The contemporary role of ε-caprolactone chemistry to create advanced polymer architectures

Sisson, Adam L.; Ekinci, Duygu; Lendlein, Andreas

doi:10.1016/j.polymer.2013.04.045

Cited by 190

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The contemporary role of ε-caprolactone chemistry to create advanced polymer architectures

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Sisson, Adam L., Ekinci, Duygu, Lendlein, Andreas·2013·Polymer

DOI 10.1016/j.polymer.2013.04.045

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Abstract

Poly(ε-caprolactones) (PCLs) belong to the first generation of synthetic aliphatic polyesters. Their biodegradability motivated their extensive exploration as resorbable materials, particularly in controlled drug release applications. While PCL fell out of fashion due to the increasing popularity of shorter chain polyglycolides and derivatives, there has been a noticeable renewed interest in ε-caprolactone derived components for copolymer systems with advanced functions in the last decade or so. PCL has particular properties that are attractive for the design of tunable biomaterials such as slow crystallization kinetics and low melting temperatures in the physiological range. Slow degradation rates, with relatively minimal acid generation, can be valuable for prolonged drug release or longer-term stability of implants. Herein we cover recent developments of PCL chemistry, focussing on innovative uses of ε-caprolactone-based segments in sophisticated polymer architectures such as multiblock copolymer networks, and micellar systems. Such polymer constructs are of high interest for biomedical applications.

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Biomedical applications of biodegradable polymers
Ulery, B. D., Nair, L. S., & Laurencin, C. T. (2011) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.22259 · Cited by 2,206
Biodegradable, Elastic Shape-Memory Polymers for Potential Biomedical Applications
Lendlein, A., & Langer, R. (2002) · Science · doi:10.1126/science.1066102 · Cited by 2,146
Self-citation
Aliphatic polyester polymer stars: Synthesis, properties and applications in biomedicine and nanotechnology
Cameron, D. J. A., & Shaver, M. P. (2011) · Chem. Soc. Rev. · doi:10.1039/c0cs00091d · Cited by 421
Synthesis and evaluation of a star amphiphilic block copolymer from poly (ε-caprolactone) and poly (ethylene glycol) as a potential drug delivery carrier
Wang, F., Bronich, T. K., Kabanov, A. V., Rauh, R. D., & Roovers, J. (2005) · Bioconjugate Chemistry · doi:10.1021/bc049784m · Cited by 317
Polycaprolactone-b-poly(ethylene Oxide) Block Copolymer Micelles as a Novel Drug Delivery Vehicle for Neurotrophic Agents FK506 and L-685,818
Allen, C., Yu, Y., Maysinger, D., & Eisenberg, A. (1998) · Bioconjugate Chemistry · doi:10.1021/bc9702157 · Cited by 273
Effects of crystalline microstructure on drug release behavior of poly(ε-caprolactone) microspheres
Jeong, J.-C., Lee, J., & Cho, K. (2003) · Journal of Controlled Release · doi:10.1016/s0168-3659(03)00367-5 · Cited by 209
Synthesis and characterization of degradable polyurethane elastomers containing an amino acid-based chain extender
Skarja, G. A., & Woodhouse, K. A. (1998) · Journal of Biomaterials Science, Polymer Edition · doi:10.1163/156856298x00659 · Cited by 173
A Novel Route To Poly(ε-caprolactone)-Based Copolymers via Anionic Derivatization
Ponsart, S., Coudane, J., & Vert, M. (2000) · Biomacromolecules · doi:10.1021/bm005521t · Cited by 126
Biodegradable Shape-Memory Polymers Exhibiting Sharp Thermal Transitions and Controlled Drug Release
Nagahama, K., Ueda, Y., Ouchi, T., & Ohya, Y. (2009) · Biomacromolecules · doi:10.1021/bm9002078 · Cited by 124

