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Terpolymerization of β-Butyrolactone, Epoxides, and CO2: Chemoselective CO2-Switch and Its Impact on Kinetics and Material Properties

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Redox Control of Aluminum Ring-Opening Polymerization: A Combined Experimental and DFT Investigation

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Strategies for the synthesis of block copolymers with biodegradable polyester segments

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Cooperative rare earth metal–zinc based heterometallic catalysts for copolymerization of CO 2 and cyclohexene oxide

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Performance tailorable terpolymers synthesized from carbon dioxide, phthalic anhydride and propylene oxide using Lewis acid-base dual catalysts

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CO2 Controlled Catalysis: Switchable Homopolymerization and Copolymerization

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One-step synthesis of sequence-controlled multiblock polymers with up to 11 segments from monomer mixture

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Multidimensional Control of Repeating Unit/Sequence/Topology for One-Step Synthesis of Block Polymers from Monomer Mixtures

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Alternating copolymerization of dihydrocoumarin and epoxides catalyzed by chromium salen complexes: a new route to functional polyesters

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Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone

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Switch in Catalyst State: Single Bifunctional Bi‐state Catalyst for Two Different Reactions

Semwal, S., & Choudhury, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702142 · Cited by 64 · see citing works

Heterodinuclear titanium/zinc catalysis: synthesis, characterization and activity for CO 2 /epoxide copolymerization and cyclic ester polymerization

Garden, J. A., White, A. J. P., & Williams, C. K. (2017) · Dalton Transactions · doi:10.1039/c6dt04193k · Cited by 60 · see citing works

Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO2‐Based Block Copolymers from Monomer Mixtures

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Bimetallic Aluminum Complexes Bearing Binaphthyl-Based Iminophenolate Ligands as Catalysts for the Synthesis of Polyesters

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Switchable Ring‐Opening Polymerization by a Ferrocene Supported Aluminum Complex

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Redox-Switchable Hydroelementation of a Cobalt Complex Supported by a Ferrocene-Based Ligand

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RAFT polymerization and associated reactivity ratios of methacrylate-functionalized mixed bio-oil constituents

Holmberg, A. L., Karavolias, M. G., & Epps, T. H. I. (2015) · Polymer Chemistry · doi:10.1039/c5py00291e · Cited by 54 · see citing works

Switchable Polymerization Organocatalysis: From Monomer Mixtures to Block Copolymers

Tang, J., Li, M., Wang, X., & Tao, Y. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202115465 · Cited by 52 · see citing works

One‐Pot Precision Synthesis of AB, ABA and ABC Block Copolymers via Switchable Catalysis

Yang, Z., Hu, C., Cui, F., Pang, X., Huang, Y., Zhou, Y., & Chen, X. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202117533 · Cited by 52 · see citing works

Mechanistic Studies of Redox-Switchable Copolymerization of Lactide and Cyclohexene Oxide by a Zirconium Complex

Quan, S. M., Wei, J., & Diaconescu, P. L. (2017) · Organometallics · doi:10.1021/acs.organomet.7b00672 · Cited by 50 · see citing works

Copolymerization of cyclic esters, epoxides and anhydrides: evidence of the dual role of the monomers in the reaction mixture

Isnard, F., Carratù, M., Lamberti, M., Venditto, V., & Mazzeo, M. (2018) · Catalysis Science & Technology · doi:10.1039/c8cy01174e · Cited by 49 · see citing works

Heterodinuclear Zn(II), Mg(II) or Co(III) with Na(I) Catalysts for Carbon Dioxide and Cyclohexene Oxide Ring Opening Copolymerizations

Lindeboom, W., Fraser, D. A. X., Durr, C. B., & Williams, C. K. (2021) · Chemistry - A European Journal · doi:10.1002/chem.202101140 · Cited by 50 · see citing works

The role of ligand redox non-innocence in ring-opening polymerization reactions catalysed by bis(imino)pyridine iron alkoxide complexes

Delle Chiaie, K. R., Biernesser, A. B., Ortuño, M. A., Dereli, B., Iovan, D. A., Wilding, M. J. T., Li, B., Cramer, C. J., & Byers, J. A. (2017) · Dalton Transactions · doi:10.1039/c7dt03067c · Cited by 48 · see citing works

