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Frequency Ratio of Al+and Hg+Single-Ion Optical Clocks; Metrology at the 17th Decimal Place
Open accessAbstract
Time has always had a special status in physics because of its fundamental role in specifying the regularities of nature and because of the extraordinary precision with which it can be measured. This precision enables tests of fundamental physics and cosmology, as well as practical applications such as satellite navigation. Recently, a regime of operation for atomic clocks based on optical transitions has become possible, promising even higher performance. We report the frequency ratio of two optical atomic clocks with a fractional uncertainty of 5.2 × 10–17. The ratio of aluminum and mercury single-ion optical clock frequencies ν Al+/ν Hg+is 1.052871833148990438(55), where the uncertainty comprises a statistical measurement uncertainty of 4.3 × 10–17, and systematic uncertainties of 1.9 × 10–17 and 2.3 × 10–17 in the mercury and aluminum frequency standards, respectively. Repeated measurements during the past year yield a preliminary constraint on the temporal variation of the fine-structure constant α of\batchmode \documentclass[fleqn,10pt,legalpaper]{article} \usepackage{amssymb} \usepackage{amsfonts} \usepackage{amsmath} \pagestyle{empty} \begin{document} \({\dot{{\alpha}}}{/}{\alpha}=(-1.6{\pm}2.3){\times}10^{-17}{/}\mathrm{year}\) \end{document}.
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“Atomic clock experiments constrain the current variation of the fine structure constant, | α/α 0 | < 10 -17 yr -1 [13]”
From Stress-energy tensor of a scalar field on a product spacetime with a time-dependent compact dimension (2026) · cites this paper as [13]
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Experimental — accuracy not yet measuredIn the citing paper
“d dt ln m Hg m Al ¼ ð5:3 Æ 7:9Þ Â 10 À17 yr À1 :ð131Þ”
From Fundamental constants: from measurement to the universe, a window on gravitation and cosmology (2025) · cites this paper as Rosenband et al. 2008
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“_ a EM =a EM ¼ ðÀ1:6 Æ 2:3Þ Â 10 À17 yr À1 on a EM alone”
From Fundamental constants: from measurement to the universe, a window on gravitation and cosmology (2025) · cites this paper as Rosenband et al. 2008
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Actinide ions for testing the spatial α -variation hypothesis
Dzuba, V. A., Safronova, M. S., Safronova, M. S., & Flambaum, V. V. (2015) · Physical Review A · doi:10.1103/physreva.92.060502 · Cited by 28
Recent atomic clock comparisons at NIST
Lorini, L., Ashby, N., Brusch, A., Diddams, S. A., Drullinger, R. E., Eason, E., Fortier, T. M., Hastings, P., Heavner, T. P., Hume, D. B., et al. (2008) · The European Physical Journal Special Topics · doi:10.1140/epjst/e2008-00807-7 · Cited by 29
Self-citationExperimental apparatus for overlapping a ground-state cooled ion with ultracold atoms
Meir, Z., Šikorský, T., Ben-shlomi, R., Akerman, N., Pinkas, M., Dallal, Y., & Ozeri, R. (2017) · Journal of Modern Optics · doi:10.1080/09500340.2017.1397217 · Cited by 30
Towards a 229Th-Based Nuclear Clock
von der Wense, L., Seiferle, B., & Thirolf, P. G. (2018) · Measurement Techniques · doi:10.1007/s11018-018-1337-1 · Cited by 27
“ptical clocks were developed and are operated in metrologyinstitutes aroundthe world [14]. A 2008comparison of two single-ion optical clocks revealed a fractional frequency uncertainty of 5.2 · 10−17 [15] and in 2016 the operation of a single ion Yb+ optical clock at 3 · 10−18 frequency uncertainty was reported [16].…”
BackgroundInfluentialDamage-free single-mode transmission of deep-UV light in hollow-core PCF
Gebert, F., Frosz, M. H., Weiss, T., Wan, Y., Ermolov, A., Joly, N. Y., Schmidt, P. O., & Russell, P. S. J. (2014) · MPG.PuRe (Max Planck Society) · Cited by 29
Self-citationRotational spectrum of the molecular ion NH + as a probe for α and me/mp variation
Beloy, K., Kozlov, M. G., Borschevsky, A., Hauser, A. W., Flambaum, V. V., & Schwerdtfeger, P. (2011) · Physical Review A · doi:10.1103/physreva.83.062514 · Cited by 29
Ultrastable lasers: new developments and applications
Sterr, U., Legero, T., Keßler, T., Schnatz, H., Grosche, G., Terra, O., & Riehle, F. (2009) · Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE · doi:10.1117/12.825217 · Cited by 29
Quantum logic readout and cooling of a single dark electron spin