Show all 12 references

Research works printed but not linked: 224

Jenkins, 2006, Polym Adv Technol, 17, 474, 10.1002/pat.733 · DOI · Paper page
Kulkarni, 2007, Langmuir, 23, 12202, 10.1021/la701523e · DOI
Karimi, 2012, J Supercrit Fluid, 61, 175, 10.1016/j.supflu.2011.09.022 · DOI
Nair, 2007, Prog Polym Sci, 32, 762, 10.1016/j.progpolymsci.2007.05.017 · DOI · Paper page
Zhuravlev, 2011, Polymer, 52, 1983, 10.1016/j.polymer.2011.03.013 · DOI · Paper page
Penczek, 2007, Prog Polym Sci, 32, 247, 10.1016/j.progpolymsci.2007.01.002 · DOI · Paper page
Duda, 2012, ROP of cyclic esters. Mechanisms of ionic and coordination processes, vol. 4, 213
Labet, 2009, Chem Soc Rev, 38, 3484, 10.1039/b820162p · DOI · Paper page
Okada, 2002, Prog Polym Sci, 27, 87, 10.1016/S0079-6700(01)00039-9 · DOI · Paper page
Dash, 2012, J Control Release, 158, 15, 10.1016/j.jconrel.2011.09.064 · DOI · Paper page
Cai, 2000, J Biomater Sci Polym Ed, 11, 273, 10.1163/156856200743698 · DOI · Paper page
Hu, 2004, Polym Degrad Stab, 85, 705, 10.1016/j.polymdegradstab.2003.12.010 · DOI
Wang, 2003, Macromol Symp, 195, 263, 10.1002/masy.200390132 · doi:10.1002/masy.200390132
Kasperczyk, 2008, J Appl Polym Sci, 107, 3258, 10.1002/app.27404 · DOI
Weiss, 2011, J Polym Sci Part A Polym Chem, 49, 1847, 10.1002/pola.24610 · DOI
Dubois, 1993, Macromolecules, 26, 2730, 10.1021/ma00063a015 · DOI
Baez, 2006, Polymer, 47, 8420, 10.1016/j.polymer.2006.10.023 · DOI
Kloss, 2002, Polym Sci Part A Polym Chem, 40, 4117, 10.1002/pola.10499 · DOI
Lendlein, 2000, Macromol Chem Phys, 201, 1067, 10.1002/1521-3935(20000701)201:11<1067::AID-MACP1067>3.0.CO;2-Y · DOI
Guillaume, 2003, Macromolecules, 36, 54, 10.1021/ma020993g · DOI
Hwang, 2005, Biomacromolecules, 6, 885, 10.1021/bm049347a · DOI · Paper page
Ferruti, 2003, Biomacromolecules, 4, 181, 10.1021/bm020115q · DOI
Wang, 2001, Biomacromolecules, 2, 1206, 10.1021/bm010093s · DOI
Wang, 2006, Biomaterials, 27, 832, 10.1016/j.biomaterials.2005.07.013 · DOI
Kricheldorf, 2001, Biomacromolecules, 2, 1110, 10.1021/bm0100561 · DOI
Schappacher, 2006, Biomacromolecules, 7, 1373, 10.1021/bm060008m · DOI
Toncheva, 2007, Adv Polym Technol, 26, 121, 10.1002/adv.20093 · doi:10.1002/adv.20093
Ferreira, 2008, Int J Pharm, 352, 172, 10.1016/j.ijpharm.2007.10.026 · DOI
Clement, 2009, Biomacromolecules, 10, 1436, 10.1021/bm900003f · DOI
Lu, 2002, Bioconjug Chem, 13, 1159, 10.1021/bc025531m · DOI
Le Hellaye, 2008, Biomacromolecules, 9, 1924, 10.1021/bm8001792 · DOI
Zhou, 2008, Chem Commun, 44, 5806, 10.1039/b810297j · DOI
Stoilova, 2006, Chem Mater, 18, 4917, 10.1021/cm060796m · DOI
Stoilova, 2007, Polymer, 48, 1835, 10.1016/j.polymer.2007.02.026 · DOI
Sinnwell, 2008, Macromol Rapid Commun, 29, 1090, 10.1002/marc.200800233 · DOI
Gou, 2009, J Polym Sci Part A Polym Chem, 47, 2905, 10.1002/pola.23371 · DOI
Li, 2008, Chem Eur J, 14, 358, 10.1002/chem.200700603 · DOI
Xiong, 2010, Polym Bull, 65, 455, 10.1007/s00289-009-0221-1 · DOI
Carrot, 1999, Macromolecules, 32, 5264, 10.1021/ma990198b · DOI
