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Effective Passivation of Exfoliated Black Phosphorus Transistors against Ambient Degradation
Open accessAbstract
Unencapsulated, exfoliated black phosphorus (BP) flakes are found to chemically degrade upon exposure to ambient conditions. Atomic force microscopy, electrostatic force microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy are employed to characterize the structure and chemistry of the degradation process, suggesting that O2 saturated H2O irreversibly reacts with BP to form oxidized phosphorus species. This interpretation is further supported by the observation that BP degradation occurs more rapidly on hydrophobic octadecyltrichlorosilane self-assembled monolayers and on H-Si(111) versus hydrophilic SiO2. For unencapsulated BP field-effect transistors, the ambient degradation causes large increases in threshold voltage after 6 h in ambient, followed by a ∼ 10(3) decrease in FET current on/off ratio and mobility after 48 h. Atomic layer deposited AlOx overlayers effectively suppress ambient degradation, allowing encapsulated BP FETs to maintain high on/off ratios of ∼ 10(3) and mobilities of ∼ 100 cm(2) V(-1) s(-1) for over 2 weeks in ambient conditions. This work shows that the ambient degradation of BP can be managed effectively when the flakes are sufficiently passivated. In turn, our strategy for enhancing BP environmental stability will accelerate efforts to implement BP in electronic and optoelectronic applications.
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Cites
Black phosphorus field-effect transistors
Li, L., Yu, Y., Ye, G. J., Ge, Q., Ou, X., Wu, H., Feng, D., Chen, X. H., & Zhang, Y. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.35 · Cited by 8,413
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility
Liu, H., Neal, A. T., Zhu, Z., Luo, Z., Xu, X., Tománek, D., & Ye, P. D. (2014) · ACS Nano · doi:10.1021/nn501226z · Cited by 6,480
Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane
Elias, D. C., Nair, R. R., Mohiuddin, T. M. G., Morozov, S. V., Blake, P., Halsall, M. P., Ferrari, A. C., Boukhvalov, D. W., Katsnelson, M. I., Geim, A. K., et al. (2009) · Science · doi:10.1126/science.1167130 · Cited by 4,163
Xia, F., Wang, H., & Jia, Y. (2014) · Nature Communications · doi:10.1038/ncomms5458 · Cited by 3,516
Blake, P., Hill, E. W., Castro Neto, A. H., Novoselov, K. S., Jiang, D., Yang, R., Booth, T. J., & Geim, A. K. (2007) · Applied Physics Letters · doi:10.1063/1.2768624 · Cited by 1,794
Fast and Broadband Photoresponse of Few-Layer Black Phosphorus Field-Effect Transistors
Buscema, M., Groenendijk, D. J., Blanter, S. I., Steele, G. A., van der Zant, H. S. J., & Castellanos-Gomez, A. (2014) · Nano Letters · doi:10.1021/nl5008085 · Cited by 1,656
Isolation and characterization of few-layer black phosphorus
Castellanos-Gomez, A., Vicarelli, L., Prada, E., Island, J. O., Narasimha-Acharya, K. L., Blanter, S. I., Groenendijk, D. J., Buscema, M., Steele, G. A., Alvarez, J. V., et al. (2014) · 2D Materials · doi:10.1088/2053-1583/1/2/025001 · Cited by 1,621
Strain-Induced Gap Modification in Black Phosphorus
Rodin, A. S., Carvalho, A., & Castro Neto, A. H. (2014) · Physical Review Letters · doi:10.1103/physrevlett.112.176801 · Cited by 1,523
Fluorographene: A Two‐Dimensional Counterpart of Teflon
Nair, R. R., Ren, W., Jalil, R., Riaz, I., Kravets, V. G., Britnell, L., Blake, P., Schedin, F., Mayorov, A. S., Yuan, S., et al. (2010) · Small · doi:10.1002/smll.201001555 · Cited by 1,326
Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus
Fei, R., & Yang, L. (2014) · Nano Letters · doi:10.1021/nl500935z · Cited by 1,282
