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Granular Bamboo‐Derived Activated Carbon for High CO2 Adsorption: The Dominant Role of Narrow Micropores
Abstract
Cost‐effective biomass‐derived activated carbons with a high CO 2 adsorption capacity are attractive for carbon capture. Bamboo was found to be a suitable precursor for activated carbon preparation through KOH activation. The bamboo size in the range of 10–200 mesh had little effect on CO 2 adsorption, whereas the KOH/C mass ratio and activation temperature had a significant impact on CO 2 adsorption. The bamboo‐derived activated carbon had a high adsorption capacity and excellent selectivity for CO 2, and also the adsorption process was highly reversible. The adsorbed amount of CO 2 on the granular activated carbon was up to 7.0 mmol g−1 at 273 K and 1 bar, which was higher than almost all carbon materials. The pore characteristics of activated carbons responsible for high CO 2 adsorption were fully investigated. Based on the analysis of narrow micropore size distribution of several activated carbons prepared under different conditions, a more accurate micropore range contributing to CO 2 adsorption was proposed. The volume of micropores in the range of 0.33–0.82 nm had a good linear relationship with CO 2 adsorption at 273 K and 1 bar, and the narrow micropores of about 0.55 nm produced the major contribution, which could be used to evaluate CO 2 adsorption on activated carbons.
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Metadata
- Authors
- Wei, H., Deng, S., Hu, B., Chen, Z., Wang, B., Huang, J., & Yu, G.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2012-11-06
- Volume
- 5
- Issue
- 12
- Pages
- 2354-2360
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2006876915
- Cited by
- 421
- References
- 6
- FWCI
- 26.95
- Type
- journal article
- Language
- en
- Open access
- closed
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