemical hydrogen production from water owing to its high electrical conductivity. However, stable 1T MoS 2 is difficult to be produced in large‐scale by either common chemical or physical approaches. Here, ultrastable in‐plane 1T–2H MoS 2 heterostructures are achieved via a simple one‐pot annealing treatment of 2H MoS 2 bulk under a mixture gas of Ar and phosphorous vapor, where phosphorus cannot only occupy the interspace of MoS 2 bulk, resulting in the expansion of MoS 2, but also embed into the lattice of MoS 2, inducing the partial phase transition from 2H to 1T phases of MoS 2. Benefiting from its significantly improved electrical conductivity, highly exposed active sites, and hydrophily property, in‐plane 1T–2H MoS 2 heterostructures exhibit largely improved electrocatalytic properties for hydrogen evolution reaction (HER) in alkaline electrolytes.

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Metadata

Authors
Wang, S., Zhang, D., Li, B., Zhang, C., Du, Z., Yin, H., Bi, X., & Yang, S.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2018-07-18
Volume
8
Issue
25
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2883391438
Cited by
577
References
4
FWCI
12.50
Type
journal article
Language
en
Open access
closed
Funders
National Natural Science Foundation of China (51572007, 51622203)

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CoChat. (2026). Citation check: Ultrastable In‐Plane 1T–2H MoS2 Heterostructures for Enhanced Hydrogen Evolution Reaction. https://app.cochat.ai/papers/10.1002/aenm.201801345
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Wang, S., Zhang, D., Li, B., Zhang, C., Du, Z., Yin, H., Bi, X., & Yang, S. (2018). Ultrastable In‐Plane 1T–2H MoS2 Heterostructures for Enhanced Hydrogen Evolution Reaction. Advanced Energy Materials. https://doi.org/10.1002/aenm.201801345

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