The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Mechanisms for strong adsorption of tetracycline to carbon nanotubes: A comparative study using activated carbon and graphite as adsorbents
Abstract
Significant concerns have been raised over the presence of antibiotics including tetracyclines in aquatic environments. We herein studied single-walled carbon nanotubes (SWNT) and multi-walled carbon nanotubes (MWNT) as potential effective adsorbents for removal of tetracycline from aqueous solution. In comparison, a nonpolar adsorbate, naphthalene, and two other carbonaceous adsorbents, pulverized activated carbon (AC) and nonporous graphite, were used. The observed adsorbent-to-solution distribution coefficient (Kd, L/kg) of tetracycline was in the order of 10(4)-10(6) L/kg for SWNT, 10(3)-10(4) L/kg for MWNT, 10(3)-10(4) L/kg for AC, and 10(3)-10(5) L/kg for graphite. Upon normalization for adsorbent surface area, the adsorption affinity of tetracycline decreased in the order of graphite/ SWNT > MWNT >> AC. The weaker adsorption of tetracycline to AC indicates that for bulky adsorbates adsorption affinity is greatly affected by the accessibility of available adsorption sites. The remarkably strong adsorption of tetracycline to the carbon nanotubes and to graphite can be attributed to the strong adsorptive interactions (van der Waals forces, pi-pi electron-donor-acceptor interactions, cation-pi bonding) with the graphene surface. Complexation between tetracycline and model graphene compounds (naphthalene, phenanthrene, pyrene) in solution phase was verified by ring current-induced 1H NMR upfield chemical shifts of tetracycline moieties.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Kolpin, D. W., Furlong, E. T., Meyer, M. T., Thurman, E. M., Zaugg, S. D., Barber, L. B., & Buxton, H. T. (2002) · Environmental Science & Technology · doi:10.1021/es011055j · Cited by 7,953
Environmental Organic Chemistry
Schwarzenbach, R. P., Gschwend, P. M., & Imboden, D. M. (2002) · Wiley eBooks · doi:10.1002/0471649643 · Cited by 4,895
Ma, J. C., & Dougherty, D. A. (1997) · Chemical Reviews · doi:10.1021/cr9603744 · Cited by 3,477
Sarmah, A. K., Meyer, M. T., & Boxall, A. B. A. (2006) · Chemosphere · doi:10.1016/j.chemosphere.2006.03.026 · Cited by 3,326
Sussman, J. L., Harel, M., Frolow, F., Oefner, C., Goldman, A., Toker, L., & Silman, I. (1991) · Science · doi:10.1126/science.1678899 · Cited by 2,707
Occurrence of Antibiotics in the Aquatic Environment
Hirsch, R., Ternes, T., Haberer, K., & Kratz, K.-L. (1999) · Science of The Total Environment · doi:10.1016/s0048-9697(98)00337-4 · Cited by 2,140
Sorption of Veterinary Pharmaceuticals in Soils: A Review
Tolls, J. (2001) · Environmental Science & Technology · doi:10.1021/es0003021 · Cited by 1,388
Assessing the Risks of Manufactured Nanomaterials
Wiesner, M. R., Lowry, G. V., Alvarez, P., Dionysiou, D., & Biswas, P. (2006) · Environmental Science & Technology · doi:10.1021/es062726m · Cited by 1,160
Carbon Nanotubes as Superior Sorbent for Dioxin Removal
Long, R. Q., & Yang, R. T. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003830l · Cited by 845
Occurrence of Antimicrobials in the Final Effluents of Wastewater Treatment Plants in Canada
Miao, X.-S., Bishay, F., Chen, M., & Metcalfe, C. D. (2004) · Environmental Science & Technology · doi:10.1021/es030653q · Cited by 817
Peer Reviewed: Are Veterinary Medicines Causing Environmental Risks?