Constructing ABA- and ABCBA-Type Multiblock Copolyesters with Structural Diversity by Organocatalytic Self-Switchable Copolymerization

Li, C., Dang, Y., Wang, B., Pan, L., & Li, Y. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c00767 · Cited by 48 · see citing works

Di‐Zinc–Aryl Complexes: CO2 Insertions and Applications in Polymerisation Catalysis

Romain, C., Garden, J. A., Trott, G., Buchard, A., White, A. J. P., & Williams, C. K. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201701013 · Cited by 48 · see citing works

Recent Developments in Ring-Opening Copolymerization of Epoxides With CO2 and Cyclic Anhydrides for Biomedical Applications

Xue, L., Tan, F., & Zhu, Y. (2021) · Frontiers in Chemistry · doi:10.3389/fchem.2021.647245 · Cited by 47 · see citing works

One-Step Synthesis of Sequence-Controlled Polyester-block-Poly(ester-alt-thioester) by Chemoselective Multicomponent Polymerization

Chen, X.-L., Wang, B., Song, D., Pan, L., & Li, Y. (2022) · Macromolecules · doi:10.1021/acs.macromol.1c02303 · Cited by 48 · see citing works

Investigation of redox switchable titanium and zirconium catalysts for the ring opening polymerization of cyclic esters and epoxides

Lowe, M. Y., Shu, S., Quan, S. M., & Diaconescu, P. L. (2017) · Inorganic Chemistry Frontiers · doi:10.1039/c7qi00227k · Cited by 47 · see citing works

Redox-triggered crosslinking of a degradable polymer

Chiaie, K. R. D., Yablon, L. M., Biernesser, A. B., Michalowski, G. R., Sudyn, A. W., & Byers, J. A. (2016) · Polymer Chemistry · doi:10.1039/c6py00975a · Cited by 45 · see citing works

Versatile Ring-Opening Copolymerization and Postprinting Functionalization of Lactone and Poly(propylene fumarate) Block Copolymers: Resorbable Building Blocks for Additive Manufacturing

Petersen, S. R., Wilson, J. A., & Becker, M. L. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01372 · Cited by 45 · see citing works

Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalysts

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Lithium achieves sequence selective ring-opening terpolymerisation (ROTERP) of ternary monomer mixtures

Rupf, S. M., Pröhm, P., & Plajer, A. J. (2022) · Chemical Science · doi:10.1039/d2sc01776h · Cited by 42 · see citing works

Photoswitchable ring-opening polymerization of lactide catalyzed by azobenzene-based thiourea

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Stereoregular CO2 Copolymers from Epoxides with an Electron-Withdrawing Group: Crystallization and Unexpected Stereocomplexation

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Ortho -vanillin derived Al( iii ) and Co( iii ) catalyst systems for switchable catalysis using ε-decalactone, phthalic anhydride and cyclohexene oxide

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Synthesis of Sequence‐specific Poly(ester‐carbonate) Copolymers via Chemoselective Terpolymerization Controlled by the Stoichiometric Ratio of Phosphazene/Triethylborane

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Block and Random Copolymers of 1,2-Cyclohexyl Cyclocarbonate and l -Lactide or Trimethylene Carbonate Synthesized by Ring-Opening Polymerization

Diallo, A. K., Guerin, W., Slawinski, M., Brusson, J., Carpentier, J., & Guillaume, S. M. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00548 · Cited by 41 · see citing works

Design and structure of catalysts: syntheses of carbon dioxide-based copolymers with cyclic anhydrides and/or cyclic esters

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Mg( ii ) heterodinuclear catalysts delivering carbon dioxide derived multi-block polymers

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Spatiotemporal control for integrated catalysis

Deng, S., Jolly, B. J., Wilkes, J. R., Mu, Y., Byers, J. A., Do, L. H., Miller, A. J. M., Wang, D., Liu, C., & Diaconescu, P. L. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00207-0 · Cited by 40 · see citing works

Investigation of a zirconium compound for redox switchable ring opening polymerization

Dai, R., & Diaconescu, P. L. (2019) · Dalton Transactions · doi:10.1039/c9dt00212j · Cited by 38 · see citing works

One-pot copolymerization of epoxides/carbon dioxide and lactide using a ternary catalyst system