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Bhimanapati, G. R., Lin, Z., Meunier, V., Jung, Y., Cha, J., Das, S., Xiao, D., Son, Y., Strano, M. S., Cooper, V. R., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b05556 · Cited by 2,659
Photooxidation and quantum confinement effects in exfoliated black phosphorus
Favron, A., Gaufrès, E., Fossard, F., Phaneuf-L’Heureux, A.-L., Tang, N. Y.-W., Lévesque, P. L., Loiseau, A., Leonelli, R., Francoeur, S., & Martel, R. (2015) · Nature Materials · doi:10.1038/nmat4299 · Cited by 1,376
Phosphorene: from theory to applications
Carvalho, A., Wang, M., Zhu, X., Rodin, A. S., Su, H., & Castro Neto, A. H. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.61 · Cited by 1,159
Hanlon, D., Backes, C., Doherty, E., Cucinotta, C. S., Berner, N. C., Boland, C., Lee, K., Harvey, A., Lynch, P., Gholamvand, Z., et al. (2015) · Nature Communications · doi:10.1038/ncomms9563 · Cited by 1,104
Two-dimensional antimonene single crystals grown by van der Waals epitaxy
Ji, J., Song, X., Liu, J., Yan, Z., Huo, C., Zhang, S., Su, M., Liao, L., Wang, W., Ni, Z., et al. (2016) · Nature Communications · doi:10.1038/ncomms13352 · Cited by 981
Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides
Chia, X., Eng, A. Y. S., Ambrosi, A., Tan, S. M., & Pumera, M. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00287 · Cited by 894
Recent progress in 2D group-VA semiconductors: from theory to experiment
Zhang, S., Guo, S., Chen, Z., Wang, Y., Gao, H., Gómez-Herrero, J., Ares, P., Zamora, F., Zhu, Z., & Zeng, H. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00125h · Cited by 850
Phosphorene: Fabrication, Properties, and Applications
Kou, L., Chen, C., & Smith, S. C. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01094 · Cited by 825
Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials
Meng, Z., Stolz, R. M., Mendecki, L., & Mirica, K. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00311 · Cited by 773
High‐Electron‐Mobility and Air‐Stable 2D Layered PtSe2 FETs
Zhao, Y., Qiao, J., Yu, Z., Yu, P., Xu, K., Lau, S. P., Zhou, W., Liu, Z., Wang, X., Ji, W., et al. (2017) · Advanced Materials · doi:10.1002/adma.201604230 · Cited by 686
Light‐Induced Ambient Degradation of Few‐Layer Black Phosphorus: Mechanism and Protection
Zhou, Q., Chen, Q., Tong, Y., & Wang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201605168 · Cited by 658
2D phosphorene as a water splitting photocatalyst: fundamentals to applications
Rahman, M. Z., Kwong, C. W., Davey, K., & Qiao, S. Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03732h · Cited by 623
Fast Charging Anode Materials for Lithium‐Ion Batteries: Current Status and Perspectives
Li, S., Wang, K., Zhang, G., Li, S., Xu, Y., Zhang, X., Zhang, X., Zheng, S., Sun, X., & Ma, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202200796 · Cited by 607
Zeng, X., Luo, M., Liu, G., Wang, X., Tao, W., Lin, Y., Ji, X., Nie, L., & Mei, L. (2018) · Advanced Science · doi:10.1002/advs.201800510 · Cited by 598
Surface Coordination of Black Phosphorus for Robust Air and Water Stability
Zhao, Y., Wang, H., Huang, H., Xiao, Q., Xu, Y., Guo, Z., Xie, H., Shao, J., Sun, Z., Han, W., et al. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201512038 · Cited by 565
Insulators for 2D nanoelectronics: the gap to bridge
Illarionov, Y. Y., Knobloch, T., Jech, M., Lanza, M., Akinwande, D., Vexler, M. I., Mueller, T., Lemme, M. C., Fiori, G., Schwierz, F., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-16640-8 · Cited by 552
Interaction of Black Phosphorus with Oxygen and Water
Huang, Y., Qiao, J., He, K., Bliznakov, S., Sutter, E., Chen, X., Luo, D., Meng, F., Su, D., Decker, J., et al. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b03592 · Cited by 532
