The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Fe/N/C Composite in Li–O2 Battery: Studies of Catalytic Structure and Activity toward Oxygen Evolution Reaction
Abstract
Atomically dispersed Fe/N/C composite was synthesized and its role in controlling the oxygen evolution reaction during Li-O(2) battery charging was studied by use of a tetra(ethylene glycol) dimethyl ether-based electrolyte. Li-O(2) cells using Fe/N/C as the cathode catalyst showed lower overpotentials than α-MnO(2)/carbon catalyst and carbon-only material. Gases evolved during the charge step contained only oxygen for Fe/N/C cathode catalyst, whereas CO(2) was also detected in the case of α-MnO(2)/C or carbon-only material; this CO(2) was presumably generated from electrolyte decomposition. Our results reiterate the catalytic effect in reducing overpotentials, which not only enhances battery efficiency but also improves its lifespan by reducing or eliminating electrolyte decomposition. The structure of the Fe/N/C catalyst was characterized by transmission electron microscopy, scanning transmission electron microscopy, inductively coupled plasma optical emission spectroscopy, and X-ray absorption spectroscopy. Iron was found to be uniformly distributed within the carbon matrix, and on average, Fe was coordinated by 3.3 ± 0.6 and 2.2 ± 0.3 low Z elements (C/N/O) at bond distances of ~1.92 and ~2.09 Å, respectively.
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Saveleva, V. A., Ebner, K., Ni, L., Smolentsev, G., Klose, D., Zitolo, A., Marelli, E., Li, J., Medarde, M., Safonova, O. V., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202016951 · Cited by 82
Metadata
- Authors
- Shui, J.-L., Karan, N. K., Balasubramanian, M., Li, S.-Y., & Liu, D.-J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-10-01
- Volume
- 134
- Issue
- 40
- Pages
- 16654-16661
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2331260692
- Cited by
- 284
- References
- 47
- FWCI
- 19.53
- Type
- journal article
- Language
- en
- Open access
- closed
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