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Improvement in Aluminum Complexes Bearing Schiff Bases in Ring-Opening Polymerization of ε-Caprolactone: A Five-Membered-Ring System

Lee, C.-L., Lin, Y., Jiang, M.-T., Lu, W., Vandavasi, J. K., Wang, L., Lai, Y., Chiang, M. Y.-N., & Chen, H. (2017) · Organometallics · doi:10.1021/acs.organomet.7b00068 · Cited by 36 · see citing works

Copolymerization of lactide, epoxides and carbon dioxide: a highly efficient heterogeneous ternary catalyst system

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CO2-Tuned Sequential Synthesis of Stereoblock Copolymers Comprising a Stereoregularity-Adjustable Polyester Block and an Atactic CO2-Based Polycarbonate Block

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Semi-crystalline terpolymers with varying chain sequence structures derived from CO 2 , cyclohexene oxide and ε-caprolactone: one-step synthesis catalyzed by tri-zinc complexes

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PLA Block Polymers: Versatile Materials for a Sustainable Future

Krajovic, D. M., Kumler, M. S., & Hillmyer, M. A. (2025) · Biomacromolecules · doi:10.1021/acs.biomac.5c00161 · Cited by 35 · see citing works

Molecularly Controlled Catalysis – Targeting Synergies Between Local and Non‐local Environments

Chatterjee, B., Chang, W., & Werlé, C. (2020) · ChemCatChem · doi:10.1002/cctc.202001431 · Cited by 34 · see citing works

Recent Advances in Sequence‐Controlled Ring‐Opening Copolymerizations of Monomer Mixtures

Wang, X., Huo, Z., Xie, X., Shanaiah, N., & Tong, R. (2022) · Chemistry - An Asian Journal · doi:10.1002/asia.202201147 · Cited by 34 · see citing works

Lithium-Assisted Copolymerization of CO2/Cyclohexene Oxide: A Novel and Straightforward Route to Polycarbonates and Related Block Copolymers

Zhang, D., Zhang, H., Hadjichristidis, N., Gnanou, Y., & Feng, X. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b00203 · Cited by 33 · see citing works

Switchable catalytic processes involving the copolymerization of epoxides and carbon dioxide for the preparation of block polymers

Darensbourg, D. J. (2017) · Inorganic Chemistry Frontiers · doi:10.1039/c7qi00013h · Cited by 33 · see citing works

Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe–M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination

Abubekerov, M., Khan, S. I., & Diaconescu, P. L. (2017) · Organometallics · doi:10.1021/acs.organomet.7b00626 · Cited by 33 · see citing works

One‐Step Access to Sequence‐Controlled Block Copolymers by Self‐Switchable Organocatalytic Multicomponent Polymerization

Ji, H., Wang, B., Pan, L., & Li, Y. (2018) · Angewandte Chemie · doi:10.1002/ange.201810083 · Cited by 35 · see citing works

Influences of a Dizinc Catalyst and Bifunctional Chain Transfer Agents on the Polymer Architecture in the Ring-Opening Polymerization of ε-Caprolactone

Zhu, Y., Romain, C., Poirier, V., & Williams, C. K. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00225 · Cited by 32 · see citing works

Using Redox‐Switchable Polymerization Catalysis to Synthesize a Chemically Recyclable Thermoplastic Elastomer

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Selective Polymerization Catalysis: Controlling the Metal Chain End Group to Prepare Block Copolyesters

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Chemoselective Polymerizations from Mixtures of Epoxide, Lactone, Anhydride, and Carbon Dioxide

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Zinc versus Magnesium: Orthogonal Catalyst Reactivity in Selective Polymerizations of Epoxides, Bio‐derived Anhydrides and Carbon Dioxide

Saini, P. K., Fiorani, G., Mathers, R. T., & Williams, C. K. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201605690 · Cited by 52 · see citing works

Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity

Plajer, A. J., & Williams, C. K. (2021) · Angewandte Chemie · doi:10.1002/ange.202101180 · Cited by 11 · see citing works

Highly Active and Readily Accessible Proline‐Based Dizinc Catalyst for CO2/Epoxide Copolymerization

Schütze, M., Sebastian Dechert, B., & Meyer, F. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201704754 · Cited by 25 · see citing works