The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol
Open accessAbstract
Particulate methane monooxygenase (pMMO) is an enzyme that oxidizes methane to methanol with high activity and selectivity. Limited success has been achieved in incorporating biologically relevant ligands for the formation of such active site in a synthetic system. Here, we report the design and synthesis of metal-organic framework (MOF) catalysts inspired by pMMO for selective methane oxidation to methanol. By judicious selection of a framework with appropriate topology and chemical functionality, MOF-808 was used to postsynthetically install ligands bearing imidazole units for subsequent metalation with Cu(I) in the presence of dioxygen. The catalysts show high selectivity for methane oxidation to methanol under isothermal conditions at 150 °C. Combined spectroscopies and density functional theory calculations suggest bis(μ-oxo) dicopper species as probable active site of the catalysts.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Density-functional thermochemistry. III. The role of exact exchange
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464913 · Cited by 103,767
Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
ATHENA,ARTEMIS,HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT
Ravel, B., & Newville, M. (2005) · Journal of Synchrotron Radiation · doi:10.1107/s0909049505012719 · Cited by 16,965
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Self-citationIFEFFIT : interactive XAFS analysis and FEFF fitting
Newville, M. (2001) · Journal of Synchrotron Radiation · doi:10.1107/s0909049500016964 · Cited by 3,046
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W. L., Hudson, M. R., & Yaghi, O. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500330a · Cited by 2,888
Self-citationO’Keeffe, M., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr200205j · Cited by 2,143
Self-citationStructure and Spectroscopy of Copper−Dioxygen Complexes
Mirica, L. M., Ottenwaelder, X., & Stack, T. D. P. (2004) · Chemical Reviews · doi:10.1021/cr020632z · Cited by 1,341
Kau, L. S., Spira-Solomon, D. J., Penner-Hahn, J. E., Hodgson, K. O., & Solomon, E. I. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00255a032 · Cited by 1,045
Selective anaerobic oxidation of methane enables direct synthesis of methanol
Sushkevich, V. L., Palagin, D., Ranocchiari, M., & van Bokhoven, J. A. (2017) · Science · doi:10.1126/science.aam9035 · Cited by 887
Supercapacitors of Nanocrystalline Metal–Organic Frameworks
Choi, K. M., Jeong, H. M., Park, J. H., Zhang, Y.-B., Kang, J. K., & Yaghi, O. M. (2014) · ACS Nano · doi:10.1021/nn5027092 · Cited by 794
Self-citationGrundner, S., Markovits, M. A. C., Li, G., Tromp, M., Pidko, E. A., Hensen, E. J. M., Jentys, A., Sanchez-Sanchez, M., & Lercher, J. A. (2015) · Nature Communications · doi:10.1038/ncomms8546 · Cited by 773
Groothaert, M. H., Smeets, P. J., Sels, B. F., Jacobs, P. A., & Schoonheydt, R. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja047158u · Cited by 731
Design of functional metalloproteins
Lu, Y., Yeung, N., Sieracki, N., & Marshall, N. M. (2009) · Nature · doi:10.1038/nature08304 · Cited by 704
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity
Elwell, C. E., Gagnon, N. L., Neisen, B. D., Dhar, D., Spaeth, A. D., Yee, G. M., & Tolman, W. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00636 · Cited by 702
Hammond, C., Forde, M. M., Ab Rahim, M. H., Thetford, A., He, Q., Jenkins, R. L., Dimitratos, N., Lopez‐Sanchez, J. A., Dummer, N. F., Murphy, D. M., et al. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108706 · Cited by 634
Deria, P., Mondloch, J. E., Tylianakis, E., Ghosh, P., Bury, W., Snurr, R. Q., Hupp, J. T., & Farha, O. K. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408959g · Cited by 591