Hedfors, 2005, Macromolecules, 38, 647, 10.1021/ma048056r · DOI
Wiltshire, 2009, J Polym Sci Part A Polym Chem, 47, 1485, 10.1002/pola.23206 · DOI
Wu, 2010, Pharm Res, 27, 187, 10.1007/s11095-009-9998-8 · DOI
Zhang, 2009, Polym Int, 58, 752, 10.1002/pi.2588 · DOI
Motala-Timol, 2007, Polym Int, 56, 1053, 10.1002/pi.2243 · doi:10.1002/pi.2243
Hedrick, 1998, Macromolecules, 31, 8691, 10.1021/ma980932b · DOI · Paper page
Jia, 2005, J Polym Sci Part A Polym Chem, 43, 6534, 10.1002/pola.21128 · DOI
Schramm, 2009, Macromolecules, 42, 1808, 10.1021/ma8024738 · DOI
Chen, 2005, J Macromol Sci Pure Appl Chem, A42, 1247, 10.1080/10601320500189554 · DOI
Shi, 2004, Polym Bull, 52, 401, 10.1007/s00289-004-0303-z · DOI
Lele, 2002, Polymer, 43, 5595, 10.1016/S0032-3861(02)00435-4 · DOI
Perret, 1972, Makromol Chem, 162, 143, 10.1002/macp.1972.021560111 · DOI
Liu, 2008, J Biomed Mater Res Part B Appl Biomater, 84B, 165, 10.1002/jbm.b.30858 · DOI · Paper page
Bae, 2005, Macromolecules, 38, 5260, 10.1021/ma050489m · DOI · Paper page
An, 2001, J Mater Sci, 36, 715, 10.1023/A:1004845109809 · DOI
Ryu, 2000, Int J Pharm, 200, 231, 10.1016/S0378-5173(00)00392-6 · DOI
Quaglia, 2008, Biomed Mater Res Part A, 87A, 563, 10.1002/jbm.a.31804 · DOI
Kricheldorf, 2003, Biomacromolecules, 4, 950, 10.1021/bm0300148 · DOI
Huang, 2004, J Biomed Mater Res Part A, 69A, 417, 10.1002/jbm.a.30008 · DOI
Li, 2002, Biomacromolecules, 3, 525, 10.1021/bm010168s · DOI
Zastre, 2004, Pharm Res, 21, 1489, 10.1023/B:PHAM.0000036925.45002.a2 · DOI
Zastre, 2007, J Pharm Sci, 96, 864, 10.1002/jps.20785 · DOI
Elamanchili, 2009, J Pharm Sci, 98, 945, 10.1002/jps.21479 · DOI
Kang, 2010, Biomaterials, 31, 2453, 10.1016/j.biomaterials.2009.11.115 · DOI
Rieger, 2006, Adv Funct Mater, 16, 1506, 10.1002/adfm.200500110 · DOI · Paper page
Petrova, 2009, Eur Polym J, 45, 3442, 10.1016/j.eurpolymj.2009.09.009 · DOI
Shuai, 2001, Macromolecules, 34, 7355, 10.1021/ma0109626 · DOI
Shuai, 2002, Biomacromolecules, 3, 201, 10.1021/bm015609m · DOI
Bogdanov, 1999, J Therm Anal Calorim, 56, 1115, 10.1023/A:1010100927407 · DOI
Gorna, 2002, J Polym Sci Part A Polym Chem, 40, 156, 10.1002/pola.10096 · DOI
Skarja, 2001, J Biomater Sci Polym Ed, 12, 851, 10.1163/156856201753113060 · DOI
deGroot, 1996, Biomaterials, 17, 163, 10.1016/0142-9612(96)85761-9 · DOI · Paper page
Lendlein, 1998, Macromol Chem Phys, 199, 2785, 10.1002/(SICI)1521-3935(19981201)199:12<2785::AID-MACP2785>3.0.CO;2-X · DOI
Ciardelli, 1997, Macromol Chem Phys, 198, 1481, 10.1002/macp.1997.021980514 · DOI
Kratz, 2012, Adv Funct Mater, 22, 3057, 10.1002/adfm.201200211 · DOI
Gorna, 2002, J Biomed Mater Res, 60, 592, 10.1002/jbm.10100 · DOI
Zhang, 2006, J Biomed Mater Res Part B Appl Biomater, 79B, 335, 10.1002/jbm.b.30547 · DOI
Cao, 2008, Carbohydr Polym, 71, 119, 10.1016/j.carbpol.2007.05.023 · DOI
Santayanon, 2003, Carbohydr Polym, 51, 17, 10.1016/S0144-8617(02)00109-1 · DOI
Zhang, 2008, J Control Release, 131, 128, 10.1016/j.jconrel.2008.07.026 · doi:10.1016/j.jconrel.2008.07.026
