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Thermally Induced Structural Evolution and Performance of Mesoporous Block Copolymer-Directed Alumina Perovskite Solar Cells
Open accessAbstract
Structure control in solution-processed hybrid perovskites is crucial to design and fabricate highly efficient solar cells. Here, we utilize in situ grazing incidence wide-angle X-ray scattering and scanning electron microscopy to investigate the structural evolution and film morphologies of methylammonium lead tri-iodide/chloride (CH3NH3PbI(3-x)Cl(x)) in mesoporous block copolymer derived alumina superstructures during thermal annealing. We show the CH3NH3PbI(3-x)Cl(x) material evolution to be characterized by three distinct structures: a crystalline precursor structure not described previously, a 3D perovskite structure, and a mixture of compounds resulting from degradation. Finally, we demonstrate how understanding the processing parameters provides the foundation needed for optimal perovskite film morphology and coverage, leading to enhanced block copolymer-directed perovskite solar cell performance.
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Metadata
- Authors
- Tan, K. W., Moore, D. T., Saliba, M., Sai, H., Estroff, L. A., Hanrath, T., Snaith, H. J., & Wiesner, U.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-11
- Volume
- 8
- Issue
- 5
- Pages
- 4730-4739
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2319430767
- Cited by
- 293
- References
- 58
- FWCI
- 26.88
- Type
- journal article
- Language
- en
- Open access
- hybrid
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