Di-magnesium and zinc catalysts for the copolymerization of phthalic anhydride and cyclohexene oxide
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Di-zinc and di-magnesium catalysts for the ring-opening copolymerization of phthalic anhydride and cyclohexene oxide are presented. They are applied in terpolymerizations to prepare block copoly(ester-carbonates).
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When the two blocks are miscible, only one intermediate Tg higher than that of the pure polyester and lower than the polycarbonate is obtained.
“When the two blocks are miscible, only one intermediate Tg higher than that of the pure polyester and lower than the polycarbonate is obtained.368”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [368]
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- Authors
- Saini, P. K., Romain, C., Zhu, Y., & Williams, C. K.
- Affiliations
- Imperial College London (GB)
- Corresponding author
- Williams, Charlotte K.
- Venue
- Polym. Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 5
- Issue
- 20
- Pages
- 6068-6075
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W1972190683
- Cited by
- 153
- References
- 45
- Citations by year
- 2026: 2 · 2025: 10 · 2024: 5 · 2023: 13 · 2022: 16 · 2021: 19 · 2020: 15 · 2019: 14 · 2018: 22 · 2017: 13 · 2016: 9 · 2015: 15
- FWCI
- 4.67
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- Polymer Chemistry (publishedVersion, cc-by)
- Spiral (Imperial College London) (submittedVersion)
- Funders
- Engineering and Physical Sciences Research Council (EP/K014070/1, EP/K035274/1, EP/L017393/1)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- ring-opening copolymerization, phthalic anhydride, cyclohexene oxide, terpolymerization, block copolymers, organozinc catalysis
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