Buruiana, 2004, J Biomater Sci Polym Ed, 15, 781, 10.1163/156856204774196162 · DOI
Woo, 2000, Biomaterials, 21, 1235, 10.1016/S0142-9612(00)00003-X · DOI · Paper page
Baron, 2009, Int J Adhes Adhes, 29, 1, 10.1016/j.ijadhadh.2007.02.008 · doi:10.1016/j.ijadhadh.2007.02.008
Gisselfalt, 2002, Biomacromolecules, 3, 951, 10.1021/bm025535u · DOI
Guan, 2005, Biomacromolecules, 6, 2833, 10.1021/bm0503322 · DOI
Yu, 2006, Biopolymer, 83, 233, 10.1002/bip.20551 · DOI
Liu, 2005, Biopolymer, 78, 163, 10.1002/bip.20261 · DOI
Liu, 2005, Carbohydr Polym, 60, 351, 10.1016/j.carbpol.2005.01.009 · doi:10.1016/j.carbpol.2005.01.009
Duan, 2010, Carbohydr Polym, 80, 498, 10.1016/j.carbpol.2009.12.013 · DOI
Lu, 2007, Biopolymer, 86, 403, 10.1002/bip.20743 · doi:10.1002/bip.20743
Huang, 2010, J Mater Sci Mater Med, 21, 557, 10.1007/s10856-009-3880-4 · DOI
Chen, 2005, Carbohydr Polym, 60, 103, 10.1016/j.carbpol.2004.11.028 · DOI
Sugih, 2009, Carbohydr Polym, 77, 267, 10.1016/j.carbpol.2008.12.032 · doi:10.1016/j.carbpol.2008.12.032
Barikani, 2007, Carbohydr Polym, 68, 773, 10.1016/j.carbpol.2006.08.017 · DOI
Seiffert, 2012, Chem Soc Rev, 41, 909, 10.1039/C1CS15191F · DOI · Paper page
Bender, 2002, J Am Chem Soc, 124, 8526, 10.1021/ja0261269 · DOI
Hoogenboom, 2006, Chem Commun, 38, 4010, 10.1039/B608313G · DOI · Paper page
Nawaby, 2005, Biomacromolecules, 6, 2458, 10.1021/bm050223n · DOI
Fustin, 2007, Adv Mater, 19, 1665, 10.1002/adma.200602170 · DOI · Paper page
Luo, 2010, J Phys Chem B, 114, 4739, 10.1021/jp1001836 · DOI
Shuai, 2005, Bioconjug Chem, 16, 322, 10.1021/bc0498471 · DOI
Wu, 2008, Langmuir, 24, 10306, 10.1021/la8006876 · DOI · Paper page
Dai, 2006, Biomacromolecules, 7, 3527, 10.1021/bm060725g · DOI
Wisse, 2006, Biomacromolecules, 7, 3385, 10.1021/bm060688t · DOI
van Beek, 2007, Macromolecules, 40, 6340, 10.1021/ma0705927 · DOI
Wietor, 2011, Macromolecules, 44, 1211, 10.1021/ma1026065 · DOI
Kim, 2008, ACS Nano, 2, 386, 10.1021/nn700408z · DOI · Paper page
Choi, 2005, Polymer, 46, 9725, 10.1016/j.polymer.2005.08.057 · DOI
Wang, 2006, Polymer, 47, 3218, 10.1016/j.polymer.2006.02.047 · DOI · Paper page
Xie, 2008, Macromol Biosci, 8, 775, 10.1002/mabi.200800011 · DOI
Wang, 2005, J Polym Sci Part A Polym Chem, 43, 5449, 10.1002/pola.20954 · DOI
Lang, 2002, J Polym Sci Part A Polym Chem, 40, 1127, 10.1002/pola.10171 · DOI
Celik, 2009, React Funct Polym, 69, 705, 10.1016/j.reactfunctpolym.2009.05.005 · DOI
Cui, 2004, Eur Polym J, 40, 299, 10.1016/j.eurpolymj.2003.09.024 · DOI
Yuan, 2007, J Appl Polym Sci, 104, 2310, 10.1002/app.25699 · DOI
Wu, 2009, Chem Commun, 14, 1822, 10.1039/B818790H · doi:10.1039/b818790h
Gou, 2008, J Polym Sci Part A Polym Chem, 46, 6455, 10.1002/pola.22955 · DOI
Xu, 2006, Polymer, 47, 5161, 10.1016/j.polymer.2006.04.062 · DOI
Chan, 2005, Macromolecules, 38, 3099, 10.1021/ma050036h · DOI
Hecht, 1999, J Am Chem Soc, 121, 9239, 10.1021/ja9922882 · DOI
Hecht, 2001, J Am Chem Soc, 123, 18, 10.1021/ja003304u · DOI
