The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Catalytic Activity Trends of Oxygen Reduction Reaction for Nonaqueous Li-Air Batteries
Abstract
We report the intrinsic oxygen reduction reaction (ORR) activity of polycrystalline palladium, platinum, ruthenium, gold, and glassy carbon surfaces in 0.1 M LiClO(4) 1,2-dimethoxyethane via rotating disk electrode measurements. The nonaqueous Li(+)-ORR activity of these surfaces primarily correlates to oxygen adsorption energy, forming a "volcano-type" trend. The activity trend found on the polycrystalline surfaces was in good agreement with the trend in the discharge voltage of Li-O(2) cells catalyzed by nanoparticle catalysts. Our findings provide insights into Li(+)-ORR mechanisms in nonaqueous media and design of efficient air electrodes for Li-air battery applications.
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Self-citation
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Metadata
- Authors
- Lu, Y.-C., Gasteiger, H. A., & Shao-Horn, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-11-08
- Volume
- 133
- Issue
- 47
- Pages
- 19048-19051
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2041088325
- Cited by
- 567
- References
- 29
- FWCI
- 36.99
- Type
- journal article
- Language
- en
- Open access
- closed
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