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Curved Surface Boosts Electrochemical CO2 Reduction to Formate via Bismuth Nanotubes in a Wide Potential Window

Fan, Ke, Jia, Yufei, Ji, Yongfei, Kuang, Panyong, Zhu, Bicheng, Liu, Xiangyu, Yu, Jiaguo·2020·ACS Catalysis

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Abstract

Electrochemical CO 2 reduction reaction (CO2RR) to formate is considered as one of the most promising routes for value-added fuels and chemical productions. The achievement of excellent activity and high Faradaic efficiency in a wide potential range is critical for mature applications. To this regard, we first employed density functional theory simulations to predict activity of Bi nanotubes and Bi nanosheets to CO2RR and selectivity toward formate. The theoretical thermodynamic analysis of the reaction energetics suggests that the limiting potential for CO 2 reduction to HCOOH decreases with the increase of the curvature, suggesting a wider potential window of Bi nanotubes for formate formation. Then, Bi nanotubes with highly curved surface were experimentally prepared, showing a large current density (−39.4 mA cm –2 at −1.1 V vs reversible hydrogen electrode (RHE)) for CO 2 reduction and a maximum formate selectivity of 97% at −1.0 V vs RHE. More importantly, compared with Bi nanosheets, an appreciable selectivity for formate was achieved on Bi nanotubes in a significantly wider potential window of ∼600 mV (selectivity > 80%). This research provides not only the CO2RR activity–surface structure relationship of metallic Bi but also an efficient strategy for the rational design of electrocatalysts with high activity and selectivity in a wide potential window for CO2RR, which is favorable for compatible application with varied types of photovoltaics and other renewable energy sources.

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Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction
Wang, W.-H., Himeda, Y., Muckerman, J. T., Manbeck, G. F., & Fujita, E. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00197 · Cited by 1,507
Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products
Gao, D., Arán-Ais, R. M., Jeon, H. S., & Roldan Cuenya, B. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0235-5 · Cited by 1,489
A selective and efficient electrocatalyst for carbon dioxide reduction
Lu, Q., Rosen, J., Zhou, Y., Hutchings, G. S., Kimmel, Y. C., Chen, J. G., & Jiao, F. (2014) · Nature Communications · doi:10.1038/ncomms4242 · Cited by 1,478
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO2 to CO
Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,382
Hierarchical Porous O‐Doped g‐C3N4 with Enhanced Photocatalytic CO2 Reduction Activity
Fu, J., Zhu, B., Jiang, C., Cheng, B., You, W., & Yu, J. (2017) · Small · doi:10.1002/smll.201603938 · Cited by 1,291
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Surface modification and enhanced photocatalytic CO2 reduction performance of TiO2: a review
Low, J., Cheng, B., & Yu, J. (2017) · Applied Surface Science · doi:10.1016/j.apsusc.2016.09.093 · Cited by 1,181
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Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate
Han, N., Wang, Y., Yang, H., Deng, J., Wu, J., Li, Y., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03712-z · Cited by 914
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In Situ Grown Monolayer N‐Doped Graphene on CdS Hollow Spheres with Seamless Contact for Photocatalytic CO2 Reduction
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Lim, B., Jiang, M., Tao, J., Camargo, P. H. C., Zhu, Y., & Xia, Y. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200801439 · Cited by 612
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate
Luc, W., Fu, X., Shi, J., Lv, J.-J., Jouny, M., Ko, B. H., Xu, Y., Tu, Q., Hu, X., Wu, J., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0269-8 · Cited by 600
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Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530
Review on nanoscale Bi-based photocatalysts
He, R., Xu, D., Cheng, B., Yu, J., & Ho, W. (2018) · Nanoscale Horizons · doi:10.1039/c8nh00062j · Cited by 518
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Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086796 · Cited by 482
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Kumar, B., Atla, V., Brian, J. P., Kumari, S., Nguyen, T. Q., Sunkara, M., & Spurgeon, J. M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612194 · Cited by 451
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Grosse, P., Gao, D., Scholten, F., Sinev, I., Mistry, H., & Roldan Cuenya, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802083 · Cited by 425
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Varela, A. S., Ju, W., Bagger, A., Franco, P., Rossmeisl, J., & Strasser, P. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01405 · Cited by 390
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Hu, X.-M., Hval, H. H., Bjerglund, E. T., Dalgaard, K. J., Madsen, M. R., Pohl, M.-M., Welter, E., Lamagni, P., Buhl, K. B., Bremholm, M., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01022 · Cited by 344
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Guo, S., Zhang, Y., Zhang, X., Easton, C. D., MacFarlane, D. R., & Zhang, J. (2019) · ChemSusChem · doi:10.1002/cssc.201802409 · Cited by 48
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Wu, J., Risalvato, F. G., & Zhou, X. (2012) · ECS Transactions · doi:10.1149/1.3702412 · Cited by 23
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Authors: Fan, K., Jia, Y., Ji, Y., Kuang, P., Zhu, B., Liu, X., & Yu, J.
Venue: ACS Catalysis
Publisher: American Chemical Society (ACS)
Published: 2019-11-27
Volume: 10
Issue: 1
Pages: 358-364
ISSN: 2155-5435 (ISSN-L)
DOI: 10.1021/acscatal.9b04516
OpenAlex: W2989589299
Cited by: 298
References: 52
FWCI: 7.47
Type: journal article
Language: en
Open access: closed

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Curved Surface Boosts Electrochemical CO2 Reduction to Formate via Bismuth Nanotubes in a Wide Potential Window

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