Smet, 2005, Macromol Chem Phys, 206, 2421, 10.1002/macp.200500397 · DOI
Meier, 2004, J Am Chem Soc, 126, 11517, 10.1021/ja0488481 · doi:10.1021/ja0488481
Joncheray, 2006, Langmuir, 22, 9264, 10.1021/la061290l · DOI
Burgath, 2000, Macromol Chem Phys, 201, 792, 10.1002/(SICI)1521-3935(20000401)201:7<792::AID-MACP792>3.0.CO;2-K · DOI
Ding, 2009, J Appl Polym Sci, 112, 1209, 10.1002/app.29584 · DOI
Hans, 2006, Macromolecules, 39, 3184, 10.1021/ma052657g · DOI
Cao, 2009, J Polym Sci Part A Polym Chem, 47, 5184, 10.1002/pola.23568 · DOI
Lin, 2008, Biomacromolecules, 9, 2629, 10.1021/bm800607a · DOI
Yang, 2007, Eur Polym J, 43, 2298, 10.1016/j.eurpolymj.2007.03.039 · DOI
Yang, 2009, J Biomed Mater Res Part A, 89A, 988, 10.1002/jbm.a.31881 · DOI
Heise, 2001, Macromolecules, 34, 2798, 10.1021/ma0012954 · DOI
Tunca, 2004, J Polym Sci Part A Polym Chem, 42, 4228, 10.1002/pola.20284 · DOI
Yuan, 2008, Macromolecules, 41, 8620, 10.1021/ma801452n · DOI
Saito, 2008, Macromolecules, 41, 8815, 10.1021/ma801001s · DOI
Altintas, 2009, Des Monomers Polym, 12, 83, 10.1163/156855508X391158 · DOI
Yang, 2008, J Polym Sci Part A Polym Chem, 46, 6641, 10.1002/pola.22975 · DOI
Chen, 2008, Polymer, 49, 3965, 10.1016/j.polymer.2008.06.056 · DOI
Miura, 2007, J Polym Sci Part A Polym Chem, 45, 1159, 10.1002/pola.21885 · DOI
Gou, 2010, Biomacromolecules, 11, 934, 10.1021/bm901371p · DOI
Wang, 2008, J Polym Sci Part A Polym Chem, 46, 1388, 10.1002/pola.22479 · DOI
Du, 2004, Macromolecules, 37, 3588, 10.1021/ma035457i · DOI
Wiltshire, 2006, Macromolecules, 39, 9018, 10.1021/ma0622027 · DOI
Kweon, 2003, Biomaterials, 24, 801, 10.1016/S0142-9612(02)00370-8 · DOI · Paper page
Busby, 2001, Biomacromolecules, 2, 154, 10.1021/bm0000889 · doi:10.1021/bm0000889
Pereira, 2010, Acta Biomater, 6, 3056, 10.1016/j.actbio.2010.02.036 · doi:10.1016/j.actbio.2010.02.036
Lendlein, 2005, J Polym Sci Part A Polym Chem, 43, 1369, 10.1002/pola.20598 · DOI · Paper page
Lendlein, 2001, Proc Natl Acad Sci U S A, 98, 842
Kelch, 2007, Biomacromolecules, 8, 1018, 10.1021/bm0610370 · DOI
Wischke, 2010, Macromol Biosci, 10, 1063, 10.1002/mabi.201000089 · DOI
Zotzmann, 2010, Adv Mater, 22, 3424, 10.1002/adma.200904202 · DOI · Paper page
Zotzmann, 2010, Adv Funct Mater, 20, 3583, 10.1002/adfm.201000478 · DOI · Paper page
Jabbari, 2005, Biomacromolecules, 6, 2503, 10.1021/bm050206y · DOI
Sharifi, 2008, Polym Adv Technol, 19, 1828, 10.1002/pat.1207 · doi:10.1002/pat.1207
Wu, 2003, J Biomater Sci Polym Ed, 14, 777, 10.1163/156856203768366521 · DOI
Turunen, 2002, Polym Int, 51, 92, 10.1002/pi.805 · DOI
Bat, 2008, Biomacromolecules, 9, 3208, 10.1021/bm8007988 · DOI
Cho, 1999, Int J Pharm, 181, 235, 10.1016/S0378-5173(99)00031-9 · DOI
Fay, 2007, Biomacromolecules, 8, 1751, 10.1021/bm061013t · DOI
Sahoo, 2010, Carbohydr Polym, 79, 106, 10.1016/j.carbpol.2009.07.042 · DOI
Lemmouchi, 1998, J Control Release, 55, 79, 10.1016/S0168-3659(98)00021-2 · doi:10.1016/s0168-3659(98)00021-2
Turunen, 2006, J Appl Polym Sci, 101, 3677, 10.1002/app.22832 · DOI
