Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH
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Ohmic losses may be prohibitively large in the case of less conductive electrolytes, such as 0.1 M KHCO3 (conductivity of 10 mS/cm compared to 1.0 M KOH which has a conductivity of 220 mS/cm), where the energy efficiency would be greatly impacted.
“Ohmic losses may be prohibitively large in the case of less conductive electrolytes, such as 0.1 M KHCO3 (conductivity of 10 mS/cm as compared to 1.0 M KOH which has a conductivity of 220 mS/cm), [218,219] where the energy efficiency would be greatly impacted”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [218]
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- Authors
- Varela, A. S., Kroschel, M., Reier, T., & Strasser, P.
- Affiliations
- Technische Universität Berlin (DE)
- Corresponding author
- Strasser, Peter
- Venue
- Catalysis Today
- Publisher
- Elsevier BV
- Published
- 2016-02
- Volume
- 260
- Pages
- 8-13
- ISSN
- 0920-5861 (ISSN-L)
- OpenAlex
- W1108713415
- Cited by
- 542
- References
- 30
- Citations by year
- 2026: 28 · 2025: 55 · 2024: 44 · 2023: 65 · 2022: 58 · 2021: 68 · 2020: 68 · 2019: 60 · 2018: 30 · 2017: 39 · 2016: 26 · 2015: 1
- FWCI
- 9.48
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Today (publishedVersion)
- Funders
- German Federal Ministry of Education and Research
- Mexican National Council for Science and Technology
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- electrochemical CO2 reduction, copper electrocatalysts, bicarbonate electrolyte, electrolyte concentration, product distribution, hydrogen evolution reaction, methane production, ethylene selectivity, carbon monoxide, buffering capacity
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