Cited by 352Heavy metals in environmentAdsorption and biosorption for pollutant removalEnvironmental remediation with nanomaterials

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Adsorption of Pb(II) on variable charge soils amended with rice-straw derived biochar

Jiang, Tian-Yu, Jiang, Jun, Xu, Ren-Kou, Li, Zhuo·2012·Chemosphere

DOI 10.1016/j.chemosphere.2012.04.028

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Abstract

Two Ultisols and one Oxisol from tropical regions of southern China were incubated with rice straw biochar to investigate the effect of biochar on their surface charge and Pb(II) adsorption using batch methods. The incorporation of biochar induced a remarkable increase in soil cation exchange capacity after 30 d of incubation. The incorporation of biochar significantly increased the adsorption of Pb(II) by these variable charge soils; the enhancement of adsorption of Pb(II) by these soils increased with the addition level of biochar. Adsorption of Pb(II) involved both electrostatic and non-electrostatic mechanisms; however, biochar mainly increased Pb(II) adsorption through the non-electrostatic mechanism via the formation of surface complexes between Pb(2+) and functional groups on biochar. There was greater enhancement of biochar on the non-electrostatic adsorption of Pb(II) by the variable charge soils at relatively low pH. Therefore, the incorporation of biochar decreased the activity and availability of Pb(II) to plants through increased non-electrostatic adsorption of Pb(II) by acidic variable charge soils.

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Self-citation

Authors: Jiang, T.-Y., Jiang, J., Xu, R.-K., & Li, Z.
Affiliations: Nanjing Agricultural University (CN)
Chinese Academy of Sciences (CN)
Nanjing Forestry University (CN)
Corresponding author: Xu, Ren-Kou
ORCID: Jiang, Jun
Xu, Ren-Kou
Li, Zhuo
Venue: Chemosphere
Publisher: Elsevier BV
Published: 2012-09
Volume: 89
Issue: 3
Pages: 249-256
ISSN: 0045-6535 (ISSN-L)
DOI: 10.1016/j.chemosphere.2012.04.028
OpenAlex: W2064743010
Cited by: 352
References: 32
Citations by year: 2026: 9 · 2025: 14 · 2024: 20 · 2023: 26 · 2022: 31 · 2021: 38 · 2020: 39 · 2019: 37 · 2018: 34 · 2017: 20 · 2016: 24 · 2015: 30 · 2014: 18 · 2013: 11 · 2012: 1
FWCI: 15.84
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Chemosphere (publishedVersion)
PubMed (publishedVersion)
Funders: National Natural Science Foundation of China
Key Technologies Research and Development Program
National Key Research and Development Program of China
Topics: Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
Keywords: lead adsorption, Pb2+, biochar, rice straw, variable charge soils, Ultisol, Oxisol, cation exchange capacity, surface complexation, electrostatic adsorption, soil amendment, heavy metal availability, pH effect
MeSH terms: Adsorption, Cations, Divalent, Charcoal, Hydrogen-Ion Concentration, Lead, Oryza, Soil, Soil Pollutants

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Adsorption of Pb(II) on variable charge soils amended with rice-straw derived biochar

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