Olivos-Suarez, A. I., Szécsényi, À., Hensen, E. J. M., Ruiz-Martinez, J., Pidko, E. A., & Gascon, J. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00428 · Cited by 575
Oxidation of methane by a biological dicopper centre
Balasubramanian, R., Smith, S. M., Rawat, S., Yatsunyk, L. A., Stemmler, T. L., & Rosenzweig, A. C. (2010) · Nature · doi:10.1038/nature08992 · Cited by 545
The role of metal–organic frameworks in a carbon-neutral energy cycle
Schoedel, A., Ji, Z., & Yaghi, O. M. (2016) · Nature Energy · doi:10.1038/nenergy.2016.34 · Cited by 516
Self-citationAlkane Oxidation: Methane Monooxygenases, Related Enzymes, and Their Biomimetics
Wang, V. C.-C., Maji, S., Chen, P. P.-Y., Lee, H. K., Yu, S. S.-F., & Chan, S. I. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00624 · Cited by 464
Xiao, D. J., Bloch, E. D., Mason, J. A., Queen, W. L., Hudson, M. R., Planas, N., Borycz, J., Dzubak, A. L., Verma, P., Lee, K., et al. (2014) · Nature Chemistry · doi:10.1038/nchem.1956 · Cited by 455
Narsimhan, K., Iyoki, K., Dinh, K., & Román-Leshkov, Y. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00139 · Cited by 453
Yuan, S., Lu, W., Chen, Y.-P., Zhang, Q., Liu, T.-F., Feng, D., Wang, X., Qin, J., & Zhou, H.-C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512762r · Cited by 421
Bis(μ-oxo)dimetal “Diamond” Cores in Copper and Iron Complexes Relevant to Biocatalysis
Que, Jr., & Tolman, W. B. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020402)41:7<1114::aid-anie1114>3.0.co;2-6 · Cited by 416
Analysis of Soils and Minerals Using X‐ray Absorption Spectroscopy
Kelly, S. D., Hesterberg, D., & Ravel, B. (2008) · SSSA Book Series · doi:10.2136/sssabookser5.5.c14 · Cited by 400
Groothaert, M. H., van Bokhoven, J. A., Battiston, A. A., Weckhuysen, B. M., & Schoonheydt, R. A. (2003) · Journal of the American Chemical Society · doi:10.1021/ja029684w · Cited by 378
Methane to Methanol: Structure–Activity Relationships for Cu-CHA
Pappas, D. K., Borfecchia, E., Dyballa, M., Pankin, I. A., Lomachenko, K. A., Martini, A., Signorile, M., Teketel, S., Arstad, B., Berlier, G., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06472 · Cited by 371
Coordinative alignment of molecules in chiral metal-organic frameworks
Lee, S., Kapustin, E. A., & Yaghi, O. M. (2016) · Science · doi:10.1126/science.aaf9135 · Cited by 345
Self-citationManna, K., Zhang, T., & Lin, W. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5018267 · Cited by 313
Shadle, S. E., Penner-Hahn, J. E., Schugar, H. J., Hedman, B., Hodgson, K. O., & Solomon, E. I. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00055a057 · Cited by 297
Isoreticular Metalation of Metal−Organic Frameworks
Doonan, C. J., Morris, W., Furukawa, H., & Yaghi, O. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903251e · Cited by 291
Self-citationMetal–Organic Frameworks as Biomimetic Catalysts
Gu, Z., Park, J., Raiff, A., Wei, Z., & Zhou, H. (2014) · ChemCatChem · doi:10.1002/cctc.201300493 · Cited by 283
Kraft, S., Stümpel, J., Becker, P., & Kuetgens, U. (1996) · Review of Scientific Instruments · doi:10.1063/1.1146657 · Cited by 273
Beamline 10.3.2 at ALS: a hard X-ray microprobe for environmental and materials sciences
Marcus, M. A., MacDowell, A. A., Celestre, R., Manceau, A., Miller, T., Padmore, H. A., & Sublett, R. E. (2004) · Journal of Synchrotron Radiation · doi:10.1107/s0909049504005837 · Cited by 267
Isolated Fe Sites in Metal Organic Frameworks Catalyze the Direct Conversion of Methane to Methanol
Osadchii, D. Y., Olivos-Suarez, A. I., Szécsényi, Á., Li, G., Nasalevich, M. A., Dugulan, I. A., Crespo, P. S., Hensen, E. J. M., Veber, S. L., Fedin, M. V., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00505 · Cited by 266