Lin, Z., McCreary, A., Briggs, N., Subramanian, S., Zhang, K., Sun, Y., Li, X., Borys, N. J., Yuan, H., Fullerton-Shirey, S. K., et al. (2016) · 2D Materials · doi:10.1088/2053-1583/3/4/042001 · Cited by 530
Self-citationBlack Phosphorus Rediscovered: From Bulk Material to Monolayers
Gusmão, R., Sofer, Z., & Pumera, M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201610512 · Cited by 521
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702093 · Cited by 518
Metal‐Ion‐Modified Black Phosphorus with Enhanced Stability and Transistor Performance
Guo, Z., Chen, S., Wang, Z., Yang, Z., Liu, F., Xu, Y., Wang, J., Yi, Y., Zhang, H., Liao, L., et al. (2017) · Advanced Materials · doi:10.1002/adma.201703811 · Cited by 516
Production of Two‐Dimensional Nanomaterials via Liquid‐Based Direct Exfoliation
Niu, L., Coleman, J. N., Zhang, H., Shin, H., Chhowalla, M., & Zheng, Z. (2016) · Small · doi:10.1002/smll.201502207 · Cited by 502
Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy
Woomer, A. H., Farnsworth, T. W., Hu, J., Wells, R. A., Donley, C. L., & Warren, S. C. (2015) · ACS Nano · doi:10.1021/acsnano.5b02599 · Cited by 498
Phosphorene and Phosphorene‐Based Materials – Prospects for Future Applications
Batmunkh, M., Bat‐Erdene, M., & Shapter, J. G. (2016) · Advanced Materials · doi:10.1002/adma.201602254 · Cited by 494
Aging of Transition Metal Dichalcogenide Monolayers
Gao, J., Li, B., Tan, J., Chow, P., Lu, T.-M., & Koratkar, N. (2016) · ACS Nano · doi:10.1021/acsnano.5b07677 · Cited by 490
Microfiber-based few-layer black phosphorus saturable absorber for ultra-fast fiber laser
Luo, Z.-C., Liu, M., Guo, Z.-N., Jiang, X.-F., Luo, A.-P., Zhao, C.-J., Yu, X.-F., Xu, W.-C., & Zhang, H. (2015) · Optics Express · doi:10.1364/oe.23.020030 · Cited by 476
Zheng, Y., Yu, Z., Ou, H., Asiri, A. M., Chen, Y., & Wang, X. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201705407 · Cited by 462
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Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456
Monolayer atomic crystal molecular superlattices
Wang, C., He, Q., Halim, U., Liu, Y., Zhu, E., Lin, Z., Xiao, H., Duan, X., Feng, Z., Cheng, R., et al. (2018) · Nature · doi:10.1038/nature25774 · Cited by 444
Self‐Powered Photodetectors Based on 2D Materials
Qiao, H., Huang, Z., Ren, X., Liu, S., Zhang, Y., Qi, X., & Zhang, H. (2020) · Advanced Optical Materials · doi:10.1002/adom.201900765 · Cited by 435
Superior Chemical Sensing Performance of Black Phosphorus: Comparison with MoS2 and Graphene
Cho, S., Lee, Y., Koh, H., Jung, H., Kim, J., Yoo, H., Kim, J., & Jung, H. (2016) · Advanced Materials · doi:10.1002/adma.201601167 · Cited by 431
Flexible Black Phosphorus Ambipolar Transistors, Circuits and AM Demodulator
Zhu, W., Yogeesh, M. N., Yang, S., Aldave, S. H., Kim, J.-S., Sonde, S., Tao, L., Lu, N., & Akinwande, D. (2015) · Nano Letters · doi:10.1021/nl5047329 · Cited by 428
Toward air-stable multilayer phosphorene thin-films and transistors
Kim, J.-S., Liu, Y., Zhu, W., Kim, S., Wu, D., Tao, L., Dodabalapur, A., Lai, K., & Akinwande, D. (2015) · Scientific Reports · doi:10.1038/srep08989 · Cited by 408
Black phosphorus nanostructures: recent advances in hybridization, doping and functionalization
Lei, W., Liu, G., Zhang, J., & Liu, M. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00021a · Cited by 365
Cai, Y., Zhang, G., & Zhang, Y.-W. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b02634 · Cited by 354
Black Phosphorus and its Biomedical Applications
Choi, J. R., Yong, K. W., Choi, J. Y., Nilghaz, A., Lin, Y., Xu, J., & Lu, X. (2018) · Theranostics · doi:10.7150/thno.22573 · Cited by 353
Emerging Trends in Phosphorene Fabrication towards Next Generation Devices
Dhanabalan, S. C., Ponraj, J. S., Guo, Z., Li, S., Bao, Q., & Zhang, H. (2017) · Advanced Science · doi:10.1002/advs.201600305 · Cited by 344
