Hydrogen Sorption in Functionalized Metal−Organic Frameworks

Rowsell, Jesse L. C., Millward, Andrew R., Park, Kyo Sung, Yaghi, Omar M.·2004·Journal of the American Chemical Society

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Abstract

Five porous metal-organic frameworks based on linking zinc oxide clusters with benzene-1,4-dicarboxylate, naphthalene-2,6-dicarboxylate, 4,5,9,10-tetrahydropyrene-2,7-dicarboxylate, 2,3,5,6-tetramethylbenzene-1,4-dicarboxylate, or benzene-1,3,5-tris(4-benzoate) were synthesized in gram-scale quantities to measure their hydrogen uptake properties. Hydrogen adsorption isotherms measured at 77 K show a distinct dependence of uptake on the nature of the link. At 1 atm, the materials sorb between 4.2 and 9.3 molecules of H2 per formula unit. The results imply a trend in hydrogen uptake with the number of rings in the organic moiety.

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Authors: Rowsell, J. L. C., Millward, A. R., Park, K. S., & Yaghi, O. M.
Venue: Journal of the American Chemical Society
Publisher: American Chemical Society (ACS)
Published: 2004-04-17
Volume: 126
Issue: 18
Pages: 5666-5667
ISSN: 0002-7863 (ISSN-L)
1520-5126
DOI: 10.1021/ja049408c
OpenAlex: W2090532065
Cited by: 1,326
References: 0
FWCI: 61.71
Type: journal article
Language: en
Open access: closed

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Hydrogen Sorption in Functionalized Metal−Organic Frameworks

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