Fracaroli, A. M., Siman, P., Nagib, D. A., Suzuki, M., Furukawa, H., Toste, F. D., & Yaghi, O. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04204 · Cited by 232
Self-citationMahadevan, V., Hou, Z., Cole, A. P., Root, D. E., Lal, T. K., Solomon, E. I., & Stack, T. D. P. (1997) · Journal of the American Chemical Society · doi:10.1021/ja972946n · Cited by 212
Copper dioxygen (bio)inorganic chemistry
Solomon, E. I., Ginsbach, J. W., Heppner, D. E., Kieber-Emmons, M. T., Kjaergaard, C. H., Smeets, P. J., Tian, L., & Woertink, J. S. (2011) · Faraday Discuss. · doi:10.1039/c005500j · Cited by 174
Innershell Absorption Spectroscopy of Amino Acids at All Relevant Absorption Edges
Zubavichus, Y. V., Shaporenko, A., Grunze, M., & Zharnikov, M. (2005) · The Journal of Physical Chemistry A · doi:10.1021/jp0535846 · Cited by 173
Methane-Oxidizing Enzymes: An Upstream Problem in Biological Gas-to-Liquids Conversion
Lawton, T. J., & Rosenzweig, A. C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04568 · Cited by 164
Herres-Pawlis, S., Verma, P., Haase, R., Kang, P., Lyons, C. T., Wasinger, E. C., Flörke, U., Henkel, G., & Stack, T. D. P. (2009) · Journal of the American Chemical Society · doi:10.1021/ja807809x · Cited by 163
Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models
Citek, C., Herres‐Pawlis, S., & Stack, T. D. P. (2015) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00220 · Cited by 126
Spiers Memorial Lecture: : Progress and prospects of reticular chemistry
Rungtaweevoranit, B., Diercks, C. S., Kalmutzki, M. J., & Yaghi, O. M. (2017) · Faraday Discussions · doi:10.1039/c7fd00160f · Cited by 120
Self-citationEvidence for Oxygen Binding at the Active Site of Particulate Methane Monooxygenase
Culpepper, M. A., Cutsail, G. E., Hoffman, B. M., & Rosenzweig, A. C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302195p · Cited by 94
Designing Heterogeneous Catalysts by Incorporating Enzyme-Like Functionalities into MOFs
Lillerud, K. P., Olsbye, U., & Tilset, M. (2010) · Topics in Catalysis · doi:10.1007/s11244-010-9518-4 · Cited by 83
Popp, T. M. O., & Yaghi, O. M. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00529 · Cited by 66
Self-citationCulpepper, M. A., Cutsail, G. E., Gunderson, W. A., Hoffman, B. M., & Rosenzweig, A. C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5053126 · Cited by 60
Kang, P., Bobyr, E., Dustman, J., Hodgson, K. O., Hedman, B., Solomon, E. I., & Stack, T. D. P. (2010) · Inorganic Chemistry · doi:10.1021/ic101515g · Cited by 57
Cited by
Bavykina, A., Kolobov, N., Khan, I. S., Bau, J. A., Ramirez, A., & Gascon, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00685 · Cited by 1,754
Metal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y.-S., Zhang, M., Zou, R., & Xu, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,233
Li, J., Huang, H., Xue, W., Sun, K., Song, X., Wu, C., Nie, L., Li, Y., Liu, C., Pan, Y., et al. (2021) · Nature Catalysis · doi:10.1038/s41929-021-00665-3 · Cited by 843
Water and Metal–Organic Frameworks: From Interaction toward Utilization
Liu, X., Wang, X., & Kapteijn, F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00746 · Cited by 614
Using nature’s blueprint to expand catalysis with Earth-abundant metals
Bullock, R. M., Chen, J. G., Gagliardi, L., Chirik, P. J., Farha, O. K., Hendon, C. H., Jones, C. W., Keith, J. A., Klosin, J., Minteer, S. D., et al. (2020) · Science · doi:10.1126/science.abc3183 · Cited by 592
Metadata
- Authors
- Baek, J., Rungtaweevoranit, B., Pei, X., Park, M., Fakra, S. C., Liu, Y.-S., Matheu, R., Alshmimri, S. A., Alshehri, S., Trickett, C. A., Somorjai, G. A., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-12-10
- Volume
- 140
- Issue
- 51
- Pages
- 18208-18216
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2904352928
- Cited by
- 417
- References
- 49
- FWCI
- 12.49
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
