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Trifunctional Single‐Atomic Ru Sites Enable Efficient Overall Water Splitting and Oxygen Reduction in Acidic Media
Open accessAbstract
Development of cost‐effective, active trifunctional catalysts for acidic oxygen reduction (ORR) as well as hydrogen and oxygen evolution reactions (HER and OER, respectively) is highly desirable, albeit challenging. Herein, single‐atomic Ru sites anchored onto Ti 3 C 2 Tx MXene nanosheets are first reported to serve as trifunctional electrocatalysts for simultaneously catalyzing acidic HER, OER, and ORR. A half‐wave potential of 0.80 V for ORR and small overpotentials of 290 and 70 mV for OER and HER, respectively, at 10 mA cm−2 are achieved. Hence, a low cell voltage of 1.56 V is required for the acidic overall water splitting. The maximum power density of an H 2–O 2 fuel cell using the as‐prepared catalyst can reach as high as 941 mW cm−2. Theoretical calculations reveal that isolated Ru–O 2 sites can effectively optimize the adsorption of reactants/intermediates and lower the energy barriers for the potential‐determining steps, thereby accelerating the HER, ORR, and OER kinetics.
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Engineering Ruthenium-Based Electrocatalysts for Effective Hydrogen Evolution Reaction
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Li, Y., Feng, A., Dai, L., Xi, B., An, X., Xiong, S., & An, C. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202316296 · Cited by 91
Kim, T., Jung, H., Choi, H., Lee, W., Patil, U. M., Parale, V. G., Kim, Y., Kim, J., Kim, S.-H., & Park, H.-H. (2024) · Materials Horizons · doi:10.1039/d4mh00242c · Cited by 5
Metadata
- Authors
- Peng, X., Zhao, S., Mi, Y., Han, L., Liu, X., Qi, D., Sun, J., Liu, Y., Bao, H., Zhuo, L., Xin, H. L., Luo, J., & Sun, X.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2020-07-14
- Volume
- 16
- Issue
- 33
- Pages
- e2002888-e2002888
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W3043132186
- Cited by
- 207
- References
- 10
- FWCI
- 5.59
- Type
- journal article
- Language
- en
- Open access
- green
- Licence
- Funders
- National Natural Science Foundation of China (51971157, 21601136, 51808037, 51761165012)
- Office of Science (DE‐SC0012704)
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- Peng, X., Zhao, S., Mi, Y., Han, L., Liu, X., Qi, D., Sun, J., Liu, Y., Bao, H., Zhuo, L., Xin, H. L., Luo, J., & Sun, X. (2020). Trifunctional Single‐Atomic Ru Sites Enable Efficient Overall Water Splitting and Oxygen Reduction in Acidic Media. Small. https://doi.org/10.1002/smll.202002888
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