Coccoli, 2008, J Mater Sci Mater Med, 19, 1703, 10.1007/s10856-007-3253-9 · DOI
Campos, 2008, J Microencapsul, 25, 154, 10.1080/02652040701806476 · DOI
Benoit, 1999, Int J Pharm, 184, 73, 10.1016/S0378-5173(99)00109-X · doi:10.1016/s0378-5173(99)00109-x
Gutierrez-Pauls, 2007, Pharmazie, 62, 864
Shah, 2006, Pharm Res, 23, 2638, 10.1007/s11095-006-9101-7 · DOI
Ahmed, 2004, J Control Release, 96, 37, 10.1016/j.jconrel.2003.12.021 · DOI · Paper page
Allen, 2000, J Control Release, 63, 275, 10.1016/S0168-3659(99)00200-X · DOI · Paper page
Aliabadi, 2005, J Control Release, 104, 301, 10.1016/j.jconrel.2005.02.015 · DOI · Paper page
Kim, 2010, Int J Cosmet Sci, 32, 185, 10.1111/j.1468-2494.2010.00526.x · DOI
Park, 2005, J Control Release, 109, 158, 10.1016/j.jconrel.2005.09.039 · DOI · Paper page
Hu, 2010, Biomacromolecules, 11, 481, 10.1021/bm901211r · DOI
Quaglia, 2006, Int J Pharm, 324, 56, 10.1016/j.ijpharm.2006.07.020 · DOI
Balmayor, 2009, Acta Biomater, 5, 1035, 10.1016/j.actbio.2008.11.006 · DOI
Geng, 2005, J Am Chem Soc, 127, 12780, 10.1021/ja053902e · DOI · Paper page
Cai, 2007, Pharm Res, 24, 2099, 10.1007/s11095-007-9335-z · DOI · Paper page
Kim, 1998, J Control Release, 51, 13, 10.1016/S0168-3659(97)00124-7 · DOI · Paper page
Duncan, 2003, Nat Rev Drug Discov, 2, 347, 10.1038/nrd1088 · DOI · Paper page
Gros, 1981, Angew Chem Int Ed, 20, 305, 10.1002/anie.198103051 · DOI · Paper page
Duan, 2010, Colloid Surf B, 76, 475, 10.1016/j.colsurfb.2009.12.007 · DOI
Du, 2006, Biomacromolecules, 7, 1898, 10.1021/bm051003c · DOI
Azzam, 2007, Langmuir, 23, 2126, 10.1021/la0627563 · DOI
Gong, 2009, J Phys Chem B, 113, 10183, 10.1021/jp902697d · DOI
Sheikh, 2009, J Mater Sci Mater Med, 20, 821, 10.1007/s10856-008-3637-5 · DOI
Kim, 2005, J Microencapsul, 22, 193, 10.1080/02652040400015346 · DOI
Slomkowski, 2012, Ring-opening dispersion polymerization, vol. 4, 645
Lemoine, 1996, Biomaterials, 17, 2191, 10.1016/0142-9612(96)00049-X · DOI · Paper page
Lemarchand, 2003, Pharm Res, 20, 1284, 10.1023/A:1025017502379 · DOI
Wang, 2008, Int J Pharm, 350, 130, 10.1016/j.ijpharm.2007.08.030 · doi:10.1016/j.ijpharm.2007.08.030
Calvo, 1996, Pharm Res, 13, 311, 10.1023/A:1016015803611 · DOI
Cauchetier, 2003, Int J Pharm, 250, 273, 10.1016/S0378-5173(02)00556-2 · doi:10.1016/s0378-5173(02)00556-2
Espuelas, 2002, J Drug Target, 10, 593, 10.1080/1061186021000060738 · doi:10.1080/1061186021000060738
Jiao, 2002, Drug Dev Ind Pharm, 28, 1033, 10.1081/DDC-120014740 · DOI
Hamoudeh, 2006, J Colloid Interface Sci, 300, 584, 10.1016/j.jcis.2006.04.024 · DOI
Karatas, 2009, J Microencapsul, 26, 63, 10.1080/02652040802141039 · DOI
Jang, 2006, J Control Release, 113, 173, 10.1016/j.jconrel.2006.03.021 · DOI
Elvira, 2004, J Control Release, 99, 231, 10.1016/j.jconrel.2004.06.020 · DOI
Ghaderi, 1999, Pharm Res, 16, 676, 10.1023/A:1018868423309 · DOI
Busby, 2005, Adv Mater, 17, 364, 10.1002/adma.200400297 · DOI
Lee, 2008, J Phys Chem Solids, 69, 1596, 10.1016/j.jpcs.2007.09.016 · DOI