Shi, F., Zhang, Q., Naydenov, B., Jelezko, F., Du, J., Reinhard, F., & Wrachtrup, J. (2013) · Physical Review B · doi:10.1103/physrevb.87.195414 · Cited by 30
Hyperfine-mediated electric quadrupole shifts in Al+ and In+ ion clocks
Beloy, K., Leibrandt, D. R., & Itano, W. M. (2017) · Physical Review A · doi:10.1103/physreva.95.043405 · Cited by 29
Self-citationClocks in Space for Tests of Fundamental Physics
Delva, P., Hees, A., & Wolf, P. (2017) · Space Science Reviews · doi:10.1007/s11214-017-0361-9 · Cited by 28
Stadnik, Y. V. (2017) · Springer theses · doi:10.1007/978-3-319-63417-3 · Cited by 24
“of systems have provided some of the most precise limits on temporal drifts in and particle masses to date [170{ 185]. The most stringent laboratory limits on temporal variations of come from Al +/Hg [182] and Yb /Yb+ [185] clock comparison experiments: j(d=dt)=j. 2 10 17 year 1; (25) while the most stringent laborato…”
BackgroundTime variation of fundamental couplings and dynamical dark energy
Dent, T., Stern, S., & WETTERICH, C. (2009) · Journal of Cosmology and Astroparticle Physics · doi:10.1088/1475-7516/2009/01/038 · Cited by 29
Varying alpha: New constraints from seasonal variations
Barrow, J. D., & Shaw, D. J. (2008) · Physical review. D. Particles, fields, gravitation, and cosmology/Physical review. D. Particles and fields · doi:10.1103/physrevd.78.067304 · Cited by 29
Absolute frequency measurement of the 88 Sr + clock transition using a GPS link to the SI second
Dubé, P., Bernard, J. E., & Gertsvolf, M. (2017) · Metrologia · doi:10.1088/1681-7575/aa5e60 · Cited by 28
Narrow and Ultranarrow Transitions in Highly Charged Xe Ions as Probes of Fifth Forces
Rehbehn, N.-H., Rosner, M. K., Berengut, J. C., Schmidt, P. O., Pfeifer, T., Gu, M. F., & López-Urrutia, J. R. C. (2023) · Physical Review Letters · doi:10.1103/physrevlett.131.161803 · Cited by 30
Self-citationThe CIPM list ‘Recommended values of standard frequencies’: 2021 update
Margolis, H. S., Panfilo, G., Petit, G., Oates, C. W., Ido, T., & Bize, S. (2024) · Metrologia · doi:10.1088/1681-7575/ad3afc · Cited by 32
Phonon-mediated entanglement for trapped ion quantum computing
Soderberg, K.-A. B., & Monroe, C. R. (2010) · Reports on Progress in Physics · doi:10.1088/0034-4885/73/3/036401 · Cited by 28
“Recently, researchers at NIST in Boulder, CO have used entanglement between a trapped 9Be ion and a trapped 27Al ion to cool, initialize, and readout information in the 27Al ion to produce an atomic clock that rivals the current Cs time standard [87].”
BackgroundSuperposition, Entanglement, and Raising Schrödinger’s Cat (Nobel Lecture)
Wineland, D. J. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201303404 · Cited by 33
Self-citationParticle-hole configuration interaction and many-body perturbation theory: Application to Hg+
Berengut, J. C. (2016) · Physical Review A · doi:10.1103/physreva.94.012502 · Cited by 28
Metadata
- Authors
- Rosenband, T., Hume, D. B., Schmidt, P. O., Chou, C. W., Brusch, A., Lorini, L., Oskay, W. H., Drullinger, R. E., Fortier, T. M., Stalnaker, J. E., Diddams, S. A., Swann, W. C., Newbury, N. R., Itano, W. M., Wineland, D. J., & Bergquist, J. C.
- Affiliations
- National Institute of Standards and Technology (US)
- Corresponding author
- Rosenband, T.
- Schmidt, P. O.
- Lorini, L.
- Oskay, W. H.
- Stalnaker, J. E.
- ORCID
- Venue
- Science
- Published
- 2008-03-28
- Volume
- 319
- Issue
- 5871
- Pages
- 1808-1812
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1997269293
- Cited by
- 1,450
- References
- 31
- Citations by year
- 2026: 27 · 2025: 62 · 2024: 52 · 2023: 44 · 2022: 43 · 2021: 50 · 2020: 60 · 2019: 78 · 2018: 65 · 2017: 76 · 2016: 85 · 2015: 96 · 2014: 129 · 2013: 99 · 2012: 99
- FWCI
- 73.95
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- CINECA IRIS Institutional Research Information System (IRIS Istituto Nazionale di Ricerca Metrologica) (submittedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Advanced Frequency and Time Standards
- Physical Sciences › Physics and Astronomy › Instrumentation › Scientific Measurement and Uncertainty Evaluation
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Atomic and Subatomic Physics Research
- Keywords
- optical atomic clocks, aluminum ions, mercury ions, frequency ratio, frequency metrology, fine-structure constant variation, systematic uncertainties
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