Boxall, A. B. A., Kolpin, D. W., Halling-Sørensen, B., & Tolls, J. (2003) · Environmental Science & Technology · doi:10.1021/es032519b · Cited by 796
Adsorption of Polar and Nonpolar Organic Chemicals to Carbon Nanotubes
Chen, W., Duan, L., & Zhu, D. (2007) · Environmental Science & Technology · doi:10.1021/es071230h · Cited by 756
Self-citationBenzene Forms Hydrogen Bonds with Water
Suzuki, S., Green, P. G., Bumgarner, R. E., Dasgupta, S., Goddard, W. A., & Blake, G. A. (1992) · Science · doi:10.1126/science.257.5072.942 · Cited by 720
Kumpf, R. A., & Dougherty, D. A. (1993) · Science · doi:10.1126/science.8378771 · Cited by 636
Modeling Tetracycline Antibiotic Sorption to Clays
Figueroa, R. A., Leonard, A., & MacKay, A. A. (2004) · Environmental Science & Technology · doi:10.1021/es0342087 · Cited by 621
Interaction of Tetracycline with Aluminum and Iron Hydrous Oxides
Gu, C., & Karthikeyan, K. G. (2005) · Environmental Science & Technology · doi:10.1021/es048603o · Cited by 558
Adsorption of 1,2-dichlorobenzene from water to carbon nanotubes
Peng, X., Li, Y., Luan, Z., Di, Z., Wang, H., Tian, B., & Jia, Z. (2003) · Chemical Physics Letters · doi:10.1016/s0009-2614(03)00960-6 · Cited by 538
Kulshrestha, P., Giese, & Aga, D. S. (2004) · Environmental Science & Technology · doi:10.1021/es034856q · Cited by 527
Sorption of Three Tetracyclines by Several Soils: Assessing the Role of pH and Cation Exchange
Sassman, S. A., & Lee, L. S. (2005) · Environmental Science & Technology · doi:10.1021/es0480217 · Cited by 526
Adsorption of zinc(II) from water with purified carbon nanotubes
Lu, C., & Chiu, H. (2006) · Chemical Engineering Science · doi:10.1016/j.ces.2005.08.007 · Cited by 519
Kim, S., Eichhorn, P., Jensen, J. N., Weber, A. S., & Aga, D. S. (2005) · Environmental Science & Technology · doi:10.1021/es050006u · Cited by 510
Algal toxicity of antibacterial agents used in intensive farming
Halling-Sørensen, B. (2000) · Chemosphere · doi:10.1016/s0045-6535(99)00445-2 · Cited by 498
Zhu, D., & Pignatello, J. J. (2005) · Environmental Science & Technology · doi:10.1021/es0491376 · Cited by 425
Self-citationAdsorption of Hydroxyl- and Amino-Substituted Aromatics to Carbon Nanotubes
Chen, W., Duan, L., Wang, L., & Zhu, D. (2008) · Environmental Science & Technology · doi:10.1021/es8013612 · Cited by 391
Self-citationComplexation of the antibiotic tetracycline with humic acid
Gu, C., Karthikeyan, K. G., Sibley, S. D., & Pedersen, J. A. (2007) · Chemosphere · doi:10.1016/j.chemosphere.2006.08.028 · Cited by 372
Environmental Risks of Nanotechnology: National Nanotechnology Initiative Funding, 2000−2004
Dunphy Guzmán, K. A., Taylor, M. R., & Banfield, J. F. (2006) · Environmental Science & Technology · doi:10.1021/es0515708 · Cited by 355
Pils, J. R. V., & Laird, D. A. (2007) · Environmental Science & Technology · doi:10.1021/es062316y · Cited by 318
Desorption of polycyclic aromatic hydrocarbons from carbon nanomaterials in water
Yang, K., & Xing, B. (2007) · Environmental Pollution · doi:10.1016/j.envpol.2006.04.020 · Cited by 314
Chen, Y., Hu, C., Qu, J., & Yang, M. (2008) · Journal of Photochemistry and Photobiology A: Chemistry · doi:10.1016/j.jphotochem.2007.12.007 · Cited by 290
Gotovac, S., Honda, H., Hattori, Y., Takahashi, K., Kanoh, H., & Kaneko, K. (2007) · Nano Letters · doi:10.1021/nl0622597 · Cited by 283
Zhu, D., Kwon, S., & Pignatello, J. J. (2005) · Environmental Science & Technology · doi:10.1021/es050129e · Cited by 272