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Background
Ring-opening polymerization and copolymerization of cyclic esters catalyzed by amidinate aluminum complexes
Osorio Meléndez, D., Castro‐Osma, J. A., Lara‐Sánchez, A., Rojas, R. S., & Otero, A. (2017) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.28629 · Cited by 38

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Authors: Sisson, A. L., Ekinci, D., & Lendlein, A.
Venue: Polymer
Publisher: Elsevier BV
Published: 2013-08
Volume: 54
Issue: 17
Pages: 4333-4350
ISSN: 0032-3861 (ISSN-L)
DOI: 10.1016/j.polymer.2013.04.045
OpenAlex: W2042278836
Cited by: 190
References: 12
FWCI: 4.19
Type: journal article
Language: en
Open access: hybrid
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
creativecommons.org/licenses/by-nc-nd/3.0/ (vor, 12 d)

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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

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Cite CoChat for the checks on this page, and the paper for its own findings.

This page: CoChat. (2026). Citation check: The contemporary role of ε-caprolactone chemistry to create advanced polymer architectures. https://app.cochat.ai/papers/10.1016/j.polymer.2013.04.045
The paper: Sisson, A. L., Ekinci, D., & Lendlein, A. (2013). The contemporary role of ε-caprolactone chemistry to create advanced polymer architectures. Polymer. https://doi.org/10.1016/j.polymer.2013.04.045

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.

The contemporary role of ε-caprolactone chemistry to create advanced polymer architectures

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