Flexible All‐Solid‐State Supercapacitors based on Liquid‐Exfoliated Black‐Phosphorus Nanoflakes
Hao, C., Yang, B., Wen, F., Xiang, J., Li, L., Wang, W., Zeng, Z., Xu, B., Zhao, Z., Liu, Z., et al. (2016) · Advanced Materials · doi:10.1002/adma.201505730 · Cited by 339
Electronic Transport in Two-Dimensional Materials
Sangwan, V. K., & Hersam, M. C. (2018) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-050317-021353 · Cited by 336
Self-citationRecent advances in black phosphorus-based photonics, electronics, sensors and energy devices
Zhou, Y., Zhang, M., Guo, Z., Miao, L., Han, S.-T., Wang, Z., Zhang, X., Zhang, H., & Peng, Z. (2017) · Materials Horizons · doi:10.1039/c7mh00543a · Cited by 332
Yang, Z., Hao, J., Yuan, S., Lin, S., Yau, H. M., Dai, J., & Lau, S. P. (2015) · Advanced Materials · doi:10.1002/adma.201500990 · Cited by 330
Black phosphorus and its isoelectronic materials
Xia, F., Wang, H., Hwang, J. C. M., Neto, A. H. C., & Yang, L. (2019) · Nature Reviews Physics · doi:10.1038/s42254-019-0043-5 · Cited by 322
The Rise of 2D Photothermal Materials beyond Graphene for Clean Water Production
Xie, Z., Duo, Y., Lin, Z., Fan, T., Xing, C., Yu, L., Wang, R., Qiu, M., Zhang, Y., Zhao, Y., et al. (2020) · Advanced Science · doi:10.1002/advs.201902236 · Cited by 320
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Zhao, Q., Wang, W., Carrascoso-Plana, F., Jie, W., Wang, T., Castellanos-Gomez, A., & Frisenda, R. (2020) · Materials Horizons · doi:10.1039/c9mh01020c · Cited by 317
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Frisenda, R., Molina-Mendoza, A. J., Mueller, T., Castellanos-Gomez, A., & van der Zant, H. S. J. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00880e · Cited by 312
Localized Surface Plasmons in Nanostructured Monolayer Black Phosphorus
Liu, Z., & Aydin, K. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b05166 · Cited by 305
Lu, L., Tang, X., Cao, R., Wu, L., Li, Z., Jing, G., Dong, B., Lu, S., Li, Y., Xiang, Y., et al. (2017) · Advanced Optical Materials · doi:10.1002/adom.201700301 · Cited by 305
Qiao, J., Pan, Y., Yang, F., Wang, C., Chai, Y., & Ji, W. (2018) · Science Bulletin · doi:10.1016/j.scib.2018.01.010 · Cited by 284
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Zha, X.-H., Huang, Q., He, J., He, H., Zhai, J., Francisco, J. S., & Du, S. (2016) · Scientific Reports · doi:10.1038/srep27971 · Cited by 284
Ryder, C. R., Wood, J. D., Wells, S. A., & Hersam, M. C. (2016) · ACS Nano · doi:10.1021/acsnano.6b01091 · Cited by 283
Self-citationChen, P., Li, N., Chen, X., Ong, W.-J., & Zhao, X. (2017) · 2D Materials · doi:10.1088/2053-1583/aa8d37 · Cited by 283
Tian, B., Tian, B., Smith, B., Scott, M. C., Lei, Q., Hua, R., Tian, Y., & Liu, Y. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1800069115 · Cited by 267
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Room-Temperature Semiconductor Gas Sensors: Challenges and Opportunities
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Zhu, J., Park, H., Chen, J., Gu, X., Zhang, H., Karthikeyan, S., Wendel, N., Campbell, S. A., Dawber, M., Du, X., et al. (2016) · Advanced Electronic Materials · doi:10.1002/aelm.201600040 · Cited by 108
Sim, Y., Chae, Y., & Kwon, S.-Y. (2022) · iScience · doi:10.1016/j.isci.2022.105098 · Cited by 47
Metadata
- Authors
- Wood, J. D., Wells, S. A., Jariwala, D., Chen, K.-S., Cho, E., Sangwan, V. K., Liu, X., Lauhon, L. J., Marks, T. J., & Hersam, M. C.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-12
- Volume
- 14
- Issue
- 12
- Pages
- 6964-6970
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1980874018
- Cited by
- 1,491
- References
- 31
- FWCI
- 61.95
- Type
- journal article
- Language
- en
- Open access
- green
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