Self-citationChen, J., Chen, W., & Zhu, D. (2008) · Environmental Science & Technology · doi:10.1021/es801412j · Cited by 271
Self-citationTetracyclines and Tetracycline Resistance in Agricultural Soils: Microcosm and Field Studies
Schmitt, H., Stoob, K., Hamscher, G., Smit, E., & Seinen, W. (2006) · Microbial Ecology · doi:10.1007/s00248-006-9035-y · Cited by 232
Oxytetracycline Sorption to Organic Matter by Metal‐Bridging
MacKay, A. A., & Canterbury, B. (2005) · Journal of Environmental Quality · doi:10.2134/jeq2005.0014 · Cited by 199
Factors influencing the sorption of oxytetracycline to soils
Jones, A. D., Bruland, G. L., Agrawal, S. G., & Vasudevan, D. (2005) · Environmental Toxicology and Chemistry · doi:10.1897/04-037r.1 · Cited by 180
Macrocyclic polyethers as probes to assess and understand alkali metal cation-π interactions
Gokel, G. W., Barbour, L. J., De Wall, S. L., & Meadows, E. S. (2001) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(01)00380-0 · Cited by 174
1,2-Dichlorobenzene Interacting with Carbon Nanotubes
Fagan, S. B., Souza Filho, A. G., Lima, J. O. G., Filho, J. M., Ferreira, O. P., Mazali, I. O., Alves, O. L., & Dresselhaus, M. S. (2004) · Nano Letters · doi:10.1021/nl0493895 · Cited by 160
Phenanthrene Adsorption from Solution on Single Wall Carbon Nanotubes
Atlagić, S. G., Hattori, Y., Noguchi, D., Miyamoto, J., Kanamaru, M., Utsumi, S., Kanoh, H., & Kaneko, K. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0611830 · Cited by 127
Qu, X., Liu, P., & Zhu, D. (2008) · Environmental Science & Technology · doi:10.1021/es071613f · Cited by 117
Self-citationREMOVAL OF TETRACYCLINE AND SULFONAMIDE CLASSES OF ANTIBIOTIC COMPOUND BY POWDERED ACTIVATED CARBON
Choi, K. J., Kim, S. ‐., & Kim, S. ‐. (2008) · Environmental Technology · doi:10.1080/09593330802102223 · Cited by 109
Formation of π–π Complexes between Phenanthrene and Model π‐Acceptor Humic Subunits
Wijnja, H., Pignatello, J. J., & Malekani, K. (2004) · Journal of Environmental Quality · doi:10.2134/jeq2004.2650 · Cited by 97
Qu, X., Wang, X., & Zhu, D. (2007) · Environmental Science & Technology · doi:10.1021/es0718117 · Cited by 73
Self-citation
Cited by
Applications of nanotechnology in water and wastewater treatment
Qu, X., Alvarez, P. J. J., & Li, Q. (2013) · Water Research · doi:10.1016/j.watres.2012.09.058 · Cited by 2,444
Adsorption of VOCs onto engineered carbon materials: A review
Zhang, X., Gao, B., Creamer, A. E., Cao, C., & Li, Y. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2017.05.013 · Cited by 1,479
Role of nanomaterials in water treatment applications: A review
Santhosh, C., Velmurugan, V., Jacob, G., Jeong, S. K., Grace, A. N., & Bhatnagar, A. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.08.053 · Cited by 1,256
Adsorptive removal of antibiotics from water and wastewater: Progress and challenges
Ahmed, M. B., Zhou, J. L., Ngo, H. H., & Guo, W. (2015) · Science of The Total Environment · doi:10.1016/j.scitotenv.2015.05.130 · Cited by 1,207
Qu, X., Brame, J., Li, Q., & Alvarez, P. J. J. (2013) · Accounts of Chemical Research · doi:10.1021/ar300029v · Cited by 799
Metadata
- Authors
- Ji, L., Chen, W., Duan, L., & Zhu, D.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-02-27
- Volume
- 43
- Issue
- 7
- Pages
- 2322-2327
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2079209529
- Cited by
- 801
- References
- 42
- FWCI
- 23.75
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
